SAFETY DATA SHEET Revision Date 26-Apr-2017 Version 5 1. IDENTIFICATION Product identifier Product Name Spray Nine Glass & Chrome Cleaner 19 oz. Other means of identification Product Code 23319 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Glass cleaner - Aerosol Uses advised against No information available Details of the supplier of the safety data sheet 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA May Also Be Distributed by: ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Gases under pressure Liquefied gas Warning Contains gas under pressure; may explode if heated _____________________________________________________________________________________________ Page 1 / 8 _____________________________________________________________________________________________ 23319 - Spray Nine Glass & Chrome Cleaner 19 oz. Revision Date 26-Apr-2017 Precautionary Statements - Prevention Pressurized container: Do not pierce or burn, even after use In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Protect from sunlight. Store in a well-ventilated place Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % w/w 1,3-butadiene (EINECS No. 203-450-8) 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance(s) Chemical Name CAS No Weight-% Trade Secret PROPANE 74-98-6 1 - 5 * BUTANE 106-97-8 1 - 5 * 2-BUTOXYETHANOL 111-76-2 1 - 5 * 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Appearance White Physical state Liquid Odor Citrus _____________________________________________________________________________________________ Page 2 / 8 _____________________________________________________________________________________________ 23319 - Spray Nine Glass & Chrome Cleaner 19 oz. Revision Date 26-Apr-2017 Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Heating causes rise in pressure with risk of bursting. Keep product and empty container away from heat and sources of ignition. Risk of ignition. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Remove all sources of ignition. Do not puncture or incinerate cans. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling. Contents under pressure. Do not puncture or incinerate cans. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Conditions for safe storage, including any incompatibilities Storage Conditions Protect from sunlight. Store in a well-ventilated place. Keep from freezing. Incompatible materials Strong oxidizing agents, Acids 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH PROPANE 74-98-6 : See Appendix F: Minimal Oxygen Content TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 _____________________________________________________________________________________________ Page 3 / 8 _____________________________________________________________________________________________ 23319 - Spray Nine Glass & Chrome Cleaner 19 oz. Revision Date 26-Apr-2017 BUTANE 106-97-8 STEL: 1000 ppm (vacated) TWA: 800 ppm (vacated) TWA: 1900 mg/m3 TWA: 800 ppm TWA: 1900 mg/m3 2-BUTOXYETHANOL 111-76-2 TWA: 20 ppm TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection None under normal use conditions. In case of insufficient ventilation, wear suitable respiratory equipment. General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance White Odor Citrus Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Property Values Remarks ? Method pH 10.05-10.15 Melting point / freezing point No information available Boiling point / boiling range > 100 ?C / >212 ?F Flash point No information available Contents under pressure Evaporation rate < 1 Butyl acetate = 1 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density >1 Air = 1 Relative density 0.995-1.005 Water solubility Soluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available _____________________________________________________________________________________________ Page 4 / 8 _____________________________________________________________________________________________ 23319 - Spray Nine Glass & Chrome Cleaner 19 oz. Revision Date 26-Apr-2017 Other Information Softening point No information available Molecular weight No information available VOC Content (%) 7.5% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Keep from freezing. Incompatible materials Strong oxidizing agents, Acids Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 PROPANE 74-98-6 - - = 658 mg/L ( Rat ) 4 h BUTANE 106-97-8 - - = 658 g/m3 ( Rat ) 4 h 2-BUTOXYETHANOL 111-76-2 = 470 mg/kg ( Rat ) = 99 mg/kg ( Rabbit ) = 450 ppm ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA 2-BUTOXYETHANOL 111-76-2 A3 Group 3 - - ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) No data available _____________________________________________________________________________________________ Page 5 / 8 _____________________________________________________________________________________________ 23319 - Spray Nine Glass & Chrome Cleaner 19 oz. Revision Date 26-Apr-2017 Not classifiable as a human carcinogen Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Target Organ Effects Blood, Central nervous system, Eyes, Hematopoietic System, kidney, Liver, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 15667 mg/kg ATEmix (dermal) 36667 mg/kg ATEmix (inhalation-gas) 4587164 mg/l ATEmix (inhalation-dust/mist) 50 mg/l ATEmix (inhalation-vapor) 15000 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 7 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient PROPANE 74-98-6 2.3 BUTANE 106-97-8 2.89 2-BUTOXYETHANOL 111-76-2 0.81 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable 14. TRANSPORT INFORMATION DOT UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.2 Emergency Response Guide Number 126 _____________________________________________________________________________________________ Page 6 / 8 _____________________________________________________________________________________________ 23319 - Spray Nine Glass & Chrome Cleaner 19 oz. Revision Date 26-Apr-2017 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.2 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not determined IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % 2-BUTOXYETHANOL - 111-76-2 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals _____________________________________________________________________________________________ Page 7 / 8 _____________________________________________________________________________________________ 23319 - Spray Nine Glass & Chrome Cleaner 19 oz. Revision Date 26-Apr-2017 U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania WATER 7732-18-5 - - X PROPANE 74-98-6 X X X BUTANE 106-97-8 X X X 2-BUTOXYETHANOL 111-76-2 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class A Compressed gases 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 26-Apr-2017 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 1 Flammability 1 Instability 0 - HMIS Health hazards 1 Flammability 1 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 8 / 8