3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 1 of 16 Safety Data Sheet Copyright,2015,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document group: 16-2711-6 Version number: 6.00 Issue Date: 09/09/2015 Supersedes date: 09/07/2012 This Safety Data Sheet has been prepared in accordance with the Preparation of Safety Data Sheets for Hazardous Chemicals Code of Practice (Safe Work Australia, December 2011) SECTION 1: Identification 1.1. Product identifier 3M? Scuff-It? Paint Prep Gel, PN 06013 Product Identification Numbers 60-9800-4294-3 1.2. Recommended use and restrictions on use Recommended use Automotive., Preparation of automotive substrates prior to painting For Industrial or Professional use only. 1.3. Supplier?s details Address: 3M Australia - Building A, 1 Rivett Road, North Ryde NSW 2113 Telephone: 136 136 E Mail: This email address is being protected from spambots. You need JavaScript enabled to view it. Website: www.3m.com.au 1.4. Emergency telephone number EMERGENCY: 1800 097 146 (Australia only) SECTION 2: Hazard identification This product is classified as a hazardous chemical according to the Model Work Health and Safety Regulations, 2011. Refer to Section 14 of this Safety Data Sheets for product Dangerous Goods Classification. 2.1. Classification of the substance or mixture Serious Eye Damage/Irritation: Category 2. Skin Sensitizer: Category 1. Carcinogenicity: Category 1A. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements The label elements below were prepared in accordance with the Code of Practice on Preparation of Safety Data Sheets for 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 2 of 16 Hazardous Chemicals (Safe Work Australia, December 2011). This information may be different from the actual product label. Signal word DANGER! Symbols Exclamation mark | Health Hazard | Pictograms Hazard statements H319 Causes serious eye irritation. H317 May cause an allergic skin reaction. H350 May cause cancer. H372 Causes damage to organs through prolonged or repeated exposure: respiratory system | Precautionary statements Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P280A Wear eye/face protection. P280E Wear protective gloves. P281 Use personal protective equipment as required. P270 Do not eat, drink or smoke when using this product. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. Response: P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. P308 + P313 IF exposed or concerned: Get medical advice/attention. P321 Specific treatment (see Notes to Physician on this label). P314 Get medical advice/attention if you feel unwell. Storage: P405 Store locked up. Disposal: P501 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 3 of 16 2.3. Other assigned/identified product hazards None known. 2.4. Other hazards which do not result in classification Toxic to aquatic life. Harmful to aquatic life with long lasting effects. SECTION 3: Composition/information on ingredients This material is a mixture. Ingredient CAS Nbr % by Weight Feldspars 68476-25-5 30 - 60 Water 7732-18-5 15 - 40 Quartz 14808-60-7 10 - 30 Polyethylene Glycol 25322-68-3 3 - 7 Glycerin 56-81-5 1 - 5 (R)-p-mentha-1,8-diene 5989-27-5 1 - 5 Ethoxylated C12-C15 Alcohols 68131-39-5 0.5 - 1.5 Diethanolamine 111-42-2 0.01 1,2-Benzisothiazolin-3-One 2634-33-5 < 0.01 SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Remove person to fresh air. If you feel unwell, get medical attention. Skin contact Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye contact Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 4 of 16 Substance Condition Hydrocarbons. During combustion. Carbon monoxide. During combustion. Carbon dioxide. During combustion. 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with detergent and water. Seal the container. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Use personal protective equipment (eg. gloves, respirators?) as required. 7.2. Conditions for safe storage including any incompatibilities No special storage requirements. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient CAS Nbr Agency Limit type Additional comments Diethanolamine 111-42-2 ACGIH TWA(inhalable fraction and vapour):1 mg/m3 A3: Confirmed animal carcin., Skin Notation Diethanolamine 111-42-2 Australia OELs TWA(8 hours): 13 mg/m3 (3 ppm) Quartz 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Quartz 14808-60-7 Australia OELs TWA(8 hours):0.1 mg/m3;Limit value not 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 5 of 16 established: Polyethylene Glycol 25322-68-3 AIHA TWA(as particulate):10 mg/m3 Glycerin 56-81-5 Australia OELs TWA(Inspirable dust)(8 hours):10 mg/m3 Cyclohexene, 1-methyl-4-(1- methylethenyl)- 5989-27-5 AIHA TWA:165.5 mg/m3(30 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association Australia OELs : Australia. Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment CMRG : Chemical Manufacturer's Recommended Guidelines TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling Sen: Sensitiser Sk: Absorption through the skin may be a significant source of exposure. 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect vented goggles. Select and use eye protection in accordance with AS/NZS 1336. Eye protection should comply with the performance specifications of AS/NZS 1337. Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Nitrile rubber. if this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Nitrile Select and use gloves according to AS/NZ 2161. Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for particulates. For questions about suitability for a specific application, consult with your respirator manufacturer. Select and use respirators according to AS/NZS 1715. Respirators should comply with AS/NZS 1716 performance specifications. For information about respirators, call 3M on 1800 024 464. 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 6 of 16 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Liquid. Specific Physical Form: Paste Appearance/Odour Citrus odour thick white paste pH 8 Melting point/Freezing point No data available. Boiling point/Initial boiling point/Boiling range >=100 ?C Flash point >=93.9 ?C [Test Method:Closed Cup] Evaporation rate No data available. Flammability (solid, gas) Not applicable. Flammable Limits(LEL) No data available. Flammable Limits(UEL) No data available. Vapour pressure No data available. Vapour density No data available. Density 1.55 g/ml Relative density 1.55 [Ref Std:WATER=1] Water solubility Moderate Autoignition temperature No data available. Viscosity ? 150 Pa-s Volatile organic compounds (VOC) 2.1 % weight [Test Method:calculated per CARB title 2] Volatile organic compounds (VOC) 41 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 31.3 % weight VOC less H2O & exempt solvents 73 g/l [Test Method:calculated SCAQMD rule 443.1] Solids content 60.73 % weight SECTION 10: Stability and reactivity 10.1 Reactivity This material is considered to be non reactive under normal use conditions 10.2 Chemical stability Stable. 10.3. Conditions to avoid None known. 10.4. Possibility of hazardous reactions Hazardous polymerisation will not occur. 10.5 Incompatible materials None known. 10.6 Hazardous decomposition products Substance Condition None known. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 7 of 16 reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1 Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation May cause additional health effects (see below). Skin contact Allergic skin reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye contact Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. Additional Health Effects: Prolonged or repeated exposure may cause target organ effects: Silicosis: Signs/symptoms may include breathlessness, weakness, chest pain, persistent cough, increased amounts of sputum, and heart disease. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Feldspars Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Quartz Dermal LD50 estimated to be > 5,000 mg/kg Quartz Ingestion LD50 estimated to be > 5,000 mg/kg Polyethylene Glycol Dermal Rabbit LD50 > 20,000 mg/kg Polyethylene Glycol Ingestion Rat LD50 32,770 mg/kg (R)-p-mentha-1,8-diene Inhalation-Vapour (4 hours) Mouse LC50 > 3.14 mg/l (R)-p-mentha-1,8-diene Dermal Rabbit LD50 > 5,000 mg/kg (R)-p-mentha-1,8-diene Ingestion Rat LD50 4,400 mg/kg Glycerin Dermal Rabbit LD50 estimated to be > 5,000 mg/kg Glycerin Ingestion Rat LD50 > 5,000 mg/kg Ethoxylated C12-C15 Alcohols Dermal Rat LD50 5,000 mg/kg Ethoxylated C12-C15 Alcohols Ingestion Rat LD50 1,200 mg/kg Diethanolamine Dermal Rabbit LD50 8,180 mg/kg Diethanolamine Ingestion Rat LD50 1,410 mg/kg ATE = acute toxicity estimate 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 8 of 16 Skin Corrosion/Irritation Name Species Value Feldspars Professional judgement No significant irritation Quartz Professional judgement No significant irritation Polyethylene Glycol Rabbit Minimal irritation (R)-p-mentha-1,8-diene Rabbit Mild irritant Glycerin Rabbit No significant irritation Diethanolamine Rabbit Mild irritant Serious Eye Damage/Irritation Name Species Value Polyethylene Glycol Rabbit Mild irritant (R)-p-mentha-1,8-diene Rabbit Mild irritant Glycerin Rabbit No significant irritation Ethoxylated C12-C15 Alcohols Not available Corrosive Diethanolamine Rabbit Severe irritant Skin Sensitisation Name Species Value Polyethylene Glycol Guinea pig Not sensitizing (R)-p-mentha-1,8-diene Mouse Sensitising Glycerin Guinea pig Not sensitizing Diethanolamine Human and animal Not sensitizing Respiratory Sensitisation For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Quartz In Vitro Some positive data exist, but the data are not sufficient for classification Quartz In vivo Some positive data exist, but the data are not sufficient for classification Polyethylene Glycol In Vitro Not mutagenic Polyethylene Glycol In vivo Not mutagenic (R)-p-mentha-1,8-diene In Vitro Not mutagenic (R)-p-mentha-1,8-diene In vivo Not mutagenic Diethanolamine In Vitro Not mutagenic Carcinogenicity Name Route Species Value Quartz Inhalation Human and animal Carcinogenic. Polyethylene Glycol Ingestion Rat Not carcinogenic (R)-p-mentha-1,8-diene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Glycerin Ingestion Mouse Some positive data exist, but the data are not sufficient for classification Diethanolamine Dermal Mouse Carcinogenic. Reproductive Toxicity Reproductive and/or Developmental Effects 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 9 of 16 Name Route Value Species Test result Exposure Duration Polyethylene Glycol Ingestion Not toxic to female reproduction Rat NOAEL 1,125 mg/kg/day during gestation Polyethylene Glycol Ingestion Not toxic to male reproduction Rat NOAEL 5699 +/-1341 mg/kg/day 5 days Polyethylene Glycol Not specified. Some positive reproductive/develop mental data exist, but the data are not sufficient for classification NOEL N/A Polyethylene Glycol Ingestion Some positive developmental data exist, but the data are not sufficient for classification Mouse NOAEL 562 mg/animal/da y during gestation (R)-p-mentha-1,8- diene Ingestion Some positive female reproductive data exist, but the data are not sufficient for classification Rat NOAEL 750 mg/kg/day premating & during gestation (R)-p-mentha-1,8- diene Ingestion Some positive developmental data exist, but the data are not sufficient for classification Multiple animal species NOAEL 591 mg/kg/day during organogenesis Glycerin Ingestion Not toxic to female reproduction Rat NOAEL 2,000 mg/kg/day 2 generation Glycerin Ingestion Not toxic to male reproduction Rat NOAEL 2,000 mg/kg/day 2 generation Glycerin Ingestion Not toxic to development Rat NOAEL 2,000 mg/kg/day 2 generation Diethanolamine Ingestion Some positive male reproductive data exist, but the data are not sufficient for classification Rat NOAEL 97 mg/kg/day 13 weeks Diethanolamine Dermal Some positive developmental data exist, but the data are not sufficient for classification Rabbit NOAEL 100 mg/kg/day during organogenesis Diethanolamine Ingestion Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 50 mg/kg/day during organogenesis Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test result Exposure Duration Polyethylene Glycol Inhalation respiratory irritation Some positive data exist, but the Rat NOAEL 1.008 mg/l 2 weeks 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 10 of 16 data are not sufficient for classification (R)-p-mentha- 1,8-diene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification NOAEL Not available Diethanolami ne Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL not available Diethanolami ne Ingestion kidney and/or bladder May cause damage to organs Rat NOAEL 200 mg/kg not applicable Diethanolami ne Ingestion central nervous system depression Some positive data exist, but the data are not sufficient for classification Rat LOAEL 200 mg/kg not applicable Diethanolami ne Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1,600 mg/kg not applicable Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test result Exposure Duration Quartz Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Polyethylene Glycol Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.008 mg/l 2 weeks Polyethylene Glycol Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 5,640 mg/kg/day 13 weeks Polyethylene Glycol Ingestion heart | endocrine system | hematopoietic system | liver | nervous system All data are negative Rat NOAEL 5,640 mg/kg/day 13 weeks (R)-p-mentha- 1,8-diene Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 75 mg/kg/day 103 weeks (R)-p-mentha- 1,8-diene Ingestion liver Some positive data exist, but the data are not sufficient for classification Mouse NOAEL 1,000 mg/kg/day 103 weeks (R)-p-mentha- 1,8-diene Ingestion heart | endocrine system | bone, teeth, nails, All data are negative Rat NOAEL 600 mg/kg/day 103 weeks 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 11 of 16 and/or hair | hematopoietic system | immune system | muscles | nervous system | respiratory system Glycerin Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 3.91 mg/l 14 days Glycerin Inhalation heart | liver | kidney and/or bladder All data are negative Rat NOAEL 3.91 mg/l 14 days Glycerin Ingestion endocrine system | hematopoietic system | liver | kidney and/or bladder All data are negative Rat NOAEL 10,000 mg/kg/day 2 years Diethanolami ne Dermal hematopoietic system May cause damage to organs though prolonged or repeated exposure Rat LOAEL 32 mg/kg/day 13 weeks Diethanolami ne Dermal kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat LOAEL 8 mg/kg/day 2 years Diethanolami ne Dermal liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 500 mg/kg/day 13 weeks Diethanolami ne Inhalation liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.03 mg/l 13 weeks Diethanolami ne Ingestion hematopoietic system May cause damage to organs though prolonged or repeated exposure Rat NOAEL 14 mg/kg/day 13 weeks Diethanolami ne Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 57 mg/kg/day 13 weeks Diethanolami ne Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL not available 13 weeks Diethanolami ne Ingestion liver Some positive data exist, but the data are not sufficient for Rat NOAEL 436 mg/kg/day 13 weeks 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 12 of 16 classification Aspiration Hazard Name Value (R)-p-mentha-1,8-diene Aspiration hazard Exposure Levels Refer Section 8.1 Control Parameters of this Safety Data Sheet. Interactive Effects Not determined. SECTION 12: Ecological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole. 12.1. Toxicity Acute aquatic hazard: GHS Acute 2: Toxic to aquatic life. Chronic aquatic hazard: GHS Chronic 3: Harmful to aquatic life with long lasting effects. No product test data available. Material CAS Number Organism Type Exposure Test endpoint Test result 1,2- Benzisothiazoli n-3-One 2634-33-5 Crustacea Experimental 48 hours EC50 0.062 mg/l 1,2- Benzisothiazoli n-3-One 2634-33-5 Algae Experimental 72 hours EC50 0.15 mg/l 1,2- Benzisothiazoli n-3-One 2634-33-5 Rainbow trout Experimental 96 hours LC50 1.6 mg/l 1,2- Benzisothiazoli n-3-One 2634-33-5 Water flea Experimental 48 hours EC50 4.4 mg/l Diethanolamin e 111-42-2 Fathead minnow Experimental 96 hours LC50 100 mg/l Diethanolamin e 111-42-2 Water flea Experimental 48 hours EC50 2.15 mg/l Diethanolamin e 111-42-2 Green algae Experimental 96 hours EC50 2.1 mg/l (R)-p-mentha- 1,8-diene 5989-27-5 Green algae Experimental 96 hours EC50 1.81 mg/l (R)-p-mentha- 1,8-diene 5989-27-5 Water flea Experimental 96 hours EC50 0.421 mg/l (R)-p-mentha- 1,8-diene 5989-27-5 Fathead minnow Experimental 96 hours LC50 0.702 mg/l 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 13 of 16 Ethoxylated C12-C15 Alcohols 68131-39-5 Diatom Experimental 72 hours EC50 1 mg/l Ethoxylated C12-C15 Alcohols 68131-39-5 Water flea Experimental 48 hours EC50 0.302 mg/l Ethoxylated C12-C15 Alcohols 68131-39-5 Fathead minnow Experimental 96 hours LC50 0.96 mg/l Glycerin 56-81-5 Water flea Experimental 24 hours EC50 >10,000 mg/l Glycerin 56-81-5 Goldfish Experimental 24 hours LC50 >5,000 mg/l Polyethylene Glycol 25322-68-3 Atlantic Salmon Experimental 96 hours LC50 >1,000 mg/l Diethanolamin e 111-42-2 Water flea Experimental 21 days NOEC 0.78 mg/l Diethanolamin e 111-42-2 Green algae Experimental 72 hours Effect Concentration 10% 2.5 mg/l Ethoxylated C12-C15 Alcohols 68131-39-5 Water flea Experimental 21 days NOEC 0.083 mg/l Ethoxylated C12-C15 Alcohols 68131-39-5 Diatom Experimental 72 hours NOEC 0.32 mg/l Feldspars 68476-25-5 Data not available or insufficient for classification Quartz 14808-60-7 Data not available or insufficient for classification 12.2. Persistence and degradability Material CAS Number Test type Duration Study Type Test result Protocol (R)-p-mentha- 1,8-diene 5989-27-5 Experimental Photolysis Photolytic half- life (in air) 2.5 hours (t 1/2) Other methods Water 7732-18-5 Data not available or insufficient for classification N/A N/A N/A N/A Quartz 14808-60-7 Data not available or insufficient for classification N/A N/A N/A N/A Feldspars 68476-25-5 Data not available or insufficient for classification N/A N/A N/A N/A (R)-p-mentha- 1,8-diene 5989-27-5 Experimental Biodegradation 14 days BOD 98 % weight OECD 301C - MITI test (I) Diethanolamin e 111-42-2 Experimental Biodegradation 10 days BOD 72 % weight OECD 301D - Closed bottle test 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 14 of 16 Glycerin 56-81-5 Experimental Biodegradation 14 days BOD 63 % weight OECD 301C - MITI test (I) Polyethylene Glycol 25322-68-3 Experimental Biodegradation 28 days BOD 56.2 % weight OECD 301C - MITI test (I) Ethoxylated C12-C15 Alcohols 68131-39-5 Experimental Biodegradation 28 days CO2 evolution 82 % weight OECD 301B - Modified sturm or CO2 1,2- Benzisothiazoli n-3-One 2634-33-5 Experimental Biodegradation 28 days BOD 0 % weight OECD 301C - MITI test (I) 12.3 : Bioaccumulative potential Material CAS Number Test type Duration Study Type Test result Protocol Quartz 14808-60-7 Data not available or insufficient for classification N/A N/A N/A N/A Polyethylene Glycol 25322-68-3 Data not available or insufficient for classification N/A N/A N/A N/A Feldspars 68476-25-5 Data not available or insufficient for classification N/A N/A N/A N/A Water 7732-18-5 Data not available or insufficient for classification N/A N/A N/A N/A (R)-p-mentha- 1,8-diene 5989-27-5 Estimated Bioconcentrati on Bioaccumulatio n factor 2127 Other methods Ethoxylated C12-C15 Alcohols 68131-39-5 Estimated Bioconcentrati on Bioaccumulatio n factor 10 Estimated: Bioconcentration factor Glycerin 56-81-5 Experimental Bioconcentrati on Log Kow -1.76 Other methods Diethanolamin e 111-42-2 Experimental Bioconcentrati on Log Kow -2.18 1,2- Benzisothiazoli n-3-One 2634-33-5 Experimental Bioconcentrati on Log Kow 1.45 Other methods 12.4. Mobility in soil Please contact manufacturer for more details 12.5 Other adverse effects No information available. SECTION 13: Disposal considerations 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 15 of 16 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Dispose of waste product in a permitted industrial waste facility. Proper destruction may require the use of additional fuel during incineration processes. SECTION 14: Transport Information Australian Dangerous Goods Code (ADG) - Road/Rail Transport UN No.: Not applicable. Proper shipping name: Not applicable. Class/Division: Not applicable. Sub Risk: Not applicable. Packing Group: Not applicable. Hazchem Code: Not applicable IERG: Not applicable. International Air Transport Association (IATA) - Air Transport UN No.: Not applicable. Proper shipping name: Not applicable. Class/Division: Not applicable. Sub Risk: Not applicable. Packing Group: Not applicable. International Maritime Dangerous Goods Code (IMDG)- Marine Transport UN No.: Not applicable. Proper shipping name: Not applicable. Class/Division: Not applicable. Sub Risk: Not applicable. Packing Group: Not applicable. Marine Pollutant: Not applicable. SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Australian Inventory Status: The chemical components contained within this product are listed on the Australian Inventory of Chemical Substances and are in compliance with the requirements of the Industrial Chemicals (Notification and Assessment) Act 1989 as amended. Poison Schedule:This product has not been assessed for poisons scheduling as the product is intended for industrial and professional use only. SECTION 16: Other information Revision information: Conversion to GHS format SDS. DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Safety Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to 3M? Scuff-It? Paint Prep Gel, PN 06013 __________________________________________________________________________________________ Page: 16 of 16 satisfy themselves as to the suitability of the product for their own intended applications. Greenguard ? is a United States based program. The ?Low VOC? reference related to United States Federal and State regulations exemptions for some solvents. 3M Australia SDSs are available at www.3m.com.au