3M? SMC/Fiberglass Repair Adhesvie - 35 PN 08219 10/25/16 ________________________________________________________________________________________________________ Page 1 of 2 Safety Data Sheet Copyright,2016,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 28-2361-5 Version Number: 6.01 Issue Date: 10/25/16 Supercedes Date: 10/10/16 Product identifier 3M? SMC/Fiberglass Repair Adhesvie - 35 PN 08219 ID Number(s): 41-0003-6770-0, 41-0003-8021-6, 60-4550-5262-5 Recommended use Automotive, Urethane Repair Adhesive used to bond SMC and FRP (traditional fiberglass) body panels to each other and to primed metal frames. Supplier's details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 26-6862-2, 28-2365-6 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M? SMC/Fiberglass Repair Adhesvie - 35 PN 08219 10/25/16 ________________________________________________________________________________________________________ Page 2 of 2 3M USA SDSs are available at www.3M.com 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 26-6862-2 Version Number: 3.05 Issue Date: 07/26/18 Supercedes Date: 05/24/18 SECTION 1: Identification 1.1. Product identifier 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B Product Identification Numbers LB-K100-0708-1, LB-K100-0910-4 1.2. Recommended use and restrictions on use Recommended use Automotive, Body Repair 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Respiratory Sensitizer: Category 1. Skin Sensitizer: Category 1. Reproductive Toxicity: Category 2. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 2 of 11 Health Hazard | Pictograms Hazard Statements May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure: respiratory system | Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. In case of inadequate ventilation wear respiratory protection. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: If breathing is difficult, remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Get medical advice/attention if you feel unwell. Storage: Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2% of the mixture consists of ingredients of unknown acute oral toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Polyether Polyol (NJTSRN 04499600-6782) Trade Secret* 30 - 60 Trade Secret * Polyol (NJTSRN 04499600-6783) Trade Secret* 15 - 40 Trade Secret * Talc 14807-96-6 15 - 40 Trade Secret * Urethane Prepolymer (NJTSRN 04499600-6781) Trade Secret* 3 - 7 Trade Secret * Thickening Agent Trade Secret* 1 - 5 Trade Secret * Piperazine 110-85-0 0.1 - 1 Trade Secret * 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 3 of 11 Quartz Silica 14808-60-7 0.02006 - 0.06018 Trade Secret * Titanium Dioxide 13463-67-7 < 0.1 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Oxides of Nitrogen During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 4 of 11 Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Do not use in a confined area with minimal air exchange. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store away from acids. Store away from strong bases. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Piperazine 110-85-0 ACGIH TWA(as piperazine, inhalable fraction & vapor):0.03 ppm A4: Not class. as human carcin, Dermal/Respiratory Sensitizer Titanium Dioxide 13463-67-7 ACGIH TWA:10 mg/m3 A4: Not class. as human carcin Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Talc 14807-96-6 OSHA TWA:2 mg/m3 Quartz Silica 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Quartz Silica 14808-60-7 OSHA TWA Table Z- 1(respirable):0.05 mg/m3;TWA Table Z- 3(respirable):0.1 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 5 of 11 CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Butyl rubber Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Viscous Odor, Color, Grade: Slight ammonia like odor, dark green. Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point No Data Available Flash Point > 340 ?F [Test Method:Tagliabue Closed Cup] Evaporation rate <=1 [Details:Gels with exposure to humidity.] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 6 of 11 Vapor Pressure <=0.000004 mmHg [@ 68 ?F] Vapor Density >=1 [Ref Std:AIR=1] Density 1.2 g/ml Specific Gravity 1.0 - 1.2 [Ref Std:WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 1 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 0.1 % weight [Test Method:calculated per CARB title 2] Percent volatile 0.093 % weight VOC Less H2O & Exempt Solvents 1 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid High shear and high temperature conditions 10.5. Incompatible materials Strong acids Strong bases Alcohols Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition Aldehydes Not Specified Hydrogen Cyanide Not Specified Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 7 of 11 Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. Vapors released during curing may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Contact with the skin during product use is not expected to result in significant irritation. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. May cause additional health effects (see below). Eye Contact: Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: May cause additional health effects (see below). Additional Health Effects: Prolonged or repeated exposure may cause target organ effects: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Ingredient CAS No. Class Description Regulation SILICA, CRYS AIRRESP 14808-60-7 Known human carcinogen National Toxicology Program Carcinogens Quartz Silica 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Titanium Dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Polyether Polyol (NJTSRN 04499600-6782) Dermal Rat LD50 > 2,000 mg/kg Polyether Polyol (NJTSRN 04499600-6782) Ingestion Rat LD50 > 2,500 mg/kg Talc Dermal LD50 estimated to be > 5,000 mg/kg Talc Ingestion LD50 estimated to be > 5,000 mg/kg Polyol (NJTSRN 04499600-6783) Dermal Rabbit LD50 > 5,000 mg/kg Polyol (NJTSRN 04499600-6783) Ingestion Rat LD50 > 10,000 mg/kg Urethane Prepolymer (NJTSRN 04499600-6781) Dermal LD50 estimated to be > 5,000 mg/kg 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 8 of 11 Urethane Prepolymer (NJTSRN 04499600-6781) Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Piperazine Dermal estimated to be > 5,000 mg/kg Piperazine Inhalation- Dust/Mist estimated to be > 12.5 mg/l Piperazine Ingestion estimated to be > 5,000 mg/kg Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 6.82 mg/l Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Polyether Polyol (NJTSRN 04499600-6782) Rabbit No significant irritation Talc Rabbit No significant irritation Quartz Silica Professio nal judgeme nt No significant irritation Titanium Dioxide Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Polyether Polyol (NJTSRN 04499600-6782) Rabbit Mild irritant Talc Rabbit No significant irritation Titanium Dioxide Rabbit No significant irritation Skin Sensitization Name Species Value Titanium Dioxide Human and animal Not classified Respiratory Sensitization Name Species Value Talc Human Not classified Germ Cell Mutagenicity Name Route Value Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Quartz Silica In Vitro Some positive data exist, but the data are not sufficient for classification Quartz Silica In vivo Some positive data exist, but the data are not sufficient for classification Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Carcinogenicity Name Route Species Value Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Quartz Silica Inhalation Human and Carcinogenic 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 9 of 11 animal Titanium Dioxide Ingestion Multiple animal species Not carcinogenic Titanium Dioxide Inhalation Rat Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Talc Ingestion Not classified for development Rat NOAEL 1,600 mg/kg during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure For the component/components, either no data are currently available or the data are not sufficient for classification. Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Talc Inhalation pulmonary fibrosis | respiratory system Not classified Rat NOAEL 18 mg/m3 113 weeks Quartz Silica Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.01 mg/l 2 years Titanium Dioxide Inhalation pulmonary fibrosis Not classified Human NOAEL Not available occupational exposure Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 10 of 11 incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Not applicable Health Hazards Reproductive toxicity Specific target organ toxicity (single or repeated exposure) 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information HMIS Hazard Classification Health: 2 Flammability: 1 Physical Hazard: 1 Personal Protection: X - See PPE section. 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part B 07/26/18 __________________________________________________________________________________________ Page 11 of 11 Hazardous Material Identification System (HMIS? IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? IV ratings are to be used with a fully implemented HMIS? IV program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 26-6862-2 Version Number: 3.05 Issue Date: 07/26/18 Supercedes Date: 05/24/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 1 of 12 Safety Data Sheet Copyright,2016,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 28-2365-6 Version Number: 4.00 Issue Date: 10/10/16 Supercedes Date: 08/08/16 SECTION 1: Identification 1.1. Product identifier 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A Product Identification Numbers LB-K100-0796-6, LB-K100-0908-5 1.2. Recommended use and restrictions on use Recommended use Automotive, Urethane Repair Adhesive used to bond SMC and FRP (traditional fiberglass) body panels to each other and to primed metal frames. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Respiratory Sensitizer: Category 1. Skin Sensitizer: Category 1. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 2 of 12 Symbols Exclamation mark | Health Hazard | Pictograms Hazard Statements Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure: respiratory system | Precautionary Statements Prevention: Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. In case of inadequate ventilation wear respiratory protection. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. 13% of the mixture consists of ingredients of unknown acute oral toxicity. 12% of the mixture consists of ingredients of unknown acute inhalation toxicity. 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 3 of 12 SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Methylene Phenylene Isocyanate 101-68-8 30 - 60 Trade Secret * Urethane Prepolymer (NJTSRN 04499600-6779) Trade Secret* 30 - 60 Trade Secret * Diisocyanate Polymer 25686-28-6 10 - 30 Trade Secret * Talc 14807-96-6 7 - 13 Trade Secret * Aluminum Silicate (NJTSRN 04499600-6789) Trade Secret* 7 - 13 Trade Secret * Thickening Agent (NJTSRN 04499600-6784) Trade Secret* 1 - 5 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media DO NOT USE WATER In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Cyanide During Combustion 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 4 of 12 Oxides of Nitrogen During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Dispose of collected material as soon as possible. SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Do not use in a confined area with minimal air exchange. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed to prevent loss of stabilizing materials. Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Store away from heat. Store away from acids. Store away from strong bases. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Methylene Phenylene Isocyanate 101-68-8 OSHA CEIL:0.2 mg/m3(0.02 ppm) Methylene Phenylene Isocyanate 101-68-8 ACGIH TWA:0.005 ppm FREE ISOCYANATES 101-68-8 Manufacturer determined TWA:0.005 ppm;STEL:0.02 ppm Talc 14807-96-6 OSHA TWA concentration(as total dust):0.3 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 5 of 12 particles/cu. ft.);TWA:20 millions of particles/cu. ft. Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin Thickening Agent (NJTSRN 04499600-6784) Trade Secret OSHA TWA concentration:0.8 mg/m3;TWA:20 millions of particles/cu. ft. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide ventilated enclosure for heat curing. Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Nitrile Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Butyl rubber Apron ? Nitrile Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 6 of 12 General Physical Form: Liquid Odor, Color, Grade: White, slight isocyanate odor pH Not Applicable Melting point Not Applicable Boiling Point No Data Available Flash Point > 383 ?F [Test Method: Closed Cup] Evaporation rate < 1 [Ref Std: ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure .010 mmHg [Details: @77.00 F for product] Vapor Density < 1 [Ref Std: AIR=1] Density 10.72 lb/gal Specific Gravity 1.288 [Ref Std: WATER=1] Solubility In Water No Data Available Partition coefficient: n-octanol/ water No Data Available Viscosity No Data Available Hazardous Air Pollutants 0.779 lb HAPS/lb solids [Test Method: Calculated] Volatile Organic Compounds 0 g/l [Test Method: calculated SCAQMD rule 443.1] Volatile Organic Compounds 0 % weight [Test Method: calculated per CARB title 2] Percent volatile 0 % weight VOC Less H2O & Exempt Solvents 0 g/l [Test Method: calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization may occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Strong acids Strong bases Water 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 7 of 12 reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Prolonged or repeated exposure may cause target organ effects: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Carcinogenicity: Ingredient CAS No. Class Description Regulation Generic: CAS NO S14807966D 14807-96-6 Grp. 2B: Possible human carc. International Agency for Research on Cancer Additional Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE > 50 mg/l Overall product Ingestion No data available; calculated ATE > 5,000 mg/kg Methylene Phenylene Isocyanate Dermal Rabbit LD50 > 5,000 mg/kg Methylene Phenylene Isocyanate Inhalation- Rat LC50 0.368 mg/l 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 8 of 12 Dust/Mist (4 hours) Methylene Phenylene Isocyanate Ingestion Rat LD50 31,600 mg/kg Urethane Prepolymer (NJTSRN 04499600-6779) Dermal LD50 estimated to be > 5,000 mg/kg Urethane Prepolymer (NJTSRN 04499600-6779) Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Diisocyanate Polymer Dermal Rabbit LD50 > 5,000 mg/kg Diisocyanate Polymer Inhalation- Dust/Mist (4 hours) Rat LC50 0.368 mg/l Diisocyanate Polymer Ingestion Rat LD50 31,600 mg/kg Talc Dermal LD50 estimated to be > 5,000 mg/kg Talc Ingestion LD50 estimated to be > 5,000 mg/kg Thickening Agent (NJTSRN 04499600-6784) Dermal Rabbit LD50 > 5,000 mg/kg Thickening Agent (NJTSRN 04499600-6784) Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Thickening Agent (NJTSRN 04499600-6784) Ingestion Rat LD50 > 5,110 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Methylene Phenylene Isocyanate official classifica tion Irritant Diisocyanate Polymer official classifica tion Irritant Talc Rabbit No significant irritation Thickening Agent (NJTSRN 04499600-6784) Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Methylene Phenylene Isocyanate official classifica tion Severe irritant Diisocyanate Polymer official classifica tion Severe irritant Talc Rabbit No significant irritation Thickening Agent (NJTSRN 04499600-6784) Rabbit No significant irritation Skin Sensitization Name Species Value Methylene Phenylene Isocyanate official classifica tion Sensitizing Diisocyanate Polymer official classifica tion Sensitizing Thickening Agent (NJTSRN 04499600-6784) Human and animal Not sensitizing Respiratory Sensitization Name Species Value Methylene Phenylene Isocyanate Human Sensitizing Diisocyanate Polymer Human Sensitizing Talc Human Not sensitizing Germ Cell Mutagenicity 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 9 of 12 Name Route Value Methylene Phenylene Isocyanate In Vitro Some positive data exist, but the data are not sufficient for classification Diisocyanate Polymer In Vitro Some positive data exist, but the data are not sufficient for classification Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Thickening Agent (NJTSRN 04499600-6784) In Vitro Not mutagenic Carcinogenicity Name Route Species Value Methylene Phenylene Isocyanate Inhalation Rat Some positive data exist, but the data are not sufficient for classification Diisocyanate Polymer Inhalation Rat Some positive data exist, but the data are not sufficient for classification Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Thickening Agent (NJTSRN 04499600-6784) Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Methylene Phenylene Isocyanate Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 0.004 mg/l during organogenesi s Diisocyanate Polymer Inhalation Some positive developmental data exist, but the data are not sufficient for classification Rat NOAEL 0.004 mg/l during organogenesi s Talc Ingestion Not toxic to development Rat NOAEL 1,600 mg/kg during organogenesi s Thickening Agent (NJTSRN 04499600- 6784) Ingestion Not toxic to female reproduction Rat NOAEL 509 mg/kg/day 1 generation Thickening Agent (NJTSRN 04499600- 6784) Ingestion Not toxic to male reproduction Rat NOAEL 497 mg/kg/day 1 generation Thickening Agent (NJTSRN 04499600- 6784) Ingestion Not toxic to development Rat NOAEL 1,350 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methylene Phenylene Isocyanate Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Diisocyanate Polymer Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methylene Phenylene Isocyanate Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks Diisocyanate Polymer Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 10 of 12 Talc Inhalation pulmonary fibrosis | respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 18 mg/m3 113 weeks Thickening Agent (NJTSRN 04499600-6784) Inhalation respiratory system | silicosis All data are negative Human NOAEL Not available occupational exposure Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - Yes Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Methylene Phenylene Isocyanate 101-68-8 Trade Secret 30 - 60 Methylene Phenylene Isocyanate (Benzene, 1,1'- methylenebis[4-isocyanato-) 101-68-8 30 - 60 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 11 of 12 Methylene Phenylene Isocyanate (DIISOCYANATES (CERTAIN CHEMICALS ONLY)) 101-68-8 30 - 60 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the China "Measures on Environmental Management of New Chemical Substance". Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Industrial Safety and Health Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of the Korean Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain restrictions may apply. Contact the selling division for additional information. The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 1 Special Hazards: Reacts with Water National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 28-2365-6 Version Number: 4.00 Issue Date: 10/10/16 Supercedes Date: 08/08/16 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M? SMC/Fiberglass Repair Adhesive-35 PN 08219 Part A 10/10/16 __________________________________________________________________________________________ Page 12 of 12 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M 3M USA SDSs are available at www.3M.com