SAFETY DATA SHEET Revision Date 21-Aug-2018 Version 5 1. IDENTIFICATION Product identifier Product Name 35V PRUSSIAN BLUE .75OZ Other means of identification Product Code 80038 Recommended use of the chemical and restrictions on use Recommended Use Pigmented compound Uses advised against No information available Details of the supplier of the safety data sheet 24-hour emergency phone number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address: This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements Emergency Overview Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA May Also Be Distributed by: ITW Permatex Canada 101-2360 Bristol Circle Oakville, ON Canada L6H 6M5 Telephone: (800) 924-6994 The product contains no substances which at their given concentration, are considered to be hazardous to health Appearance Blue Physical state Liquid Odor Mild _____________________________________________________________________________________________ Page 1 / 7 _____________________________________________________________________________________________ 80038 - 35V PRUSSIAN BLUE .75OZ Revision Date 21-Aug-2018 Not applicable Other Information - Note L: The classification as a carcinogen 1 does not apply. The substance contains less than 3 % DMSO extract as measured by IP 346. This note applies only to certain complex oil derived substances in Annex I - Note N: The classification as a carcinogen does not apply since the full refining history is known and it can be shown that the substance from which it is produced is not a carcinogen Unknown acute toxicity 4.9979 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance(s) The product contains no substances which at their given concentration, are considered to be hazardous to health. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES:. Wash with plenty of water. Skin contact IF ON SKIN:. Wash with soap and water. Inhalation IF INHALED. Remove to fresh air. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. _____________________________________________________________________________________________ Page 2 / 7 6. ACCIDENTAL RELEASE MEASURES _____________________________________________________________________________________________ 80038 - 35V PRUSSIAN BLUE .75OZ Revision Date 21-Aug-2018 Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes and skin. Wash thoroughly after handling. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents, Acids, Alkalis 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Eyewash stations Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Blue _____________________________________________________________________________________________ Page 3 / 7 _____________________________________________________________________________________________ 80038 - 35V PRUSSIAN BLUE .75OZ Revision Date 21-Aug-2018 Odor Mild Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 0 Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents, Acids, Alkalis Hazardous Decomposition Products Carbon oxides Ammonia 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact May cause redness and tearing of the eyes. Property Values Remarks ? Method pH No information available Melting point / freezing point No information available Boiling point / boiling range > 149 ?C / >300 ?F Flash point > 95 ?C / > 203 ?F Tag Closed Cup Evaporation rate < 1 Butyl acetate = 1 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure <0.01 mm Hg Vapor density >1 Air = 1 Relative density 0.82-0.88 Water solubility Insoluble Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available _____________________________________________________________________________________________ Page 4 / 7 Stable under normal conditions _____________________________________________________________________________________________ 80038 - 35V PRUSSIAN BLUE .75OZ Revision Date 21-Aug-2018 Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse liver effects. Target Organ Effects Eyes, Gastrointestinal tract (GI), Liver, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (dermal) 4499 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 85.01 % of the mixture consists of component(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable _____________________________________________________________________________________________ Page 5 / 7 14. TRANSPORT INFORMATION _____________________________________________________________________________________________ 80038 - 35V PRUSSIAN BLUE .75OZ Revision Date 21-Aug-2018 DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product is not known to contain any chemicals listed as carcinogens or reproductive toxins U.S. State Right-to-Know Regulations _____________________________________________________________________________________________ Page 6 / 7 U.S. EPA Label Information _____________________________________________________________________________________________ 80038 - 35V PRUSSIAN BLUE .75OZ Revision Date 21-Aug-2018 EPA Pesticide Registration Number Not applicable WHMIS Hazard Class Non-controlled 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 21-Aug-2018 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 1 Flammability 1 Instability 0 - HMIS Health hazards 1 Flammability 1 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 7 / 7