MATERIAL SAFETY DATA SHEET 3M? Rubbing Compound PN 05973, 05974, 05968, 3900, 39002, 39002S, 39005 06/08/12 _________________________________________________________________________________________________ Page 1 of 8 Material Safety Data Sheet Copyright, 2012, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M? Rubbing Compound PN 05973, 05974, 05968, 3900, 39002, 39002S, 39005 MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 06/08/12 Supercedes Date: 01/23/12 Document Group: 29-3593-0 Product Use: Intended Use: Automotive Specific Use: Rubbing Compound SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt WATER 7732-18-5 30 - 60 SILICA 7631-86-9 15 - 40 HYDROTREATED LIGHT PETROLEUM DISTILLATES 64742-47-8 10 - 30 KAOLINITE 1318-74-7 3 - 7 OLEIC ACID 112-80-1 1 - 5 SOLVENT-REFINED HEAVY PARAFFINIC PETROLEUM DISTILLATES 64741-88-4 1 - 5 QUARTZ SILICA 14808-60-7 < 2.75 MINERAL OIL 64741-89-5 < 1.5 GLYCERIN 56-81-5 0.5 - 1.5 IllITE 12173-60-3 0.5 - 1.5 POLY(OXYETHYLENE)SORBITAN MONOSTEARATE 9005-67-8 0.1 - 1.0 DIBROMOACETONITRILE 3252-43-5 < 0.003 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: Tan liquid. Slight solvent odor. MATERIAL SAFETY DATA SHEET 3M? Rubbing Compound PN 05973, 05974, 05968, 3900, 39002, 39002S, 39005 06/08/12 _________________________________________________________________________________________________ Page 2 of 8 General Physical Form: Liquid Immediate health, physical, and environmental hazards: May cause target organ effects. Contains a chemical or chemicals which can cause cancer. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Mild Eye Irritation: Signs/symptoms may include redness, pain, and tearing. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Silicosis: Signs/symptoms may include breathlessness, weakness, chest pain, persistent cough, increased amounts of sputum, and heart disease. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient C.A.S. No. Class Description Regulation DIBROMOACETONITRILE 3252-43-5 Grp. 2B: Possible human carc. International Agency for Research on Cancer QUARTZ SILICA 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE) SEQ677 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE) SEQ677 Known human carcinogen National Toxicology Program Carcinogens SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. MATERIAL SAFETY DATA SHEET 3M? Rubbing Compound PN 05973, 05974, 05968, 3900, 39002, 39002S, 39005 06/08/12 _________________________________________________________________________________________________ Page 3 of 8 Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point No flash point Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. Clean-up methods Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. MATERIAL SAFETY DATA SHEET 3M? Rubbing Compound PN 05973, 05974, 05968, 3900, 39002, 39002S, 39005 06/08/12 _________________________________________________________________________________________________ Page 4 of 8 SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid skin contact. Avoid eye contact with vapors, mists, or spray. Do not breathe vapors. Do not breathe dust. Avoid breathing of dust created by sanding, grinding or machining. 7.2 STORAGE Store away from heat. Store out of direct sunlight. Store away from areas where product may come into contact with food or pharmaceuticals. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use in an enclosed process area is recommended. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles . 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Neoprene Nitrile Rubber . 8.2.3 Respiratory Protection Do not breathe vapors. Do not breathe dust. Avoid breathing of dust created by sanding, grinding or machining. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates Half facepiece or full facepiece air-purifying respirator suitable for particulates . Select and use respiratory protection to prevent an inhalation exposure based on the results of an exposure assessment. Consult with your respirator manufacturer for selection of appropriate types of respirators. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information Benzene, 1,3-dimethyl- ACGIH TWA 100 ppm Benzene, 1,3-dimethyl- ACGIH STEL 150 ppm Benzene, 1,4-dimethyl- ACGIH TWA 100 ppm MATERIAL SAFETY DATA SHEET 3M? Rubbing Compound PN 05973, 05974, 05968, 3900, 39002, 39002S, 39005 06/08/12 _________________________________________________________________________________________________ Page 5 of 8 Benzene, 1,4-dimethyl- ACGIH STEL 150 ppm GLYCERIN ACGIH TWA, as mist 10 mg/m3 GLYCERIN OSHA TWA, respirable fraction 5 mg/m3 GLYCERIN OSHA TWA, as total dust 15 mg/m3 HYDROTREATED LIGHT PETROLEUM DISTILLATES CMRG TWA 300 ppm MINERAL OILS, HIGHLY-REFINED OILS ACGIH TWA, inhalable fraction 5 mg/m3 Paraffin oil OSHA TWA, as mist 5 mg/m3 PETROLEUM DISTILLATES OSHA TWA 2000 mg/m3 POLYETHYLENE GLYCOLS AIHA TWA, as particulate 10 mg/m3 QUARTZ SILICA ACGIH TWA, respirable fraction 0.025 mg/m3 QUARTZ SILICA OSHA TWA concentration, respirable 0.1 mg/m3 QUARTZ SILICA OSHA TWA concentration, as total dust 0.3 mg/m3 SILICA CMRG TWA, as respirable dust 3 mg/m3 SILICA, AMORPHOUS OSHA TWA concentration 0.8 mg/m3 SILICA, AMORPHOUS OSHA TWA 20 millions of particles/cu. ft. SOLVENT-REFINED HEAVY PARAFFINIC PETROLEUM DISTILLATES CMRG TWA 5 mg/m3 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: Tan liquid. Slight solvent odor. General Physical Form: Liquid Autoignition temperature No Data Available Flash Point No flash point Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Boiling Point 98.3 ?C Density 1.2 g/ml Vapor Density No Data Available Vapor Pressure No Data Available Specific Gravity 1.2 [Ref Std: WATER=1] pH 7.5 - 8.5 Melting point Not Applicable Solubility in Water Negligible Evaporation rate No Data Available Hazardous Air Pollutants 0.00002 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 213 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 15.2 % weight [Test Method: calculated per CARB title 2] MATERIAL SAFETY DATA SHEET 3M? Rubbing Compound PN 05973, 05974, 05968, 3900, 39002, 39002S, 39005 06/08/12 _________________________________________________________________________________________________ Page 6 of 8 Kow - Oct/Water partition coef No Data Available Percent volatile 58.2 % weight VOC Less H2O & Exempt Solvents 414 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: 10.1 Conditions to avoid Heat Sparks and/or flames 10.2 Materials to avoid None known Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator in the presence of a combustible material. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. Since regulations vary, consult applicable regulations or authorities before disposal. MATERIAL SAFETY DATA SHEET 3M? Rubbing Compound PN 05973, 05974, 05968, 3900, 39002, 39002S, 39005 06/08/12 _________________________________________________________________________________________________ Page 7 of 8 SECTION 14:TRANSPORT INFORMATION ID Number(s): LB-K100-0959-1, LB-K100-0959-2, LB-K100-0961-4, 60-4550-5551-1, 60-4550-5552-9, 60-4550-5553-7, 60-4550-5784-8, 60- 4550-5785-5, 60-4550-5786-3, 60-4550-5787-1, 60-4550-5788-9, 60-4550-5806-9, 60-4550-6559-3 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes STATE REGULATIONS Contact 3M for more information. CALIFORNIA PROPOSITION 65 Ingredient C.A.S. No. Classification SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE) SEQ677 **Carcinogen DIBROMOACETONITRILE 3252-43-5 **Carcinogen ** WARNING: contains a chemical which can cause cancer. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. WHMIS: Hazardous This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 1 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. MATERIAL SAFETY DATA SHEET 3M? Rubbing Compound PN 05973, 05974, 05968, 3900, 39002, 39002S, 39005 06/08/12 _________________________________________________________________________________________________ Page 8 of 8 Revision Changes: Section 8: Respiratory protection - recommended respirators information was modified. Section 2: Ingredient table was modified. Section 8: Exposure guidelines ingredient information was modified. Section 13: EPA hazardous waste number (RCRA) heading was deleted. Section 13: EPA hazardous waste number (RCRA) information was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M 3M USA MSDSs are available at www.3M.com