SAFETY DATA SHEET Revision Date 08-Feb-2017 Version 4 1. IDENTIFICATION Product identifier Product Name ULTRA BOND SUPER GLUE 5 GR Other means of identification Product Code 21309 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use This product is a cyanoacrylate-based adhesive Uses advised against No information available Details of the supplier of the safety data sheet 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Label elements Emergency Overview Manufacturer Address ITW Permatex 6875 Parkland Blvd. Solon, OH 44139 USA May Also Be Distributed by: ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Warning Causes skin irritation Causes serious eye irritation May cause respiratory irritation _____________________________________________________________________________________________ Page 1 / 8 _____________________________________________________________________________________________ 21309 - ULTRA BOND SUPER GLUE 5 GR Revision Date 08-Feb-2017 Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Use only outdoors or in a well-ventilated area Precautionary Statements - Response Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Precautionary Statements - Storage Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information - Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children Unknown acute toxicity 9.75 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance(s) Chemical Name CAS No Weight-% Trade Secret ETHYL-2-CYANOACRYLATE 7085-85-0 60 - 100 * 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eyelids are bonded closed, release eyelashes with warm water by covering with a wet pad. If eye irritation persists: Get medical advice/attention. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while Appearance Clear Physical state Liquid Odor Irritating _____________________________________________________________________________________________ Page 2 / 8 _____________________________________________________________________________________________ 21309 - ULTRA BOND SUPER GLUE 5 GR Revision Date 08-Feb-2017 rinsing. If symptoms persist, call a physician. Skin contact IF ON SKIN:. Wash with soap and water. Allow warm water to penetrate the bond and gently attempt to move bonded areas without pulling the skin away from bonded area. If symptoms persist, call a physician. Immediate medical attention is not required. Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If skin irritation persists, call a physician. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Call a physician. Not an expected route of exposure. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Polymerizes with evolution of heat. Keep product and empty container away from heat and sources of ignition. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Flood with water to complete polymerization and scrape off floor. Sweep up and shovel into suitable containers for disposal. _____________________________________________________________________________________________ Page 3 / 8 _____________________________________________________________________________________________ 21309 - ULTRA BOND SUPER GLUE 5 GR Revision Date 08-Feb-2017 Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Incompatible materials Strong oxidizing agents, Water, Amines, Alkalis, Alcohols 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ETHYL-2-CYANOACRYLATE 7085-85-0 TWA: 0.2 ppm - - NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Clear Odor Irritating Odor threshold No information available Property Values Remarks ? Method pH No information available Melting point / freezing point -22 ?C Boiling point / boiling range > 200 ?C / >392 ?F Flash point 80-93.4 ?C / 176-200 ?F _____________________________________________________________________________________________ Page 4 / 8 _____________________________________________________________________________________________ 21309 - ULTRA BOND SUPER GLUE 5 GR Revision Date 08-Feb-2017 Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) <2%; <20 g/l Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions Possibility of Hazardous Reactions Polymerizes with evolution of heat. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents, Water, Amines, Alkalis, Alcohols Hazardous Decomposition Products Carbon oxides Nitrogen oxides (NOx) 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact Will bond to skin. May cause burns. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Ingestion Not an expected route of exposure. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ETHYL-2-CYANOACRYLATE > 5 mL/kg ( Rat ) - - Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure <0.2 mmHg Vapor density 3 Air = 1 Relative density 1.1 Water solubility Not applicable Polymerization Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature 485 ?C / 905 ?F Decomposition temperature No information available Kinematic viscosity 80-150 cps Dynamic viscosity No information available No data available _____________________________________________________________________________________________ Page 5 / 8 _____________________________________________________________________________________________ 21309 - ULTRA BOND SUPER GLUE 5 GR Revision Date 08-Feb-2017 7085-85-0 Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5544 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 99.75 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA UN/ID no UN 3334 Proper shipping name: Aviation regulated liquid, n.o.s, (ethyl cyanoacrylate), Limited Quantity (LQ) Hazard Class 9 _____________________________________________________________________________________________ Page 6 / 8 _____________________________________________________________________________________________ 21309 - ULTRA BOND SUPER GLUE 5 GR Revision Date 08-Feb-2017 Packing Group PGIII ERG Code 9A IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) US State Regulations California Proposition 65 This product is not known to contain any chemicals listed as carcinogens or reproductive toxins. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania ETHYL-2-CYANOACRYLATE 7085-85-0 X - - 1,4-DIHYDROXYBENZENE 123-31-9 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable _____________________________________________________________________________________________ Page 7 / 8 _____________________________________________________________________________________________ 21309 - ULTRA BOND SUPER GLUE 5 GR Revision Date 08-Feb-2017 WHMIS Hazard Class B3 - Combustible liquid, D2A - Very toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 08-Feb-2017 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet NFPA Health hazards 2 Flammability 2 Instability 0 - HMIS Health hazards 2 Flammability 2 Physical hazards 0 Personal protection B _____________________________________________________________________________________________ Page 8 / 8