1. IDENTIFICATION Product identifier Product Name Spray Nine Grez-Off? 55 gal Other means of identification Product Code 22755 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Degreaser - General Purpose - Non-Aerosol Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 8 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Causes skin irritation Causes serious eye irritation Revision Date 25-Mar-2015 SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Warning _____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Not applicable Unknown acute toxicity 1.4708% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance Chemical Name CAS No Weight-% Trade Secret WATER 7732-18-5 60 - 100 * DIPROPYLENE GLYCOL MONONBUTYL ETHER 29911-28-2 1 - 5 * ETHOXYLATED C9-C11 ALCOHOLS 68439-46-3 1 - 5 * SODIUM METASILICATE 6834-92-0 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. _____________________________________________________________________________________________ Page 2 / 8 22755 - Spray Nine Grez-Off? 55 gal Revision Date 25-Mar-2015 Odor CitrusAppearance Orange Physical state Liquid _____________________________________________________________________________________________ Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Water spray (fog), Dry chemical, Carbon dioxide (CO2), Foam Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE _____________________________________________________________________________________________ Page 3 / 8 22755 - Spray Nine Grez-Off? 55 gal Revision Date 25-Mar-2015 _____________________________________________________________________________________________ Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep from freezing. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Orange Odor Citrus Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 8 Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Revision Date 25-Mar-2015 Vapor pressure 18 mm Hg Boiling point / boiling range 100 ?C / 212 ?F Vapor density >1 Remarks ? Method Air = 1 Relative density ~1.013 g/ml Flash point Water solubility Soluble in water > 93 ?C / > 200 ?F Solubility in other solvents No information available Tag Closed Cup pH Partition coefficient No information available 8-11 Evaporation rate < 1 Autoignition temperature No information available Butyl acetate = 1 22755 - Spray Nine Grez-Off? 55 gal Flammability (solid, gas) No information available _____________________________________________________________________________________________ Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) <1% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Keep from freezing. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 WATER 7732-18-5 > 90 mL/kg ( Rat ) - - DIPROPYLENE GLYCOL MONONBUTYL ETHER 29911-28-2 = 1620 ?L/kg ( Rat ) = 5860 ?L/kg ( Rabbit ) = 42.1 ppm ( Rat ) 4 h ETHOXYLATED C9-C11 ALCOHOLS 68439-46-3 = 1378 mg/kg ( Rat ) = 1400 mg/kg ( Rat ) > 2 g/kg ( Rabbit ) - SODIUM METASILICATE 6834-92-0 = 600 mg/kg ( Rat ) - - Information on toxicological effects Symptoms No information available. _____________________________________________________________________________________________ Page 5 / 8 Decomposition temperature Dynamic viscosity No information available No information available No data available Revision Date 25-Mar-2015 Kinematic viscosity No information available 22755 - Spray Nine Grez-Off? 55 gal _____________________________________________________________________________________________ Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 17322 mg/kg ATEmix (dermal) 75518 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 3.2241% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea DIPROPYLENE GLYCOL MONONBUTYL ETHER 29911-28-2 - 841: 96 h Poecilia reticulata mg/L LC50 static - SODIUM METASILICATE 6834-92-0 - 210: 96 h Brachydanio rerio mg/L LC50 210: 96 h Brachydanio rerio mg/L LC50 semi-static 216: 96 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated _____________________________________________________________________________________________ Page 6 / 8 22755 - Spray Nine Grez-Off? 55 gal Revision Date 25-Mar-2015 _____________________________________________________________________________________________ 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed ENCS Not Listed IECSC Complies KECL Complies PICCS Not Listed AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) _____________________________________________________________________________________________ Page 7 / 8 Revision Date 25-Mar-2015 Physical hazards 0 Personal protection B Health hazards 1 Flammability 1 Instability 0 - 22755 - Spray Nine Grez-Off? 55 gal HMIS NFPA Health hazards 1 Flammability 1 _____________________________________________________________________________________________ Revision Date 25-Mar-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 8 / 8 22755 - Spray Nine Grez-Off? 55 gal Revision Date 25-Mar-2015