PENRAY TOTAL DIESEL FUEL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 04/04/2014 Revision date: 04/04/2014 Version: 1.0 04/04/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY TOTAL DIESEL FUEL SYSTEM CLEANER Product code : 105032 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Asphaltene Dispersant. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. 60090 Wheeling, IL T (800) 373-6729 This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Liquid 2 Acute toxicity 4 (Inhalation) Skin irritation 2 Reproductive toxicity 2 (developmental) Specific target organ toxicity - Single exposure 3 Specific target organ toxicity - Repeated exposure 2 Aspiration hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Highly flammable liquid and vapor. Harmful if inhaled. Causes skin irritation. Suspected of damaging the unborn child. May cause drowsiness or dizziness. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces.? No smoking. Keep container tightly closed. Ground/Bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. Do not breathe gas/mist/vapors/spray. If exposed or concerned: Get medical advice/attention. If on skin (or hair): Take off immediately all contaminated clothing and wash it before reuse. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) 4 % of the mixture consists of ingredient(s) of unknown acute toxicity. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable PENRAY TOTAL DIESEL FUEL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/04/2014 EN (English) 2/7 3.2. Mixture Name Product identifier % GHS-US classification Toluene (CAS No) 108-88-3 60 - 100 Flam. Liq. 2 Acute Tox. 4 (Oral) Skin Irrit. 2 Repr. 2 STOT SE 3 STOT RE 2 Asp. Tox. 1 Xylenes (o-, m-, p- isomers) (CAS No) 1330-20-7 7 - 13 Flam. Liq. 3 Acute Tox. 4 (Dermal, Inhalation) Skin Irrit. 2 Amines, polyethylenepoly-, reaction products with succinic anhydride polyisobutenyl derivatives (CAS No) 84605-20-9 3 - 7 Flam. Liq. 4 Eye Irrit. 2A Solvent naphtha, petroleum, heavy aromatic (CAS No) 64742-94-5 1 - 5 Flam. Liq. 3 Asp. Tox. 1 2-Butoxyethanol (CAS No) 111-76-2 1 - 5 Flam. Liq. 3 Acute Tox. 4 (Oral, Dermal, Inhalation) Skin Irrit. 2 Eye Irrit. 2A 2-Ethylhexyl nitrate (CAS No) 27247-96-7 1 - 5 Flam. Liq. 4 Acute Tox. 4 (Inhalation) Kerosene, petroleum, hydrodesulfurized (CAS No) 64742-81-0 1 - 5 Asp. Tox. 1 The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Harmful if inhaled. May cause drowsiness, dizziness and central nervous system depression. May cause respiratory tract irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, aldehydes and hydrocarbons. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Vapors may be heavier than air and may travel along the ground to a distant ignition source and flash back. Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate sources of ignition. PENRAY TOTAL DIESEL FUEL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/04/2014 EN (English) 3/7 6.2. Methods and material for containment and cleaning up For containment : Dike and contain spill. Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes. Do not breathe gas/mist/vapors/spray. Do not swallow. Handle and open container with care. Use only non-sparking tools. When using do not eat, drink or smoke. Use only outdoors or in a well- ventilated area. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed and in a well-ventilated place. Store locked up. Keep cool. Keep away from heat, sparks, and flame. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Toluene (108-88-3) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (STEL) (ppm) 150 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm Xylenes (o-, m-, p- isomers) (1330-20-7) USA ACGIH ACGIH TWA (ppm) 100 ppm USA ACGIH ACGIH STEL (ppm) 150 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 435 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 100 ppm 2-Butoxyethanol (111-76-2) USA ACGIH ACGIH TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 240 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 50 ppm Kerosene, petroleum, hydrodesulfurized (64742-81-0) USA ACGIH ACGIH TWA (mg/m?) 200 mg/m? 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. PENRAY TOTAL DIESEL FUEL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/04/2014 EN (English) 4/7 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Amber. Odour : Petroleum odor. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : ~ 111 ?C (~ 232 ?F) (Toluene) Flash point : ~ 4.4 ?C (~ 40 ?F) (Toluene) Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Flammable. Vapour pressure : No data available. Relative vapour density at 20 ?C : No data available. Relative density : No data available. Solubility : No data available. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. May form flammable/explosive vapour-air mixture. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Open flame. 10.5. Incompatible materials Acids. Bases. Oxidizers. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, aldehydes and hydrocarbons. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if inhaled. 105032 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) ~ 19.7 mg/l/4h Toluene (108-88-3) LD50 oral rat > 5000 mg/kg LD50 dermal rat 12124 mg/kg LD50 dermal rabbit 8390 mg/kg LC50 inhalation rat (mg/l) 28.1 mg/l/4h Xylenes (o-, m-, p- isomers) (1330-20-7) LD50 oral rat 4300 mg/kg PENRAY TOTAL DIESEL FUEL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/04/2014 EN (English) 5/7 Xylenes (o-, m-, p- isomers) (1330-20-7) LD50 dermal rabbit > 1700 mg/kg LC50 inhalation rat (ppm) 5000 ppm/4h LC50 inhalation rat (mg/l) 47635 mg/l/4h Solvent naphtha, petroleum, heavy aromatic (64742-94-5) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000mg/kg 2-Butoxyethanol (111-76-2) LD50 oral rat 470 mg/kg LC50 inhalation rat (ppm) 450 ppm/4h 2-Ethylhexyl nitrate (27247-96-7) LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 4820 mg/kg LC50 inhalation rat (mg/l) > 14 mg/l/4h Kerosene, petroleum, hydrodesulfurized (64742-81-0) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) > 5.2 mg/l/4h Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Based on available data, the classification criteria are not met. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. Toluene (108-88-3) IARC group 3 Xylenes (o-, m-, p- isomers) (1330-20-7) IARC group 3 2-Butoxyethanol (111-76-2) IARC group 3 National Toxicity Program (NTP) Status 1 Reproductive toxicity : Suspected of damaging the unborn child. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : May cause damage to organs through prolonged or repeated exposure. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : Harmful if inhaled. May cause drowsiness, dizziness and central nervous system depression. May cause respiratory tract irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 105032 Persistence and degradability Not established. 12.3. Bioaccumulative potential 105032 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available PENRAY TOTAL DIESEL FUEL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/04/2014 EN (English) 6/7 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Handle empty containers with care because residual vapours are flammable. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No. : UN1993 14.2. UN proper shipping name Proper Shipping Name : Flammable liquids, n.o.s. (Toluene, Xylene) Department of Transportation Hazard Classes : 3 Hazard labels : Packing group (DOT) : II 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations Toluene (108-88-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % Xylenes (o-, m-, p- isomers) (1330-20-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) SARA Section 313 - Emission Reporting 1.0 % Amines, polyethylenepoly-, reaction products with succinic anhydride polyisobutenyl derivatives (84605-20-9) Listed on the United States TSCA (Toxic Substances Control Act) inventory Solvent naphtha, petroleum, heavy aromatic (64742-94-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory 2-Butoxyethanol (111-76-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory 2-Ethylhexyl nitrate (27247-96-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Kerosene, petroleum, hydrodesulfurized (64742-81-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. US State regulations 105032 State or local regulations This product contains chemicals known to the State of California to cause cancer, birth defects or other reproductive harm. SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: IARC International Agency for Research on Cancer. 1 - Carcinogenic to humans; 2A - Probably carcinogenic to humans; 2B - Possibly carcinogenic to humans; 3 - Not classifiable; 4 - Probably not carcinogenic to humans. PENRAY TOTAL DIESEL FUEL SYSTEM CLEANER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/04/2014 EN (English) 7/7 IARC International Agency for Research on Cancer. NTP National Toxicology Program. 1 - Evidence of Carcinogenicity; 2 - Known Human Carcinogens; 3 - Reasonably anticipated to be Human Carcinogen; 4 - Substances delisted from report on Carcinogens; 5 - Twelfth Report - Items under consideration. SECTION 16: Other information Indication of changes : None. Date of issue : 04/04/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 3 NFPA reactivity : 0 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product