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3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 1 of 15 Safety Data Sheet Copyright, 2016, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 20-1581-6 Version Number: 3.00 Revision Date: 21/10/2016 Supercedes Date: 03/10/2016 Transportation version number: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 Product Identification Numbers FI-3000-0025-9 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Automotive 1.3. Details of the supplier of the safety data sheet ADDRESS: 3M Israel, 91 Medinat Ha'Yehudim Street, Herzeliya 46120 Telephone: 09-961 5000 E Mail: This email address is being protected from spambots. You need JavaScript enabled to view it. Website: www.3M.com/il 1.4. Emergency telephone number 09-961 5000 SECTION 2: Hazard identification 2.1. Classification of the substance or mixture CLP REGULATION (EC) No 1272/2008 CLASSIFICATION: Serious Eye Damage/Eye Irritation, Category 2 - Eye Irrit. 2; H319 Skin Corrosion/Irritation, Category 2 - Skin Irrit. 2; H315 Respiratory Sensitization, Category 1 - Resp. Sens. 1; H334 Hazardous to the Aquatic Environment (Chronic), Category 3 - Aquatic Chronic 3; H412 For full text of H phrases, see Section 16. 2.2. Label elements CLP REGULATION (EC) No 1272/2008 SIGNAL WORD 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 2 of 15 Danger Symbols: GHS08 (Health Hazard) | Pictograms Ingredients: Ingredient C.A.S. No. % by Wt P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 0.1 - 0.5 HAZARD STATEMENTS: H319 Causes serious eye irritation. H315 Causes skin irritation. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H412 Harmful to aquatic life with long lasting effects. PRECAUTIONARY STATEMENTS Prevention: P261A Avoid breathing vapors. P284A In case of inadequate ventilation wear respiratory protection. Response: P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Disposal: P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 39% of the mixture consists of components of unknown acute oral toxicity. Contains 27% of components with unknown hazards to the aquatic environment. 2.3. Other hazards Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. EU Inventory % by Wt Classification POLYETHER 64298-75-5 NLP 500-159- 0 30 - 60 Substance not classified as hazardous SULFONIC ACIDS, C10-21-ALKANE, PH ESTERS 91082-17-6 293-728-5 15 - 40 Substance not classified as hazardous 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 3 of 15 CARBON BLACK 1333-86-4 215-609-9 10 - 30 Substance with a Community level exposure limit in the workplace Kaolin, calcined 92704-41-1 296-473-8 5 - 15 Substance not classified as hazardous HYDROTREATED LIGHT PETROLEUM DISTILLATES 64742-47-8 265-149-8 1 - 5 **Asp. Tox. 1**, H304 (CLP) **Aquatic Chronic 2**, H411 (Vendor) **Flam. Liq. 3**, H226; **STOT SE 3**, H336; **EUH066**, EUH066 (Self Classified) P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 202-966-0 0.1 - 0.5 **Acute Tox. 4**, H332; **Skin Irrit. 2**, H315; **Eye Irrit. 2**, H319; **Resp. Sens. 1**, H334; **Skin Sens. 1**, H317; **Carc. 2**, H351; **STOT SE 3**, H335; **STOT RE 2**, H373 - Nota 2,C (CLP) 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER 2530-83-8 219-784-2 < 0.2 **Eye Dam. 1**, H318 (Self Classified) DIBUTYLTIN DICHLORIDE 683-18-1 211-670-0 <= 0.1 **Acute Tox. 2**, H330; **Acute Tox. 3**, H301; **Acute Tox. 4**, H312; **Skin Corr. 1B**, H314; **Muta. 2**, H341; **Repr. 1B**, H360FD; **STOT RE 1**, H372; **Aquatic Acute 1**, H400,M=10; **Aquatic Chronic 1**, H410,M=10 (CLP) Please see section 16 for the full text of any H statements referred to in this section For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 4 of 15 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 5.3. Advice for fire-fighters When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Clean up residue. Dispose of collected material as soon as possible. 6.4. Reference to other sections Refer to Section 8 and Section 13 for more information SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing of vapors created during cure cycle. Do not use in a confined area with minimal air exchange. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Keep cool. Protect from sunlight. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. Store away from amines. 7.3. Specific end use(s) See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations. SECTION 8: Exposure controls/personal protection 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 5 of 15 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments P,P'- METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 ACGIH TWA:0.005 ppm FREE ISOCYANATES 101-68-8 Manufacturer determined TWA:0.005 ppm;STEL:0.02 ppm CARBON BLACK 1333-86-4 ACGIH TWA(inhalable fraction):3 mg/m3 A3: Confirmed animal carcin. ACGIH : American Conference of Governmental Industrial Hygienists CMRG : Chemical Manufacturer's Recommended Guidelines TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide ventilated enclosure for heat curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Nitrile Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 6 of 15 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Solid Specific Physical Form: Paste Appearance/Odor Slight odor; Thick, black paste Odor threshold No Data Available pH Not Applicable Boiling point/boiling range >= 192 ?C Melting point No Data Available Flammability (solid, gas) Not Classified Explosive properties: Not Classified Oxidising properties: Not Classified Flash Point >= 70 ?C [Test Method: Closed Cup] Autoignition temperature >= 200 ?C Flammable Limits(LEL) 0.6 % volume Flammable Limits(UEL) 7 % volume Vapor Pressure No Data Available Relative Density 1.2 [Ref Std: WATER=1] Water solubility Negligible Solubility- non-water No Data Available Vapor Density 6 [Ref Std: AIR=1] Decomposition temperature No Data Available Density 1.2 g/cm3 [@ 20 ?C ] 9.2. Other information Percent volatile 2.5 % SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Accelerators Al or Mg powder and high/shear temperature conditions Alcohols Alkali and alkaline earth metals Amines Strong acids Strong bases Strong oxidizing agents Water 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 7 of 15 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified Carbon dioxide Not Specified Hydrogen Cyanide Not Specified Oxides of Nitrogen Not Specified SECTION 11: Toxicological information The information below may not agree with the EU material classification in Section 2 and/or the ingredient classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition, statements and data presented in Section 11 are based on UN GHS calculation rules and classifications derived from 3M assessments. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Additional Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 8 of 15 SULFONIC ACIDS, C10-21-ALKANE, PH ESTERS Dermal Rat LD50 > 1,055 mg/kg SULFONIC ACIDS, C10-21-ALKANE, PH ESTERS Ingestion Rat LD50 > 15,825 mg/kg CARBON BLACK Dermal Rabbit LD50 > 3,000 mg/kg CARBON BLACK Ingestion Rat LD50 > 8,000 mg/kg Kaolin, calcined Dermal LD50 estimated to be 2,000 - 5,000 mg/kg Kaolin, calcined Ingestion Rat LD50 > 2,000 mg/kg HYDROTREATED LIGHT PETROLEUM DISTILLATES Dermal Rabbit LD50 > 3,160 mg/kg HYDROTREATED LIGHT PETROLEUM DISTILLATES Inhalation- Dust/Mist (4 hours) Rat LC50 > 3 mg/l HYDROTREATED LIGHT PETROLEUM DISTILLATES Ingestion Rat LD50 > 5,000 mg/kg P,P'-METHYLENEBIS(PHENYL ISOCYANATE) Dermal Rabbit LD50 > 5,000 mg/kg P,P'-METHYLENEBIS(PHENYL ISOCYANATE) Inhalation- Dust/Mist (4 hours) Rat LC50 0.368 mg/l P,P'-METHYLENEBIS(PHENYL ISOCYANATE) Ingestion Rat LD50 31,600 mg/kg 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Dermal Rabbit LD50 4,000 mg/kg 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.3 mg/l 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Ingestion Rat LD50 7,010 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value SULFONIC ACIDS, C10-21-ALKANE, PH ESTERS Human and animal No significant irritation CARBON BLACK Rabbit No significant irritation HYDROTREATED LIGHT PETROLEUM DISTILLATES Rabbit Mild irritant P,P'-METHYLENEBIS(PHENYL ISOCYANATE) official classificat ion Irritant 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value SULFONIC ACIDS, C10-21-ALKANE, PH ESTERS Rabbit No significant irritation CARBON BLACK Rabbit No significant irritation HYDROTREATED LIGHT PETROLEUM DISTILLATES Rabbit Mild irritant P,P'-METHYLENEBIS(PHENYL ISOCYANATE) official classificat ion Severe irritant 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Rabbit Corrosive Skin Sensitization Name Species Value HYDROTREATED LIGHT PETROLEUM DISTILLATES Guinea pig Not sensitizing P,P'-METHYLENEBIS(PHENYL ISOCYANATE) official classificat ion Sensitizing 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Guinea pig Some positive data exist, but the data are not sufficient for classification Respiratory Sensitization Name Species Value P,P'-METHYLENEBIS(PHENYL ISOCYANATE) Human Sensitizing 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 9 of 15 Germ Cell Mutagenicity Name Route Value SULFONIC ACIDS, C10-21-ALKANE, PH ESTERS In Vitro Not mutagenic CARBON BLACK In Vitro Not mutagenic CARBON BLACK In vivo Some positive data exist, but the data are not sufficient for classification HYDROTREATED LIGHT PETROLEUM DISTILLATES In Vitro Not mutagenic P,P'-METHYLENEBIS(PHENYL ISOCYANATE) In Vitro Some positive data exist, but the data are not sufficient for classification 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER In vivo Not mutagenic 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value CARBON BLACK Dermal Mouse Not carcinogenic CARBON BLACK Ingestion Mouse Not carcinogenic CARBON BLACK Inhalation Rat Carcinogenic HYDROTREATED LIGHT PETROLEUM DISTILLATES Dermal Mouse Some positive data exist, but the data are not sufficient for classification P,P'-METHYLENEBIS(PHENYL ISOCYANATE) Inhalation Rat Some positive data exist, but the data are not sufficient for classification 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Dermal Mouse Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration SULFONIC ACIDS, C10-21-ALKANE, PH ESTERS Ingestion Not toxic to female reproduction Rat NOAEL 530 mg/kg/day 1 generation SULFONIC ACIDS, C10-21-ALKANE, PH ESTERS Ingestion Not toxic to development Rat NOAEL 530 mg/kg/day 1 generation P,P'-METHYLENEBIS(PHENYL ISOCYANATE) Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 0.004 mg/l during organogenesis 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Ingestion Not toxic to female reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Ingestion Not toxic to male reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(TRIMETHOXYSILYL)PROPYL GLYCIDYL ETHER Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 3,000 mg/kg/day during organogenesis Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration HYDROTREATED LIGHT PETROLEUM DISTILLATES Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available HYDROTREATED LIGHT PETROLEUM DISTILLATES Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available HYDROTREATED LIGHT PETROLEUM DISTILLATES Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Notavailable P,P'- METHYLENEBIS(PHEN Inhalation respiratory irritation May cause respiratory irritation official classifica NOAEL Not available 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 10 of 15 YL ISOCYANATE) tion Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration SULFONIC ACIDS, C10- 21-ALKANE, PH ESTERS Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,490 mg/kg/day 90 days CARBON BLACK Inhalation pneumoconiosis Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure P,P'- METHYLENEBIS(PHEN YL ISOCYANATE) Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks 3- (TRIMETHOXYSILYL)P ROPYL GLYCIDYL ETHER Ingestion heart | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | nervous system | kidney and/or bladder | respiratory system All data are negative Rat NOAEL 1,000 mg/kg/day 28 days Aspiration Hazard Name Value HYDROTREATED LIGHT PETROLEUM DISTILLATES Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information The information below may not agree with the EU material classification in Section 2 and/or the ingredient classifications in Section 3 if specific ingredient classifications are mandated by a competent authority. In addition, statements and data presented in Section 12 are based on UN GHS calculation rules and classifications derived from 3M assessments. 12.1. Toxicity No product test data available Material Cas # Organism Type Exposure Test Endpoint Test Result SULFONIC ACIDS, C10- 21-ALKANE, PH ESTERS 91082-17-6 Data not available or insufficient for classification HYDROTREA TED LIGHT PETROLEUM DISTILLATES 64742-47-8 Data not available or insufficient for classification CARBON BLACK 1333-86-4 Data not available or insufficient for classification 3- (TRIMETHOX YSILYL)PRO 2530-83-8 Water flea Experimental 48 hours Effect Concentration 50% 473 mg/l 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 11 of 15 PYL GLYCIDYL ETHER 3- (TRIMETHOX YSILYL)PRO PYL GLYCIDYL ETHER 2530-83-8 Green algae Experimental 96 hours Effect Concentration 50% 350 mg/l 3- (TRIMETHOX YSILYL)PRO PYL GLYCIDYL ETHER 2530-83-8 Common Carp Experimental 96 hours Lethal Concentration 50% 55 mg/l 3- (TRIMETHOX YSILYL)PRO PYL GLYCIDYL ETHER 2530-83-8 Green algae Experimental 96 hours No obs Effect Conc 130 mg/l 3- (TRIMETHOX YSILYL)PRO PYL GLYCIDYL ETHER 2530-83-8 Water flea Experimental 21 days No obs Effect Conc >=100 mg/l P,P'- METHYLENE BIS(PHENYL ISOCYANAT E) 101-68-8 Data not available or insufficient for classification Kaolin, calcined 92704-41-1 Data not available or insufficient for classification DIBUTYLTIN DICHLORIDE 683-18-1 Algae Experimental 96 hours Effect Concentration 50% 0.043 mg/l DIBUTYLTIN DICHLORIDE 683-18-1 Water flea Experimental 48 hours Effect Concentration 50% 0.84 mg/l DIBUTYLTIN DICHLORIDE 683-18-1 Water flea Experimental 21 days No obs Effect Conc 0.015 mg/l DIBUTYLTIN DICHLORIDE 683-18-1 Ricefish Experimental 28 days No obs Effect Conc 1.8 mg/l POLYETHER 64298-75-5 Data not available or insufficient for classification 12.2. Persistence and degradability Material CAS No. Test Type Duration Study Type Test Result Protocol P,P'- 101-68-8 Experimental Hydrolytic <2 hours (t 1/2) Other methods 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 12 of 15 METHYLENE BIS(PHENYL ISOCYANAT E) Hydrolysis half-life 3- (TRIMETHOX YSILYL)PRO PYL GLYCIDYL ETHER 2530-83-8 Experimental Hydrolysis Hydrolytic half-life 6.5 hours (t 1/2) Other methods POLYETHER 64298-75-5 Data not available or insufficient for classification N/A N/A N/A N/A Kaolin, calcined 92704-41-1 Data not available or insufficient for classification N/A N/A N/A N/A HYDROTREA TED LIGHT PETROLEUM DISTILLATES 64742-47-8 Data not available or insufficient for classification N/A N/A N/A N/A CARBON BLACK 1333-86-4 Data not available or insufficient for classification N/A N/A N/A N/A SULFONIC ACIDS, C10- 21-ALKANE, PH ESTERS 91082-17-6 Data not available or insufficient for classification N/A N/A N/A N/A 3- (TRIMETHOX YSILYL)PRO PYL GLYCIDYL ETHER 2530-83-8 Experimental Biodegradation 28 days Dissolv. Organic Carbon Deplet 37 % weight Other methods P,P'- METHYLENE BIS(PHENYL ISOCYANAT E) 101-68-8 Experimental Biodegradation 28 days Biological Oxygen Demand 0 % weight OECD 301C - MITI (I) DIBUTYLTIN DICHLORIDE 683-18-1 Modeled Photolysis Photolytic half- life (in air) 12.7 hours (t 1/2) Other methods DIBUTYLTIN DICHLORIDE 683-18-1 Experimental Biodegradation 28 days Carbon dioxide evolution 5.5 % weight OECD 301B - Mod. Sturm or CO2 12.3. Bioaccumulative potential Material CAS No. Test Type Duration Study Type Test Result Protocol 3- (TRIMETHOX YSILYL)PRO PYL GLYCIDYL ETHER 2530-83-8 Data not available or insufficient for classification N/A N/A N/A N/A 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 13 of 15 HYDROTREA TED LIGHT PETROLEUM DISTILLATES 64742-47-8 Data not available or insufficient for classification N/A N/A N/A N/A CARBON BLACK 1333-86-4 Data not available or insufficient for classification N/A N/A N/A N/A POLYETHER 64298-75-5 Data not available or insufficient for classification N/A N/A N/A N/A Kaolin, calcined 92704-41-1 Data not available or insufficient for classification N/A N/A N/A N/A SULFONIC ACIDS, C10- 21-ALKANE, PH ESTERS 91082-17-6 Data not available or insufficient for classification N/A N/A N/A N/A P,P'- METHYLENE BIS(PHENYL ISOCYANAT E) 101-68-8 Experimental BCF-Carp 28 days Bioaccumulatio n Factor 200 Other methods DIBUTYLTIN DICHLORIDE 683-18-1 Data not available or insufficient for classification N/A N/A N/A N/A 12.4. Mobility in soil Please contact manufacturer for more details 12.5. Results of the PBT and vPvB assessment No information available at this time, contact manufacturer for more details 12.6. Other adverse effects No information available SECTION 13: Disposal considerations 13.1 Waste treatment methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of 3M, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC - 2000/532/CE 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 14 of 15 and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor EU waste code (product as sold) 080409* Waste adhesives and sealants containing organic solvents or other dangerous substances 200127* Paint, inks, adhesives and resins containing dangerous substances SECTION 14: Transportation information ADR/IMDG/IATA: Not hazardous for transport SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Carcinogenicity Ingredient C.A.S. No. Classification Regulation CARBON BLACK 1333-86-4 Grp. 2B: Possible human carc. International Agency for Research on Cancer P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 Carc. 2 Regulation (EC) No. 1272/2008, Table 3.1 P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 Gr. 3: Not classifiable International Agency for Research on Cancer Global inventory status Contact 3M for more information. SECTION 16: Other information List of relevant H statements EUH066 Repeated exposure may cause skin dryness or cracking. H226 Flammable liquid and vapor. H301 Toxic if swallowed. H304 May be fatal if swallowed and enters airways. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H330 Fatal if inhaled. H332 Harmful if inhaled. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H341 Suspected of causing genetic defects. H351 Suspected of causing cancer. H360FD May damage fertility. May damage the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H373 May cause damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. 3M(TM) Fast Cure Glass Adhesive P/N 08613, 08628, 08629 __________________________________________________________________________________________ Page: 15 of 15 H412 Harmful to aquatic life with long lasting effects. Revision information: Section 03: Composition/ Information of ingredients table information was modified. Section 08: Occupational exposure limit table information was modified. Section 11: Acute Toxicity table information was modified. Section 11: Carcinogenicity Table information was modified. Section 11: Germ Cell Mutagenicity Table information was modified. Section 11: Serious Eye Damage/Irritation Table information was modified. Section 11: Skin Corrosion/Irritation Table information was modified. Section 11: Target Organs - Repeated Table information was modified. Section 12: Component ecotoxicity information information was modified. Section 12: Persistence and Degradability information information was modified. Section 12:Bioccumulative potential information information was modified. Section 15: Carcinogenicity information information was modified. DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications. 3M Israel SDSs are available at www.3M.com/il