1. IDENTIFICATION Product identifier Product Name Spray Nine? 5 gal Other means of identification Product Code 26805 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Disinfectant Cleaning Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements Emergency Overview Hazards not otherwise classified (HNOC) Not applicable Other Information _____________________________________________________________________________________________ Page 1 / 7 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 22-Apr-2015 SAFETY DATA SHEET Version 1 The product contains no substances which at their given concentration, are considered to be hazardous to health Odor CitrusAppearance Clear Physical state Liquid _____________________________________________________________________________________________ Not applicable 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret WATER 7732-18-5 60 - 100 * ETHOXYLATED C9-C11 ALCOHOLS 68439-46-3 1 - 5 * DIPROPYLENE GLYCOL MONONBUTYL ETHER 29911-28-2 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. _____________________________________________________________________________________________ Page 2 / 7 26805 - Spray Nine? 5 gal Revision Date 22-Apr-2015 _____________________________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Use personal protective equipment as required. Dam up. Cover liquid spill with sand, earth or other non-combustible absorbent material. Take up mechanically, placing in appropriate containers for disposal. Clean contaminated surface thoroughly. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. _____________________________________________________________________________________________ Page 3 / 7 26805 - Spray Nine? 5 gal Revision Date 22-Apr-2015 _____________________________________________________________________________________________ 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear Odor Citrus Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) <0.5% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides _____________________________________________________________________________________________ Page 4 / 7 Partition coefficient No information available No information available Evaporation rate < 1 Autoignition temperature No information available Revision Date 22-Apr-2015 Decomposition temperature No information available Butyl acetate = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Vapor pressure 18 mm Hg Boiling point / boiling range 100 ?C / 212 ?F No data available Vapor density >1 Remarks ? Method Air = 1 Relative density 1.02 g/ml 26805 - Spray Nine? 5 gal Flash point Water solubility Soluble in water > 93 ?C / > 200 ?F Solubility in other solvents No information available Tag Closed Cup pH _____________________________________________________________________________________________ 11. TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 WATER 7732-18-5 > 90 mL/kg ( Rat ) - - ETHOXYLATED C9-C11 ALCOHOLS 68439-46-3 = 1378 mg/kg ( Rat ) = 1400 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) - DIPROPYLENE GLYCOL MONONBUTYL ETHER 29911-28-2 = 1620 ?L/kg ( Rat ) = 5860 ?L/kg ( Rabbit ) = 42.1 ppm ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity This product contains one or more substances which are classified by IARC as carcinogenic to humans (Group I), probably carcinogenic to humans (Group 2A) or possibly carcinogenic to humans (Group 2B). The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 39421 mg/kg ATEmix (dermal) 76980 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 3.17% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea DIPROPYLENE GLYCOL MONONBUTYL ETHER 29911-28-2 - 841: 96 h Poecilia reticulata mg/L LC50 static - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS _____________________________________________________________________________________________ Page 5 / 7 26805 - Spray Nine? 5 gal Revision Date 22-Apr-2015 _____________________________________________________________________________________________ Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not determined ENCS Not Listed. IECSC Complies KECL Not determined PICCS Not determined AICS Not determined Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) _____________________________________________________________________________________________ Page 6 / 7 26805 - Spray Nine? 5 gal Revision Date 22-Apr-2015 _____________________________________________________________________________________________ CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania SODIUM HYDROXIDE 1310-73-2 X X X ETHANOL 64-17-5 X X X U.S. EPA Label Information EPA Pesticide Registration Number 6659-3 EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 22-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 7 / 7 - HMIS NFPA Health hazards 1 26805 - Spray Nine? 5 gal Flammability 1 Physical hazards 0 Personal protection B Health hazards 1 Revision Date 22-Apr-2015 Flammability 1 Instability 0