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3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 1 of 13 Safety Data Sheet Copyright,2016,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 07-3626-4 Version Number: 9.01 Issue Date: 02/02/16 Supercedes Date: 03/18/15 SECTION 1: Identification 1.1. Product identifier 3M? MSP Seam Sealer ? White, PN 08369 Product Identification Numbers 60-4550-5013-2, 60-9800-2682-1, 60-9800-2687-0, 60-9800-3611-9 1.2. Recommended use and restrictions on use Recommended use Automotive, Seam Sealer 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Skin Sensitizer: Category 1. Reproductive Toxicity: Category 1B. Carcinogenicity: Category 1A. 2.2. Label elements Signal word Danger Symbols Exclamation mark | Health Hazard | 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 2 of 13 Pictograms Hazard Statements May cause an allergic skin reaction. May damage fertility or the unborn child. May cause cancer. Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves. Contaminated work clothing must not be allowed out of the workplace. Response: IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified None. 8% of the mixture consists of ingredients of unknown acute dermal toxicity. 97% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Limestone 1317-65-3 15 - 40 Trade Secret * Calcium Carbonate 471-34-1 10 - 30 Trade Secret * Silyl Terminated Polyether NJ Trade Secret Registry No. 04499600-6009P Trade Secret* 10 - 30 Trade Secret * Plasticizer - NJ Trade Secret Registry No. 04499600- 5988P Trade Secret* 7 - 13 Trade Secret * Diisodecyl Phthalate 68515-49-1 1 - 5 Trade Secret * Hydrotreated Heavy Naphtha (Petroleum) 64742-48-9 1 - 5 Trade Secret * Stearic Acid 57-11-4 0.5 - 5 Trade Secret * 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- 1760-24-3 < 1 Trade Secret * 1-Methyl-2-Pyrrolidinone 872-50-4 < 1 Trade Secret * 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 3 of 13 Dibutyltin bis(acetylacetonate) 22673-19-4 < 1 Trade Secret * Quartz Silica 14808-60-7 < 0.5 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 4 of 13 information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store away from heat. Store away from acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Limestone 1317-65-3 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Quartz Silica 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Quartz Silica 14808-60-7 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.) TIN, ORGANIC COMPOUNDS 22673-19-4 ACGIH TWA(as Sn):0.1 mg/m3;STEL(as Sn):0.2 mg/m3 A4: Not class. as human carcin, Skin Notation TIN, ORGANIC COMPOUNDS 22673-19-4 OSHA TWA(as Sn):0.1 mg/m3 Calcium Carbonate 471-34-1 CMRG TWA:10 mg/m3;STEL:20 mg/m3 Limestone 471-34-1 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 STEARATES 57-11-4 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Hydrotreated Heavy Naphtha (Petroleum) 64742-48-9 Manufacturer determined TWA:100 ppm Naphtha 64742-48-9 OSHA TWA:400 mg/m3(100 ppm) Diisodecyl Phthalate 68515-49-1 CMRG TWA:5 mg/m3 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 5 of 13 1-Methyl-2-Pyrrolidinone 872-50-4 AIHA TWA:40 mg/m3(10 ppm) Skin Notation ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection None required. Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Solid Specific Physical Form: Paste Odor, Color, Grade: White thick paste Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point No boiling point Flash Point No flash point Evaporation rate No Data Available Flammability (solid, gas) Not Classified Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure Not Applicable 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 6 of 13 Vapor Density Not Applicable Density 1.68 g/cm3 Specific Gravity 1.68 [Ref Std: WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 15,000 - 20,000 poise [Test Method: Brookfield] [Details: CONDITIONS: Spindle #7, 2 rpm] Hazardous Air Pollutants 0.0009 lb HAPS/lb solids [Test Method: Calculated] Molecular weight No Data Available Volatile Organic Compounds 100 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 6 % weight [Test Method: calculated per CARB title 2] Percent volatile 6 % weight VOC Less H2O & Exempt Solvents 100 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Strong acids 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 7 of 13 Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. May cause additional health effects (see below). Eye Contact: Contact with the eyes during product use is not expected to result in significant irritation. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation SILICA, CRYS AIRRESP 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Additional Information: This product contains a form of crystalline silica. Occupational exposure to inhaled crystalline silica has been associated with silicosis and lung cancer. No exposure to crystalline silica is expected during the normal handling and use of this product. Therefore, the health effects associated with crystalline silica are not expected during normal use of this product. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE > 5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE 20 - 50 mg/l Overall product Ingestion No data available; calculated ATE 2,000 - 5,000 mg/kg Limestone Dermal Rat LD50 > 2,000 mg/kg Limestone Inhalation- Dust/Mist (4 hours) Rat LC50 3 mg/l Limestone Ingestion Rat LD50 6,450 mg/kg Calcium Carbonate Dermal Rat LD50 > 2,000 mg/kg 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 8 of 13 Calcium Carbonate Inhalation- Dust/Mist (4 hours) Rat LC50 3 mg/l Calcium Carbonate Ingestion Rat LD50 6,450 mg/kg Silyl Terminated Polyether NJ Trade Secret Registry No. 04499600-6009P Dermal LD50 estimated to be > 5,000 mg/kg Silyl Terminated Polyether NJ Trade Secret Registry No. 04499600-6009P Ingestion Rat LD50 > 20,000 mg/kg Plasticizer - NJ Trade Secret Registry No. 04499600-5988P Dermal Rabbit LD50 > 5,000 mg/kg Plasticizer - NJ Trade Secret Registry No. 04499600-5988P Ingestion similar compoun ds LD50 estimated to be 300 - 2,000 mg/kg Hydrotreated Heavy Naphtha (Petroleum) Inhalation- Vapor LC50 estimated to be 20 - 50 mg/l Hydrotreated Heavy Naphtha (Petroleum) Dermal Rabbit LD50 > 3,000 mg/kg Hydrotreated Heavy Naphtha (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg Diisodecyl Phthalate Dermal Rabbit LD50 > 3,160 mg/kg Diisodecyl Phthalate Inhalation- Dust/Mist (4 hours) Rat LC50 > 12.5 mg/l Diisodecyl Phthalate Ingestion Rat LD50 > 9,700 mg/kg Stearic Acid Dermal Rabbit LD50 > 2,000 mg/kg Stearic Acid Ingestion Rat LD50 > 5,000 mg/kg 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- Dermal Rabbit LD50 > 2,000 mg/kg 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- Inhalation- Dust/Mist (4 hours) Rat LC50 >1.49, <2.44 mg/l 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- Ingestion Rat LD50 1,897 mg/kg 1-Methyl-2-Pyrrolidinone Dermal Rabbit LD50 4,000 mg/kg 1-Methyl-2-Pyrrolidinone Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.1 mg/l 1-Methyl-2-Pyrrolidinone Ingestion Rat LD50 4,320 mg/kg Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg Dibutyltin bis(acetylacetonate) Dermal Rat LD50 > 2,000 mg/kg Dibutyltin bis(acetylacetonate) Ingestion Rat LD50 1,864 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Limestone Rabbit No significant irritation Calcium Carbonate Rabbit No significant irritation Hydrotreated Heavy Naphtha (Petroleum) Rabbit Irritant Diisodecyl Phthalate Rabbit Minimal irritation Stearic Acid Rabbit Mild irritant 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- Rabbit Mild irritant 1-Methyl-2-Pyrrolidinone Rabbit Minimal irritation Quartz Silica Professio nal judgeme nt No significant irritation Dibutyltin bis(acetylacetonate) Rat Corrosive Serious Eye Damage/Irritation Name Species Value Limestone Rabbit No significant irritation Calcium Carbonate Rabbit No significant irritation Hydrotreated Heavy Naphtha (Petroleum) Rabbit No significant irritation Diisodecyl Phthalate Rabbit Mild irritant Stearic Acid Professio nal Moderate irritant 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 9 of 13 judgeme nt 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- Rabbit Corrosive 1-Methyl-2-Pyrrolidinone Rabbit Severe irritant Dibutyltin bis(acetylacetonate) In vitro data Corrosive Skin Sensitization Name Species Value Hydrotreated Heavy Naphtha (Petroleum) Guinea pig Not sensitizing Diisodecyl Phthalate Guinea pig Some positive data exist, but the data are not sufficient for classification 1,2-Ethanediamine, N1-[3-(trimethoxysilyl)propyl]- Multiple animal species Sensitizing 1-Methyl-2-Pyrrolidinone Human and animal Not sensitizing Dibutyltin bis(acetylacetonate) Guinea pig Sensitizing Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Hydrotreated Heavy Naphtha (Petroleum) In vivo Not mutagenic Hydrotreated Heavy Naphtha (Petroleum) In Vitro Some positive data exist, but the data are not sufficient for classification Diisodecyl Phthalate In Vitro Not mutagenic Diisodecyl Phthalate In vivo Not mutagenic Stearic Acid In Vitro Not mutagenic 1-Methyl-2-Pyrrolidinone In vivo Not mutagenic 1-Methyl-2-Pyrrolidinone In Vitro Some positive data exist, but the data are not sufficient for classification Quartz Silica In Vitro Some positive data exist, but the data are not sufficient for classification Quartz Silica In vivo Some positive data exist, but the data are not sufficient for classification Dibutyltin bis(acetylacetonate) In Vitro Some positive data exist, but the data are not sufficient for classification Dibutyltin bis(acetylacetonate) In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Hydrotreated Heavy Naphtha (Petroleum) Dermal Mouse Some positive data exist, but the data are not sufficient for classification Hydrotreated Heavy Naphtha (Petroleum) Inhalation Human and animal Some positive data exist, but the data are not sufficient for classification Stearic Acid Ingestion Rat Not carcinogenic 1-Methyl-2-Pyrrolidinone Inhalation Rat Not carcinogenic Quartz Silica Inhalation Human and animal Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 10 of 13 Limestone Ingestion Not toxic to development Rat NOAEL 625 mg/kg/day premating & during gestation Calcium Carbonate Ingestion Not toxic to development Rat NOAEL 625 mg/kg/day premating & during gestation Hydrotreated Heavy Naphtha (Petroleum) Inhalation Not toxic to development Rat NOAEL 2.4 mg/l during organogenesi s Diisodecyl Phthalate Ingestion Not toxic to female reproduction Rat NOAEL 927 mg/kg/day 2 generation Diisodecyl Phthalate Ingestion Not toxic to male reproduction Rat NOAEL 929 mg/kg/day 2 generation Diisodecyl Phthalate Ingestion Toxic to development Rat NOAEL 38 mg/kg/day 2 generation 1-Methyl-2-Pyrrolidinone Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat LOAEL 0.68 mg/l during gestation 1-Methyl-2-Pyrrolidinone Ingestion Toxic to female reproduction Rat LOAEL 50 mg/kg/day 2 generation 1-Methyl-2-Pyrrolidinone Ingestion Toxic to male reproduction Rat LOAEL 50 mg/kg/day 2 generation 1-Methyl-2-Pyrrolidinone Dermal Toxic to development Rat NOAEL 237 mg/kg/day during organogenesi s 1-Methyl-2-Pyrrolidinone Ingestion Toxic to development Rat NOAEL 160 mg/kg/day 2 generation Dibutyltin bis(acetylacetonate) Ingestion Toxic to female reproduction Rat NOAEL 2 mg/kg/day premating into lactation Dibutyltin bis(acetylacetonate) Ingestion Toxic to development Rat NOAEL 2.5 mg/kg/day during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Limestone Inhalation respiratory system All data are negative Rat NOAEL 0.812 mg/l 90 minutes Calcium Carbonate Inhalation respiratory system All data are negative Rat NOAEL 0.812 mg/l 90 minutes Hydrotreated Heavy Naphtha (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Heavy Naphtha (Petroleum) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hydrotreated Heavy Naphtha (Petroleum) Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Dog NOAEL 6.5 mg/l 4 hours Hydrotreated Heavy Naphtha (Petroleum) Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Stearic Acid Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available 1,2-Ethanediamine, N1-[3- (trimethoxysilyl)propyl]- Inhalation respiratory irritation May cause respiratory irritation similar health hazards NOAEL Not available 1-Methyl-2-Pyrrolidinone Inhalation respiratory irritation All data are negative Human NOAEL 0.05 mg/l 8 hours Dibutyltin bis(acetylacetonate) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification similar health hazards NOAEL Not available 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 11 of 13 Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Limestone Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Calcium Carbonate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available occupational exposure Hydrotreated Heavy Naphtha (Petroleum) Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 4.6 mg/l 6 months Hydrotreated Heavy Naphtha (Petroleum) Inhalation kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 1.9 mg/l 13 weeks Hydrotreated Heavy Naphtha (Petroleum) Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL 0.6 mg/l 90 days Hydrotreated Heavy Naphtha (Petroleum) Inhalation bone, teeth, nails, and/or hair | blood | liver | muscles All data are negative Rat NOAEL 5.6 mg/l 12 weeks Hydrotreated Heavy Naphtha (Petroleum) Inhalation heart All data are negative Multiple animal species NOAEL 1.3 mg/l 90 days Diisodecyl Phthalate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.5 mg/l 2 weeks Diisodecyl Phthalate Inhalation hematopoietic system | liver All data are negative Rat NOAEL 0.5 mg/l 2 weeks Diisodecyl Phthalate Inhalation kidney and/or bladder All data are negative Rat NOAEL 0.5 mg/l 2 generation Diisodecyl Phthalate Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 686 mg/kg/day 90 days Diisodecyl Phthalate Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 500 mg/kg/day 90 days Diisodecyl Phthalate Ingestion heart All data are negative Rat NOAEL 500 mg/kg/day 90 days Diisodecyl Phthalate Ingestion hematopoietic system All data are negative Dog NOAEL 320 mg/kg/day 90 days Stearic Acid Ingestion blood Some positive data exist, but the data are not sufficient for classification Rat NOAEL Not available 6 weeks 1-Methyl-2-Pyrrolidinone Inhalation bone marrow | immune system | respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.5 mg/l 4 weeks 1-Methyl-2-Pyrrolidinone Ingestion endocrine system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 250 mg/kg/day 90 days 1-Methyl-2-Pyrrolidinone Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 2,060 mg/kg/day 4 weeks 1-Methyl-2-Pyrrolidinone Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,057 mg/kg/day 90 days 1-Methyl-2-Pyrrolidinone Ingestion hematopoietic system Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 300 mg/kg/day 90 days 1-Methyl-2-Pyrrolidinone Ingestion liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 150 mg/kg/day 3 months Quartz Silica Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Dibutyltin bis(acetylacetonate) Ingestion immune system Causes damage to organs through prolonged or repeated exposure Rat NOAEL 0.3 mg/kg/day 28 days 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 12 of 13 Aspiration Hazard Name Value Hydrotreated Heavy Naphtha (Petroleum) Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Classification SILICA, CRYSTALLINE (AIRBORNE PARTICLES OF RESPIRABLE SIZE) None Carcinogen Diisodecyl Phthalate 68515-49-1 Developmental Toxin 1-Methyl-2-Pyrrolidinone 872-50-4 Developmental Toxin 3M? MSP Seam Sealer ? White, PN 08369 02/02/16 __________________________________________________________________________________________ Page 13 of 13 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. WARNING: This product contains a chemical known to the State of California to cause cancer. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: *2 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? IV ratings are to be used with a fully implemented HMIS? IV program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 07-3626-4 Version Number: 9.01 Issue Date: 02/02/16 Supercedes Date: 03/18/15 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com