SAFETY DATA SHEET Revision Date 07-Jun-2016 Version 1 1. IDENTIFICATION Product identifier Product Name RS-9 BLACK RUBBER SEALANT 1.5FLOZ TB Other means of identification Product Code 80338 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Aspiration toxicity Category 1 Label elements Emergency Overview Manufactured and Distributed by: ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA May Also Be Distributed by: ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Flammable liquids Category 2 Danger Causes skin irritation Causes serious eye irritation May cause drowsiness or dizziness May be fatal if swallowed and enters airways _____________________________________________________________________________________________ Page 1 / 9 Highly flammable liquid and vapor _____________________________________________________________________________________________ 80338 - RS-9 BLACK RUBBER SEALANT 1.5FLOZ TB Revision Date 07-Jun-2016 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep container tightly closed Use only non-sparking tools Take precautionary measures against static discharge Keep cool Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) Get medical advice/attention if you feel unwell IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention If skin irritation occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Very toxic to aquatic life with long lasting effects Unknown acute toxicity 42.4 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret METHYL ETHYL KETONE (BUTANONE) 78-93-3 25-50 * HEPTANE 142-82-5 25-50 * Appearance Black Physical state Liquid Odor Solvent _____________________________________________________________________________________________ Page 2 / 9 _____________________________________________________________________________________________ 80338 - RS-9 BLACK RUBBER SEALANT 1.5FLOZ TB Revision Date 07-Jun-2016 CYCLOHEXANE 110-82-7 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Rinse mouth. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire. Specific hazards arising from the chemical Highly flammable. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Remove all sources of ignition. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. _____________________________________________________________________________________________ Page 3 / 9 _____________________________________________________________________________________________ 80338 - RS-9 BLACK RUBBER SEALANT 1.5FLOZ TB Revision Date 07-Jun-2016 Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH METHYL ETHYL KETONE (BUTANONE) 78-93-3 STEL: 300 ppm TWA: 200 ppm TWA: 200 ppm TWA: 590 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 590 mg/m3 (vacated) STEL: 300 ppm (vacated) STEL: 885 mg/m3 IDLH: 3000 ppm TWA: 200 ppm TWA: 590 mg/m3 STEL: 300 ppm STEL: 885 mg/m3 HEPTANE 142-82-5 STEL: 500 ppm TWA: 400 ppm TWA: 500 ppm TWA: 2000 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 1600 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 2000 mg/m3 IDLH: 750 ppm Ceiling: 440 ppm 15 min Ceiling: 1800 mg/m3 15 min TWA: 85 ppm TWA: 350 mg/m3 CYCLOHEXANE 110-82-7 TWA: 100 ppm TWA: 300 ppm TWA: 1050 mg/m3 (vacated) TWA: 300 ppm (vacated) TWA: 1050 mg/m3 IDLH: 1300 ppm TWA: 300 ppm TWA: 1050 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ 80338 - RS-9 BLACK RUBBER SEALANT 1.5FLOZ TB Revision Date 07-Jun-2016 Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Black Odor Solvent Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 57.6% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Property Values Remarks ? Method pH No information available Melting point / freezing point No information available Boiling point / boiling range 79 ?C / 174 ?F Flash point -4 ?C / 25 ?F Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: 11.5% Lower flammability limit: 1.1% Vapor pressure 79 mm Hg Vapor density No information available Relative density 0.97 Water solubility Immiscible in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature 215 ?C / 419 ?F Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available No data available _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ 80338 - RS-9 BLACK RUBBER SEALANT 1.5FLOZ TB Revision Date 07-Jun-2016 Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) Hydrogen chloride 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 METHYL ETHYL KETONE (BUTANONE) 78-93-3 = 2483 mg/kg ( Rat ) = 2737 mg/kg ( Rat ) = 5000 mg/kg ( Rabbit ) = 6480 mg/kg ( Rabbit ) = 11700 ppm ( Rat ) 4 h HEPTANE 142-82-5 - = 3000 mg/kg ( Rabbit ) = 103 g/m3 ( Rat ) 4 h CYCLOHEXANE 110-82-7 = 12705 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 13.9 mg/L ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available. Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 228690 mg/kg ATEmix (dermal) 5469 mg/kg ATEmix (inhalation-vapor) 24417 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 42.4 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea METHYL ETHYL KETONE (BUTANONE) 78-93-3 - 3130 - 3320: 96 h Pimephales promelas mg/L LC50 flow-through 4025 - 6440: 48 h Daphnia magna mg/L EC50 Static 5091: 48 h Daphnia magna mg/L EC50 520: 48 h Daphnia magna mg/L EC50 HEPTANE 142-82-5 - 375.0: 96 h Cichlid fish mg/L LC50 10: 24 h Daphnia magna mg/L EC50 CYCLOHEXANE 110-82-7 500: 72 h Desmodesmus subspicatus mg/L EC50 3.96 - 5.18: 96 h Pimephales promelas mg/L LC50 flow-through 23.03 - 42.07: 96 h Pimephales promelas mg/L LC50 static 24.99 - 44.69: 96 h Lepomis macrochirus 400: 24 h Daphnia magna mg/L EC50 _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ 80338 - RS-9 BLACK RUBBER SEALANT 1.5FLOZ TB Revision Date 07-Jun-2016 mg/L LC50 static 48.87 - 68.76: 96 h Poecilia reticulata mg/L LC50 static Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient METHYL ETHYL KETONE (BUTANONE) 78-93-3 0.3 HEPTANE 142-82-5 4.66 CYCLOHEXANE 110-82-7 3.44 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes METHYL ETHYL KETONE (BUTANONE) 78-93-3 U159 Included in waste streams: F005, F039 200.0 mg/L regulatory level U159 CYCLOHEXANE 110-82-7 - - - U056 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status METHYL ETHYL KETONE (BUTANONE) 78-93-3 Toxic Ignitable HEPTANE 142-82-5 Toxic Ignitable CYCLOHEXANE 110-82-7 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group II Emergency Response Guide 128 _____________________________________________________________________________________________ Page 7 / 9 _____________________________________________________________________________________________ 80338 - RS-9 BLACK RUBBER SEALANT 1.5FLOZ TB Revision Date 07-Jun-2016 Number IATA UN/ID no ID8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1133 Proper shipping name: Adhesives, Limited Quantity (LQ) Hazard Class 3 Packing Group II EmS-No F-E, S-D 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not determined ENCS Not determined IECSC Not determined KECL Not determined PICCS Not determined AICS Not determined Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % CYCLOHEXANE - 110-82-7 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances CYCLOHEXANE 110-82-7 1000 lb - - X _____________________________________________________________________________________________ Page 8 / 9 CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive _____________________________________________________________________________________________ 80338 - RS-9 BLACK RUBBER SEALANT 1.5FLOZ TB Revision Date 07-Jun-2016 Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) METHYL ETHYL KETONE (BUTANONE) 78-93-3 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ CYCLOHEXANE 110-82-7 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania METHYL ETHYL KETONE (BUTANONE) 78-93-3 X X X HEPTANE 142-82-5 X X X CYCLOHEXANE 110-82-7 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class B2 - Flammable liquid, D2B - Toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 07-Jun-2016 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 3 Instability 0 - HMIS Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 9 / 9