SAFETY DATA SHEET Revision Date 01-May-2018 Version 4 1. IDENTIFICATION Product identifier Product Name DECAL & ADHESIVE REMOVER 5 OZ. Other means of identification Product Code 80025 Recommended use of the chemical and restrictions on use Recommended Use Adhesive Remover. Uses advised against No information available Details of the supplier of the safety data sheet 24-hour emergency phone number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin sensitization Category 1 Aspiration toxicity Category 1 Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA May Also Be Distributed by: ITW Permatex Canada 101-2360 Bristol Circle Oakville, ON Canada L6H 6M5 Telephone: (800) 924-6994 Flammable aerosols Category 1 Gases under pressure Liquefied gas Signal word Danger May cause an allergic skin reaction May be fatal if swallowed and enters airways Extremely flammable aerosol Contains gas under pressure; may explode if heated _____________________________________________________________________________________________ Page 1 / 8 _____________________________________________________________________________________________ 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date 01-May-2018 Precautionary Statements - Prevention Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Keep away from heat/sparks/open flames/hot surfaces. - No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - The classification as a carcinogen or mutagen need not apply since it can be shown that the substance contains less than 0.1 % w/w 1,3-butadiene (EINECS No. 203-450-8) Unknown acute toxicity 2 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance(s) Chemical Name CAS No Weight-% DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 80-90 PROPANE 74-98-6 3 - 7 D-LIMONENE 5989-27-5 3 - 7 BUTANE 106-97-8 3 - 7 Any concentration shown as a range is due to batch variation. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Appearance Clear Physical state Aerosol Odor Citrus _____________________________________________________________________________________________ Page 2 / 8 _____________________________________________________________________________________________ 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date 01-May-2018 Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. In the case of skin irritation or allergic reactions see a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce vomiting. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable. Contains gas under pressure; may explode if heated. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Ensure adequate ventilation, especially in confined areas. Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wash thoroughly after handling. Other Information Ventilate the area. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. _____________________________________________________________________________________________ Page 3 / 8 _____________________________________________________________________________________________ 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date 01-May-2018 Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Conditions Store locked up. Do not expose to temperatures exceeding 50 ?C/122 ?F. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH PROPANE 74-98-6 : See Appendix F: Minimal Oxygen Content TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 BUTANE 106-97-8 STEL: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Aerosol Appearance Clear Odor Citrus Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 8 _____________________________________________________________________________________________ 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date 01-May-2018 Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 19.75% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Temperatures >50 ?C / 122 ?F. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Property Values Remarks ? Method pH No information available Melting point / freezing point No information available Boiling point / boiling range No information available Flash point -104 ?C / -155 ?F Gives a flame projection at full valve opening or flashback at any degree of valve opening Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: 6.6% Lower flammability limit: 0.9% Vapor pressure 30-44 psig @70?F/55-75 psig @ 130?F Vapor density No information available Relative density 0.769 Water solubility Insoluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Stable under normal conditions _____________________________________________________________________________________________ Page 5 / 8 _____________________________________________________________________________________________ 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date 01-May-2018 Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h PROPANE 74-98-6 - - = 658 mg/L ( Rat ) 4 h D-LIMONENE 5989-27-5 = 4400 mg/kg ( Rat ) > 5 g/kg ( Rabbit ) - BUTANE 106-97-8 - - = 658 g/m3 ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA D-LIMONENE 5989-27-5 - Group 3 - - IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Target Organ Effects Central nervous system. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5764 mg/kg ATEmix (dermal) 2430 mg/kg ATEmix (inhalation-gas) 2623373 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 14 % of the mixture consists of component(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient PROPANE 74-98-6 2.3 BUTANE 106-97-8 2.89 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS _____________________________________________________________________________________________ Page 6 / 8 Waste treatment methods _____________________________________________________________________________________________ 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date 01-May-2018 Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number D001 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status D-LIMONENE 5989-27-5 Toxic 14. TRANSPORT INFORMATION DOT UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 Emergency Response Guide Number 126 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations _____________________________________________________________________________________________ Page 7 / 8 SARA 313 _____________________________________________________________________________________________ 80025 - DECAL & ADHESIVE REMOVER 5 OZ. Revision Date 01-May-2018 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania PROPANE 74-98-6 X X X BUTANE 106-97-8 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class A Compressed gases, B5 - Flammable aerosol, D2B - Toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 01-May-2018 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 4 Instability 0 - HMIS Health hazards 2 Flammability 4 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 8 / 8