3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 1 of 15 Safety Data Sheet Copyright,2014,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 29-0759-0 Version Number: 1.00 Issue Date: 17/11/2014 Supercedes Date: Initial Issue This Safety Data Sheet has been prepared in accordance with the Malaysia Occupational Safety and Health (Chemical Classification, Labelling and Safety Data Sheets) Regulations 2013. SECTION 1: Identification 1.1. Product identifier 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 Product Identification Numbers 60-4550-4948-0 60-4550-5501-6 XH-0038-1778-6 XH-0038-5388-0 1.2. Recommended use and restrictions on use Recommended use Hand Cleaner 1.3. Supplier?s details ADDRESS: 3M Malaysia Sdn. Bhd., Level 8, Block F, Oasis Square, No.2, Jalan PJU 1A/7A, Ara Damansara 47301 Petaling, Jaya, Selangor Telephone: 03-7884 2888 E Mail: This email address is being protected from spambots. You need JavaScript enabled to view it. Website: www.3M.com.my 1.4. Emergency telephone number +60 03-7884 2888 SECTION 2: Hazard identification 2.1. Classification of the substance or mixture Specific Target Organ Toxicity (repeated exposure): Category 2. 2.2. Label elements Signal word Danger Symbols Health Hazard | Pictograms 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 2 of 15 Hazard Statements H373 May cause damage to organs through prolonged or repeated exposure: respiratory system | Precautionary statements General: P102 Keep out of reach of children. P101 If medical advice is needed, have product container or label at hand. Prevention: P260 Do not breathe dust/fume/gas/mist/vapors/spray. Disposal: P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Other hazards None known SECTION 3: Composition/information on ingredients This material is a mixture. Ingredient C.A.S. No. % by Wt Dimethyl Adipate 627-93-0 40 - 70 Polyethylene Glycol 25322-68-3 7 - 13 Dimethyl Glutarate 1119-40-0 1 - 10 Bentonite 1302-78-9 < 7 Talc 14807-96-6 3 - 7 Stearic Acid 57-11-4 3 - 7 Cellulose 9004-34-6 3 - 7 Lanolin 8006-54-0 1 - 5 Triethanolamine 102-71-6 1 - 5 Petrolatum 8009-03-8 1 - 5 Synthetic Amorphous Silica, Fumed, Crystalline Free 112945-52-5 1 - 5 D-Limonene 5989-27-5 0.5 - 1.5 Quartz Silica 14808-60-7 < 0.5 Cristobalite 14464-46-1 < 0.15 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 3 of 15 Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Oxides of Nitrogen During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with water. Seal the container. Dispose of collected material as soon as possible. 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 4 of 15 SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Keep from freezing. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Triethanolamine 102-71-6 ACGIH TWA:5 mg/m3 Triethanolamine 102-71-6 Malaysia OELs TWA(8 hours):5 mg/m3 Dimethyl Glutarate 1119-40-0 CMRG TWA(as Dimethyl Esters):1.5 ppm(10 mg/m3) Cristobalite 14464-46-1 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Cristobalite 14464-46-1 Malaysia OELs TWA(respirable fraction)(8 hours):0.05 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Talc 14807-96-6 CMRG TWA(as respirable dust):0.5 mg/m3 Talc 14807-96-6 Malaysia OELs TWA(respirable fraction)(8 hours):2 mg/m3 Quartz Silica 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Quartz Silica 14808-60-7 Malaysia OELs TWA(respirable fraction)(8 hours):0.1 mg/m3 STEARATES 57-11-4 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin STEARATES 57-11-4 Malaysia OELs TWA(8 hours):10 mg/m3 Dimethyl Adipate 627-93-0 CMRG TWA(as Dimethyl Esters):1.5 ppm(10 mg/m3) OIL MIST, MINERAL 8009-03-8 Malaysia OELs TWA(as mist)(8 hours):5 mg/m3 Cellulose 9004-34-6 ACGIH TWA:10 mg/m3 Cellulose 9004-34-6 Malaysia OELs TWA(8 hours):10 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists CMRG : Chemical Manufacturer's Recommended Guidelines Malaysia OELs : Malaysia. Occupational Safety and Health (Use and Standards of Exposure of Chemicals Hazardous to Health) Regulations TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 5 of 15 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection None required. Skin/hand protection No chemical protective gloves are required. Respiratory protection Under normal use conditions, airborne exposures are not expected to be significant enough to require respiratory protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Paste Specific Physical Form: Paste Appearance/Odor sweet odor, light tan paste Odor threshold No Data Available pH 8.1 - 8.7 Melting point/Freezing point No Data Available Boiling point/Initial boiling point/Boiling range >=101.7 ?C Flash Point 93.9 ?C [Test Method: Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure 133.3 Pa [Test Method: Estimated] [Details: CONDITIONS: @ 20 C] Vapor Density No Data Available Density 1.1 - 1.2 kg/l Relative Density 1.1 - 1.2 kg/l [Ref Std: WATER=1] Water solubility Slight (less than 10%) Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity >= 40 Pa-s Hazardous Air Pollutants 0.0019 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 0.8 % weight [Test Method: calculated per CARB title 2] Volatile Organic Compounds 678 g/l [Test Method: calculated SCAQMD rule 443.1] Percent volatile 58.5 % weight [Details: (excluding exempt compounds)] VOC Less H2O & Exempt Solvents 681 g/l [Test Method: calculated SCAQMD rule 443.1] 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 6 of 15 SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 7 of 15 Target Organ Effects: Prolonged or repeated exposure may cause: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Carcinogenicity: Contains a chemical(s) which may cause cancer following prolonged, repeated inhalation of dust from dried or cured product. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Polyethylene Glycol Dermal Rabbit LD50 > 20,000 mg/kg Polyethylene Glycol Ingestion Rat LD50 32,770 mg/kg Dimethyl Glutarate Dermal Rabbit LD50 > 5,000 mg/kg Dimethyl Glutarate Ingestion Rat LD50 > 5,000 mg/kg Stearic Acid Dermal Rabbit LD50 > 2,000 mg/kg Stearic Acid Ingestion Rat LD50 > 5,000 mg/kg Talc Dermal LD50 Not available Talc Ingestion LD50 Not available Cellulose Dermal Rabbit LD50 > 2,000 mg/kg Cellulose Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.8 mg/l Cellulose Ingestion Rat LD50 > 5,000 mg/kg Triethanolamine Dermal Rabbit LD50 > 2,000 mg/kg Triethanolamine Ingestion Rat LD50 9,000 mg/kg Petrolatum Dermal LD50 estimated to be > 5,000 mg/kg Petrolatum Ingestion Rat LD50 > 5,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Dermal Rabbit LD50 > 5,000 mg/kg Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Rat LD50 > 5,110 mg/kg D-Limonene Inhalation- Vapor (4 hours) Mouse LC50 > 3.14 mg/l D-Limonene Dermal Rabbit LD50 > 5,000 mg/kg D-Limonene Ingestion Rat LD50 4,400 mg/kg Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg Cristobalite Dermal LD50 estimated to be > 5,000 mg/kg Cristobalite Ingestion LD50 estimated to be > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Polyethylene Glycol Rabbit Minimal irritation Stearic Acid Rabbit Mild irritant Talc Rabbit No significant irritation Cellulose Not available No significant irritation Triethanolamine Rabbit Minimal irritation Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation D-Limonene Rabbit Mild irritant Quartz Silica No significant irritation Cristobalite No significant irritation Serious Eye Damage/Irritation 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 8 of 15 Name Species Value Polyethylene Glycol Rabbit Mild irritant Stearic Acid Moderate irritant Talc Rabbit No significant irritation Cellulose Not available No significant irritation Triethanolamine Rabbit Mild irritant Synthetic Amorphous Silica, Fumed, Crystalline Free Rabbit No significant irritation D-Limonene Rabbit Mild irritant Skin Sensitization Name Species Value Polyethylene Glycol Guinea pig Not sensitizing Triethanolamine Human Some positive data exist, but the data are not sufficient for classification Synthetic Amorphous Silica, Fumed, Crystalline Free Human and animal Not sensitizing D-Limonene Mouse Sensitizing Respiratory Sensitization Name Species Value Talc Human Not sensitizing Germ Cell Mutagenicity Name Route Value Polyethylene Glycol In Vitro Not mutagenic Polyethylene Glycol In vivo Not mutagenic Stearic Acid In Vitro Not mutagenic Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Triethanolamine In Vitro Not mutagenic Triethanolamine In vivo Not mutagenic Synthetic Amorphous Silica, Fumed, Crystalline Free In Vitro Not mutagenic D-Limonene In Vitro Not mutagenic D-Limonene In vivo Not mutagenic Quartz Silica In Vitro Some positive data exist, but the data are not sufficient for classification Quartz Silica In vivo Some positive data exist, but the data are not sufficient for classification Cristobalite In Vitro Some positive data exist, but the data are not sufficient for classification Cristobalite In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Polyethylene Glycol Ingestion Rat Not carcinogenic Stearic Acid Ingestion Rat Not carcinogenic Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Triethanolamine Dermal Multiple animal species Not carcinogenic Triethanolamine Ingestion Mouse Some positive data exist, but the data are not sufficient for classification Synthetic Amorphous Silica, Fumed, Crystalline Free Not Specified Mouse Some positive data exist, but the data are not sufficient for classification D-Limonene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Quartz Silica Inhalation Human and animal Carcinogenic Cristobalite Inhalation Human and Carcinogenic 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 9 of 15 animal Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Polyethylene Glycol Ingestion Not toxic to female reproduction Rat NOAEL 1,125 mg/kg/day during gestation Polyethylene Glycol Ingestion Not toxic to male reproduction Rat NOAEL 5699 +/- 1341 mg/kg/day 5 days Polyethylene Glycol Not Specified Some positive reproductive/developmental data exist, but the data are not sufficient for classification NOEL N/A Polyethylene Glycol Ingestion Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL 562 mg/animal/da y during gestation Talc Ingestion Not toxic to development Rat NOAEL 1,600 mg/kg during organogenesis Triethanolamine Ingestion Not toxic to development Mouse NOAEL 1,125 mg/kg/day during organogenesis Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Synthetic Amorphous Silica, Fumed, Crystalline Free Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesis D-Limonene Ingestion Not toxic to male reproduction Rat NOAEL 150 mg/kg/day 103 weeks D-Limonene Ingestion Some positive female reproductive data exist, but the data are not sufficient for classification Rat NOAEL 750 mg/kg/day premating & during gestation D-Limonene Ingestion Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 591 mg/kg/day during organogenesis Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Polyethylene Glycol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.008 mg/l 2 weeks Stearic Acid Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available D-Limonene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Polyethylene Glycol Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.008 mg/l 2 weeks Polyethylene Glycol Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 5,640 mg/kg/day 13 weeks Polyethylene Glycol Ingestion heart | endocrine All data are negative Rat NOAEL 13 weeks 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 10 of 15 system | hematopoietic system | liver | nervous system 5,640 mg/kg/day Stearic Acid Ingestion blood Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 6 weeks Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 18 mg/m3 113 weeks Triethanolamine Dermal kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 2,000 mg/kg/day 2 years Triethanolamine Dermal liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 4,000 mg/kg/day 13 weeks Triethanolamine Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1,000 mg/kg/day 2 years Triethanolamine Ingestion liver Some positive data exist, but the data are not sufficient for classification Guinea pig NOAEL 1,600 mg/kg/day 24 weeks Synthetic Amorphous Silica, Fumed, Crystalline Free Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure D-Limonene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 75 mg/kg/day 103 weeks D-Limonene Ingestion liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1,000 mg/kg/day 103 weeks D-Limonene Ingestion heart | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | immune system | muscles | nervous system | respiratory system All data are negative Rat NOAEL 600 mg/kg/day 103 weeks Quartz Silica Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Cristobalite Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Aspiration Hazard Name Value D-Limonene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labeling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole. 12.1. Toxicity Acute aquatic hazard: 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 11 of 15 GHS Acute 3: Harmful to aquatic life. Chronic aquatic hazard: GHS Chronic 3: Harmful to aquatic life with long lasting effects No product test data available Material Cas # Organism Type Exposure Test Endpoint Test Result Bentonite 1302-78-9 Rainbow Trout Laboratory 96 hours Lethal Concentration 50% >19,000 mg/l Bentonite 1302-78-9 Data not available or insufficient for classification Dimethyl Glutarate 1119-40-0 Water flea Experimental 48 hours Effect Concentration 50% 122.1 mg/l Dimethyl Glutarate 1119-40-0 Fathead Minnow Experimental 96 hours Lethal Concentration 50% 19.6 mg/l Dimethyl Adipate 627-93-0 Water flea Experimental 48 hours Effect Concentration 50% 72 mg/l Dimethyl Adipate 627-93-0 Green Algae Experimental 72 hours Effect Concentration 50% >100 mg/l Petrolatum 8009-03-8 Rainbow Trout Estimated 96 hours Lethal Concentration 50% >1,000 mg/l Stearic Acid 57-11-4 Ricefish Laboratory 96 hours Lethal Concentration 50% 125 mg/l Triethanolamin e 102-71-6 Green algae Experimental 72 hours Effect Concentration 50% 216 mg/l Triethanolamin e 102-71-6 Water flea Experimental 48 hours Effect Concentration 50% 609.98 mg/l Triethanolamin e 102-71-6 Goldfish Experimental 24 hours Lethal Concentration 50% 5,000 mg/l Triethanolamin e 102-71-6 Water flea Experimental 21 days No obs Effect Conc 16 mg/l Cellulose 9004-34-6 Data not available or insufficient for classification Lanolin 8006-54-0 Data not available or insufficient for classification Quartz Silica 14808-60-7 Data not available or insufficient for 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 12 of 15 classification Cristobalite 14464-46-1 Data not available or insufficient for classification D-Limonene 5989-27-5 Water flea Experimental 96 hours Effect Concentration 50% 0.421 mg/l D-Limonene 5989-27-5 Green algae Experimental 96 hours Effect Concentration 50% 1.81 mg/l D-Limonene 5989-27-5 Fathead Minnow Experimental 96 hours Lethal Concentration 50% 0.702 mg/l Talc 14807-96-6 Data not available or insufficient for classification Synthetic Amorphous Silica, Fumed, Crystalline Free 112945-52-5 Green algae Analogous Compound 72 hours Effect Concentration 50% 440 mg/l Synthetic Amorphous Silica, Fumed, Crystalline Free 112945-52-5 Water flea Analogous Compound 48 hours Effect Concentration 50% 7,600 mg/l Synthetic Amorphous Silica, Fumed, Crystalline Free 112945-52-5 Zebra Fish Analogous Compound 96 hours Lethal Concentration 50% 5,000 mg/l Polyethylene Glycol 25322-68-3 Atlantic Salmon Experimental 96 hours Lethal Concentration 50% >1,000 mg/l 12.2. Persistence and degradability Material CAS No. Test Type Duration Study Type Test Result Protocol D-Limonene 5989-27-5 Experimental Photolysis Photolytic half- life (in air) 2.5 hours (t 1/2) Other methods Bentonite 1302-78-9 Data not available or insufficient for classification N/A N/A N/A N/A Petrolatum 8009-03-8 Data not available or insufficient for classification N/A N/A N/A N/A Cristobalite 14464-46-1 Data not available or insufficient for classification N/A N/A N/A N/A Synthetic 112945-52-5 Data not N/A N/A N/A N/A 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 13 of 15 Amorphous Silica, Fumed, Crystalline Free available or insufficient for classification Dimethyl Glutarate 1119-40-0 Experimental Biodegradation 14 days Biological Oxygen Demand 90 % weight OECD 301C - MITI (I) Dimethyl Adipate 627-93-0 Estimated Biodegradation 14 days Biological Oxygen Demand 85 % weight OECD 301C - MITI (I) Stearic Acid 57-11-4 Experimental Biodegradation 28 days Carbon dioxide evolution 89 % weight OECD 301B - Mod. Sturm or CO2 Triethanolamin e 102-71-6 Experimental Biodegradation 19 days Dissolv. Organic Carbon Deplet 96 % weight 40CFR 796.3240-Mod. OECD Scree Cellulose 9004-34-6 Data not available or insufficient for classification N/A N/A N/A N/A Lanolin 8006-54-0 Data not available or insufficient for classification N/A N/A N/A N/A Quartz Silica 14808-60-7 Data not available or insufficient for classification N/A N/A N/A N/A D-Limonene 5989-27-5 Experimental Biodegradation 14 days Biological Oxygen Demand 98 % weight OECD 301C - MITI (I) Talc 14807-96-6 Data not available or insufficient for classification N/A N/A N/A N/A Polyethylene Glycol 25322-68-3 Experimental Biodegradation 28 days Biological Oxygen Demand 56.2 % weight OECD 301C - MITI (I) 12.3. Bioaccumulative potential Material CAS No. Test Type Duration Study Type Test Result Protocol Talc 14807-96-6 Data not available or insufficient for classification N/A N/A N/A N/A Bentonite 1302-78-9 Data not available or insufficient for classification N/A N/A N/A N/A Lanolin 8006-54-0 Data not available or insufficient for classification N/A N/A N/A N/A Synthetic Amorphous 112945-52-5 Data not available or N/A N/A N/A N/A 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 14 of 15 Silica, Fumed, Crystalline Free insufficient for classification Polyethylene Glycol 25322-68-3 Data not available or insufficient for classification N/A N/A N/A N/A Petrolatum 8009-03-8 Data not available or insufficient for classification N/A N/A N/A N/A Cellulose 9004-34-6 Data not available or insufficient for classification N/A N/A N/A N/A Quartz Silica 14808-60-7 Data not available or insufficient for classification N/A N/A N/A N/A Cristobalite 14464-46-1 Data not available or insufficient for classification N/A N/A N/A N/A Dimethyl Glutarate 1119-40-0 Experimental Bioconcentrati on Log of Octanol/H2O part. coeff 0.62 Other methods Dimethyl Adipate 627-93-0 Experimental Bioconcentrati on Log of Octanol/H2O part. coeff 1.03 Other methods Stearic Acid 57-11-4 Experimental Bioconcentrati on Log of Octanol/H2O part. coeff 8.23 Other methods Triethanolamin e 102-71-6 Experimental Bioaccumulati on Log of Octanol/H2O part. coeff -2.3 Est: Octanol-water part. coeff 12.4. Mobility in soil Please contact manufacturer for more details 12.5 Other adverse effects No information available SECTION 13: Disposal considerations 13.1. Disposal methods According to the Environmental Quality (Scheduled Wastes) Regulations 2005, scheduled waste has to be sent to a prescribed premise for recycling, treatment or disposal. Please approach Kualiti Alam for proper schedule waste classification and disposal. SECTION 14: Transport Information Marine Transport (IMDG) 3M(TM) Paint Buster Hand Cleaner, PN 05604, 05975 __________________________________________________________________________________________ Page: 15 of 15 UN Number: None assigned. Proper Shipping Name: None assigned. Technical Name: None assigned. Hazard Class/Division: None assigned. Subsidiary Risk: None assigned. Packing Group: None assigned. Limited Quantity: None assigned. Marine Pollutant: None assigned. Marine Pollutant Technical Name: None assigned. Other Dangerous Goods Descriptions: None assigned. Air Transport (IATA) UN Number: None assigned. Proper Shipping Name: None assigned. Technical Name: None assigned. Hazard Class/Division: None assigned. Subsidiary Risk: None assigned. Packing Group: None assigned. Limited Quantity: None assigned. Marine Pollutant: None assigned. Marine Pollutant Technical Name: None assigned. Other Dangerous Goods Descriptions: None assigned. Transportation classifications are provided as a customer service. As for shipping, YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling or marking requirements. The above information is only for reference. If you are shipping by air or ocean, YOU are advised to check & meet applicable regulatory requirements. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Global inventory status Contact 3M for more information. The components of this product are in compliance with the chemical notification requirements of TSCA. SECTION 16: Other information DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications. 3M Malaysia SDSs are available at www.3M.com.my