SAFETY DATA SHEET Revision Date 23-Mar-2016 Version 3 1. IDENTIFICATION Product identifier Product Name SURFACE INSENSITIVE THREADLOCKER BLUE 6ML Other means of identification Product Code 24027 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Adhesive Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Skin sensitization Category 1 Specific target organ toxicity (repeated exposure) Category 2 Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Warning Causes skin irritation Causes serious eye irritation May cause an allergic skin reaction May cause damage to organs through prolonged or repeated exposure _____________________________________________________________________________________________ Page 1 / 9 _____________________________________________________________________________________________ 24027 - SURFACE INSENSITIVE THREADLOCKER BLUE 6ML Revision Date 23-Mar-2016 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Contaminated work clothing should not be allowed out of the workplace Do not breathe dust/fume/gas/mist/vapors/spray Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) Get medical advice/attention if you feel unwell IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Not applicable Unknown acute toxicity 70.88 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret POLYGLYCOL DIMETHACRYLATE 25852-47-5 40 - 70 * TETRAETHYLENE GLYCOL HEXOATE 18268-70-7 10 - 30 * POLYVINYL ACETATE 9003-20-7 1 - 5 * SACCHARIN 81-07-2 1 - 5 * DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 1 - 5 * MALEIC ACID 110-16-7 0.1 - 1 * ACRYLIC ACID 79-10-7 0.1 - 1 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures Appearance Blue Physical state Liquid _____________________________________________________________________________________________ Page 2 / 9 Odor Mild _____________________________________________________________________________________________ 24027 - SURFACE INSENSITIVE THREADLOCKER BLUE 6ML Revision Date 23-Mar-2016 General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. In the case of skin irritation or allergic reactions see a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological Information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel _____________________________________________________________________________________________ Page 3 / 9 _____________________________________________________________________________________________ 24027 - SURFACE INSENSITIVE THREADLOCKER BLUE 6ML Revision Date 23-Mar-2016 into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials Strong oxidizing agents, Peroxides, Inert Gases 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ACRYLIC ACID 79-10-7 TWA: 2 ppm S* (vacated) TWA: 10 ppm (vacated) TWA: 30 mg/m3 (vacated) S* TWA: 2 ppm TWA: 6 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Blue Odor Mild Odor threshold No information available Property Values Remarks ? Method pH No information available _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ 24027 - SURFACE INSENSITIVE THREADLOCKER BLUE 6ML Revision Date 23-Mar-2016 Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) <3% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents, Peroxides, Inert Gases Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Ingestion may cause irritation to mucous membranes. Melting point / freezing point No information available Boiling point / boiling range > 150 ?C / >302 ?F Flash point > 95 ?C / > 203 ?F Pensky-Martens Closed Cup (PMCC) Evaporation rate < 1 Butyl acetate = 1 Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density >1 Air = 1 Relative density 1.00-1.15 Water solubility Insoluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available No data available _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ 24027 - SURFACE INSENSITIVE THREADLOCKER BLUE 6ML Revision Date 23-Mar-2016 Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 TETRAETHYLENE GLYCOL HEXOATE 18268-70-7 = 18 g/kg ( Rat ) > 20 mL/kg ( Rabbit ) - DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 = 382 mg/kg ( Rat ) = 0.126 mL/kg ( Rabbit ) = 220 ppm ( Rat ) 4 h MALEIC ACID 110-16-7 = 708 mg/kg ( Rat ) = 1560 mg/kg ( Rabbit ) > 720 mg/m3 ( Rat ) 1 h ACRYLIC ACID 79-10-7 = 193 mg/kg ( Rat ) = 33500 ?g/kg ( Rat ) = 280 ?L/kg ( Rabbit ) = 295 mg/kg ( Rabbit ) = 11.1 mg/L ( Rat ) 1 h = 3.6 mg/L ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA POLYVINYL ACETATE 9003-20-7 - Group 3 - - SACCHARIN 81-07-2 - Group 3 - - ACRYLIC ACID 79-10-7 - Group 3 - - IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5215 mg/kg ATEmix (dermal) 11522 mg/kg ATEmix (inhalation-dust/mist) 9.7 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 93.391 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea SACCHARIN 81-07-2 - 18300: 96 h Pimephales promelas mg/L LC50 - DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 - 3.9: 96 h Oncorhynchus mykiss mg/L LC50 static 7: 24 h Daphnia magna mg/L EC50 MALEIC ACID 110-16-7 - 5: 96 h Pimephales promelas mg/L LC50 static 250 - 400: 48 h Daphnia magna mg/L EC50 ACRYLIC ACID 79-10-7 0.17: 96 h Pseudokirchneriella subcapitata mg/L EC50 0.04: 72 h Desmodesmus subspicatus mg/L EC50 222: 96 h Brachydanio rerio mg/L LC50 semi-static 95: 48 h Daphnia magna mg/L EC50 270: 24 h Daphnia magna mg/L LC50 Static Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ 24027 - SURFACE INSENSITIVE THREADLOCKER BLUE 6ML Revision Date 23-Mar-2016 MALEIC ACID 110-16-7 -0.79 - 0.32 ACRYLIC ACID 79-10-7 0.38 - 0.46 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 - - - U096 ACRYLIC ACID 79-10-7 - - - U008 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 Toxic Ignitable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Not Listed. ENCS Not Listed. IECSC Complies KECL Complies PICCS Not Listed. AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List _____________________________________________________________________________________________ Page 7 / 9 EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances _____________________________________________________________________________________________ 24027 - SURFACE INSENSITIVE THREADLOCKER BLUE 6ML Revision Date 23-Mar-2016 ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % DIMETHYLBENZYL HYDROPEROXIDE - 80-15-9 1.0 SACCHARIN - 81-07-2 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances MALEIC ACID 110-16-7 5000 lb - - X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 10 lb - RQ 10 lb final RQ RQ 4.54 kg final RQ MALEIC ACID 110-16-7 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ ACRYLIC ACID 79-10-7 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania PROPYLENE GLYCOL 57-55-6 X - X DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 X X X SACCHARIN 81-07-2 X X X ACRYLIC ACID 79-10-7 X X X WATER 7732-18-5 - - X _____________________________________________________________________________________________ Page 8 / 9 U.S. EPA Label Information _____________________________________________________________________________________________ 24027 - SURFACE INSENSITIVE THREADLOCKER BLUE 6ML Revision Date 23-Mar-2016 EPA Pesticide Registration Number Not applicable WHMIS Hazard Class D2B - Toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 23-Mar-2016 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 1 Instability 0 - HMIS Health hazards 2 Flammability 1 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 9 / 9