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3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 1 of 11 Safety Data Sheet Copyright,2017,3M Canada Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document group: 24-5408-0 Version number: 5.02 Issue Date: 2017/07/12 Supercedes Date: 2017/05/18 This Safety Data Sheet has been prepared in accordance with the Canadian Hazardous Products Regulations. SECTION 1: Identification 1.1. Product identifier 3M(TM) Machine Polish, PN 05996 Product Identification Numbers LB-K100-0431-6 60-4550-3566-1 60-4550-3567-9 60-4550-3568-7 1.2. Recommended use and restrictions on use Recommended use Automotive Restrictions on use Not Applicable 1.3. Supplier?s details Company: 3M Canada Company Division: Automotive Aftermarket Address: 1840 Oxford Street East, Post Office Box 5757, London, Ontario N6A 4T1 Telephone: (800) 364-3577 Website: www.3M.ca 1.4. Emergency telephone number Medical Emergency Telephone: (519) 451-2500, Ext. 2222; Transportation Emergency Telephone (CANUTEC): (613) 996- 6666 SECTION 2: Hazard identification 2.1. Classification of the substance or mixture Flammable Liquid: Category 4. Skin Sensitizer: Category 1. 2.2. Label elements Signal word Warning Symbols 3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 2 of 11 Exclamation mark | Pictograms Hazard statements Combustible liquid. May cause an allergic skin reaction. Precautionary statements General: Keep out of reach of children. Read label before use. If medical advice is needed, have product container or label at hand. Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. Contaminated work clothing must not be allowed out of the workplace. Response: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Other hazards None known. SECTION 3: Composition/information on ingredients This material is a mixture. Ingredient C.A.S. No. % by Wt Water 7732-18-5 40 - 70 Hydrotreated Light Petroleum Distillates 64742-47-8 10 - 30 Aluminum Oxide 1344-28-1 5 - 10 Decamethylcyclopentasiloxane 541-02-6 3 - 7 Ceramic Materials and Wares, Chemicals 66402-68-4 1 - 5 Dodecamethylcyclohexasiloxane 540-97-6 1 - 5 White Mineral Oil (Petroleum) 8042-47-5 0.5 - 1.5 Ethylene oxide, polymer with ethylenediamine and propylene oxide 26316-40-5 <= 0.6 Hydrotreated Light Petroleum Distillate is a hazardous Trade Secret material according to WHMIS criteria. Refer to Section 15 for further information. 3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 3 of 11 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Oxides of Nitrogen During Combustion 5.3. Special protective actions for fire-fighters SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 4 of 11 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Aluminum, insoluble compounds 1344-28-1 ACGIH TWA(respirable fraction):1 mg/m3 Decamethylcyclopentasiloxane 541-02-6 AIHA TWA:10 ppm Kerosine (petroleum) 64742-47-8 ACGIH TWA(as total hydrocarbon vapor, non-aerosol):200 mg/m3 SKIN MINERAL OILS, HIGHLY- REFINED OILS 8042-47-5 ACGIH TWA(inhalable fraction):5 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: 3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 5 of 11 Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Neoprene Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - Neoprene Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid Specific Physical Form: Emulsion Appearance/Odour Slight solvent odour, grey liquid Odour threshold No Data Available pH 7.5 - 8.5 Melting point/Freezing point Not Applicable Boiling point/Initial boiling point/Boiling range 190.6 ?C Flash Point 76.7 ?C [Test Method:Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapour Pressure No Data Available Vapour Density No Data Available Density 0.96 g/ml Relative density 0.96 [Ref Std:WATER=1] Water solubility Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 16,000 - 20,000 mPa-s Molecular weight No Data Available Volatile Organic Compounds 14.8 % peso [Test Method:calculated per CARB title 2] Volatile Organic Compounds 145 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 82 % peso VOC Less H2O & Exempt Solvents 405 g/l [Test Method:calculated SCAQMD rule 443.1] 3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 6 of 11 SECTION 10: Stability and reactivity 10.1. Reactivity This material is considered to be non reactive under normal use conditions. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials None known. 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Toxicological Data 3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 7 of 11 If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Dust/Mist(4 hr) No data available; calculated ATE >12.5 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Hydrotreated Light Petroleum Distillates Dermal Rabbit LD50 > 3,160 mg/kg Hydrotreated Light Petroleum Distillates Inhalation- Dust/Mist (4 hours) Rat LC50 > 3 mg/l Hydrotreated Light Petroleum Distillates Ingestion Rat LD50 > 5,000 mg/kg Aluminum Oxide Dermal LD50 estimated to be > 5,000 mg/kg Aluminum Oxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 2.3 mg/l Aluminum Oxide Ingestion Rat LD50 > 5,000 mg/kg Decamethylcyclopentasiloxane Dermal Rabbit LD50 > 15,000 mg/kg Decamethylcyclopentasiloxane Inhalation- Dust/Mist (4 hours) Rat LC50 8.7 mg/l Decamethylcyclopentasiloxane Ingestion Rat LD50 > 24,134 mg/kg Dodecamethylcyclohexasiloxane Dermal Rat LD50 > 2,000 mg/kg Dodecamethylcyclohexasiloxane Ingestion Rat LD50 > 50,000 mg/kg Ceramic Materials and Wares, Chemicals Dermal LD50 estimated to be > 5,000 mg/kg Ceramic Materials and Wares, Chemicals Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg White Mineral Oil (Petroleum) Dermal Rabbit LD50 > 2,000 mg/kg White Mineral Oil (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Aluminum Oxide Rabbit No significant irritation Decamethylcyclopentasiloxane Rabbit No significant irritation Dodecamethylcyclohexasiloxane Rabbit No significant irritation Ceramic Materials and Wares, Chemicals Rabbit No significant irritation White Mineral Oil (Petroleum) Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Hydrotreated Light Petroleum Distillates Rabbit Mild irritant Aluminum Oxide Rabbit No significant irritation Decamethylcyclopentasiloxane Rabbit No significant irritation Dodecamethylcyclohexasiloxane Rabbit No significant irritation Ceramic Materials and Wares, Chemicals Rabbit Mild irritant White Mineral Oil (Petroleum) Rabbit Mild irritant Skin Sensitization Name Species Value Hydrotreated Light Petroleum Distillates Guinea pig Not classified Decamethylcyclopentasiloxane Mouse Not classified White Mineral Oil (Petroleum) Guinea pig Not classified Respiratory Sensitization 3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 8 of 11 For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Hydrotreated Light Petroleum Distillates In Vitro Not mutagenic Aluminum Oxide In Vitro Not mutagenic Decamethylcyclopentasiloxane In Vitro Not mutagenic Decamethylcyclopentasiloxane In vivo Not mutagenic Ceramic Materials and Wares, Chemicals In Vitro Some positive data exist, but the data are not sufficient for classification White Mineral Oil (Petroleum) In Vitro Not mutagenic Carcinogenicity Name Route Species Value Hydrotreated Light Petroleum Distillates Dermal Mouse Some positive data exist, but the data are not sufficient for classification Aluminum Oxide Inhalation Rat Not carcinogenic Decamethylcyclopentasiloxane Inhalation Rat Some positive data exist, but the data are not sufficient for classification Ceramic Materials and Wares, Chemicals Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification White Mineral Oil (Petroleum) Dermal Mouse Not carcinogenic White Mineral Oil (Petroleum) Inhalation Multiple animal species Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test result Exposure Duration Decamethylcyclopentasiloxane Inhalation Not classified for reproduction and/or development Rat NOAEL 2.43 mg/l 2 generation Decamethylcyclopentasiloxane Inhalation Not classified for female reproduction Rat NOAEL 2.43 mg/l 2 generation Decamethylcyclopentasiloxane Inhalation Not classified for male reproduction Rat NOAEL 2.43 mg/l 2 generation Dodecamethylcyclohexasiloxane Ingestion Not classified for female reproduction Rat NOAEL 1,000 mg/kg/day premating & during gestation Dodecamethylcyclohexasiloxane Ingestion Not classified for male reproduction Rat NOAEL 1,000 mg/kg/day 28 days Dodecamethylcyclohexasiloxane Ingestion Not classified for development Rat NOAEL 1,000 mg/kg/day premating & during gestation White Mineral Oil (Petroleum) Ingestion Not classified for female reproduction Rat NOAEL 4,350 mg/kg/day 13 weeks White Mineral Oil (Petroleum) Ingestion Not classified for male reproduction Rat NOAEL 4,350 mg/kg/day 13 weeks White Mineral Oil (Petroleum) Ingestion Not classified for development Rat NOAEL 4,350 mg/kg/day during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test result Exposure Duration Hydrotreated Light Petroleum Distillates Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Light Petroleum Distillates Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for NOAEL Not available 3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 9 of 11 classification Hydrotreated Light Petroleum Distillates Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test result Exposure Duration Aluminum Oxide Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Aluminum Oxide Inhalation pulmonary fibrosis Not classified Human NOAEL Not available occupational exposure Decamethylcyclopentasilo xane Dermal hematopoietic system | eyes Not classified Rat NOAEL 1,600 mg/kg/day 28 days Decamethylcyclopentasilo xane Inhalation hematopoietic system | respiratory system | liver | eyes | kidney and/or bladder Not classified Rat NOAEL 2.42 mg/l 2 years Decamethylcyclopentasilo xane Ingestion liver | immune system | respiratory system | heart | hematopoietic system | kidney and/or bladder Not classified Rat NOAEL 1,000 mg/kg/day 90 days Dodecamethylcyclohexasil oxane Ingestion endocrine system | liver | respiratory system | nervous system Not classified Rat NOAEL 1,000 mg/kg/day 28 days Ceramic Materials and Wares, Chemicals Inhalation pulmonary fibrosis Not classified Multiple animal species NOAEL not available Ceramic Materials and Wares, Chemicals Inhalation respiratory system Not classified Human NOAEL not available occupational exposure White Mineral Oil (Petroleum) Ingestion hematopoietic system Not classified Rat NOAEL 1,381 mg/kg/day 90 days White Mineral Oil (Petroleum) Ingestion liver | immune system Not classified Rat NOAEL 1,336 mg/kg/day 90 days Aspiration Hazard Name Value Hydrotreated Light Petroleum Distillates Aspiration hazard White Mineral Oil (Petroleum) Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information No data available. SECTION 13: Disposal considerations Dispose of contents/ container in accordance with the local/regional/national/international regulations. SECTION 14: Transport Information 3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 10 of 11 For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Global inventory status Contact 3M for more information. The components of this material are in compliance with the provisions of the Korea Chemical Control Act. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the new substance notification requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of TSCA. This product complies with Measures on Environmental Management of New Chemical Substances. All ingredients are listed on or exempt from on China IECSC inventory. Trade Secret Information: HMIRA Registry Number: Filing date: Claim status: Date of decision: 11656 11/07/2017 Claim for exemption has been filed. SECTION 16: Other information National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Health: 2 Flammability: 2 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? IV ratings are to be used with a fully implemented HMIS? IV program. HMIS? is a registered mark of the American Coatings Association (ACA). Document group: 24-5408-0 Version number: 5.02 Issue Date: 2017/07/12 Supercedes Date: 2017/05/18 The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESS OR IMPLIED, STATUTORY OR OTHERWISE, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OR CONDITION OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR ANY IMPLIED WARRANTY OR CONDITION ARISING OUT OF A COURSE OF PERFORMANCE, 3M(TM) Machine Polish, PN 05996 __________________________________________________________________________________________ Page: 11 of 11 COURSE OF DEALING, CUSTOM OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M Canada SDSs are available at www.3M.ca