SDS Repository

sds

Collection
3M SDS
Description
 
Tags
Search Tag
Filename
08090_Brand_Super_Trim_Adhesive.pdf
Source
 
Full Text
2018-09-25 21:31:54.043 7-60793 0026299440 MSDS COORDINATOR FACTORY MOTOR PARTS 5328 W ROOSEVELT PHOENIX, AZ 85043-2713 USA MSDS COORDINATOR editTest editi 3M General Offices 3M Center St. Paul, MN 55144-1000 1-800-364-3577 or (651) 737-6501 (24 hours) Safety Data Sheet Purchase Order #: Customer Number: Dear Enclosed is the Safety Data Sheet (SDS)* for the product that your company recently purchased from 3M. Please forward the attached document(s) to the individual in your organization responsible for hazard communication. If you are a distributor and resell this product, OSHA and EPA require that you transmit this SDS information to your customers at the time of first shipment or whenever you receive revised SDSs from 3M. 3M SDSs are available over the Internet at www.3m.com/MSDSSearch. You may also order a DVD of 3M SDSs by calling 1-800-364-3577. 3M is committed to meeting our customer requirements. Please contact your 3M customer service or sales representative if you have any questions. If you do not know whom to contact, please call the 3M Product Information Center at 1-800-364-3577. If you are not currently receiving 3M SDSs by e-mail and would like to do so, please contact our eSDS Administrator at This email address is being protected from spambots. You need JavaScript enabled to view it. or by calling 651-736-5875. *An Article Information Sheet (AIS) or Article Information Letter (AIL) may be enclosed in place of an SDS if the product is an article which does not require an SDS under the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 1 of 13 Safety Data Sheet Copyright,2018,3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 25-3522-7 Version Number: 6.03 Issue Date: 08/07/18 Supercedes Date: 03/08/18 SECTION 1: Identification 1.1. Product identifier 3M? Brand Super Trim Adhesive, PN 08090 Product Identification Numbers 60-4550-3687-5, 60-4550-5561-0 7000000530 1.2. Recommended use and restrictions on use Recommended use Automotive, Adhesive Aerosol 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. Serious Eye Damage/Irritation: Category 2B. Reproductive Toxicity: Category 1B. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 2 of 13 Signal word Danger Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes eye irritation. May cause drowsiness or dizziness. May damage fertility or the unborn child. May displace oxygen and cause rapid suffocation. Causes damage to organs through prolonged or repeated exposure: nervous system | sensory organs | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 3 of 13 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 34% of the mixture consists of ingredients of unknown acute oral toxicity. 34% of the mixture consists of ingredients of unknown acute dermal toxicity. 32% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Methyl Acetate 79-20-9 30 - 40 Trade Secret * Dimethyl Ether 115-10-6 25 - 35 Trade Secret * Cyclohexane 110-82-7 10 - 20 Trade Secret * Polychloroprene 9010-98-4 1 - 10 Trade Secret * Non-hazardous components (NJTSRN 04499600-7374) Trade Secret* 1 - 10 Trade Secret * Thermoplastic Rubbers Trade Secret* < 10 Trade Secret * Toluene 108-88-3 3 - 7 Trade Secret * Hydrotreated Heavy Naphtha (Petroleum) 64742-48-9 1 - 5 Trade Secret * Antioxidant Trade Secret* 1 - 5 Trade Secret * Benzene, ethenyl-, polymer with 1,3-butadiene and 2- methyl-1,3-butadiene, hydrogenated Trade Secret* 1 - 5 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Wash with soap and water. If signs/symptoms develop, get medical attention. Eye Contact: Flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 4 of 13 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Formaldehyde During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. An appropriate aqueous film forming foam (AFFF) is recommended. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 5 of 13 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Cyclohexane 110-82-7 ACGIH TWA:100 ppm Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Dimethyl Ether 115-10-6 AIHA TWA:1880 mg/m3(1000 ppm) Methyl Acetate 79-20-9 ACGIH TWA:200 ppm;STEL:250 ppm Methyl Acetate 79-20-9 OSHA TWA:610 mg/m3(200 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Gloves made from the following material(s) are recommended: Fluoroelastomer Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 6 of 13 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: Yellow to amber color, mild solvent smell Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point Not Applicable Flash Point -42 ?F Evaporation rate 1.9 [Ref Std:ETHER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure Not Applicable Vapor Density >=1 [Ref Std:AIR=1] Density 0.835 g/ml Specific Gravity 0.835 [Ref Std:WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity Not Applicable Hazardous Air Pollutants 0.50449 lb HAPS/lb solids [Test Method:Calculated] Volatile Organic Compounds 53.4 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 446 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 85.4 % weight [Test Method:Estimated] VOC Less H2O & Exempt Solvents 628 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 7 of 13 SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Prolonged or repeated exposure may cause target organ effects: Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Olfactory Effects: Signs/symptoms may include decreased ability to detect odors and/or complete loss of smell. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 8 of 13 the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE20 - 50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Methyl Acetate Dermal Rat LD50 > 2,000 mg/kg Methyl Acetate Inhalation- Vapor (4 hours) Rat LC50 > 49 mg/l Methyl Acetate Ingestion Rat LD50 > 5,000 mg/kg Dimethyl Ether Inhalation- Gas (4 hours) Rat LC50 164,000 ppm Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Polychloroprene Dermal LD50 estimated to be > 5,000 mg/kg Polychloroprene Ingestion Rat LD50 > 20,000 mg/kg Non-hazardous components (NJTSRN 04499600-7374) Dermal LD50 estimated to be > 5,000 mg/kg Non-hazardous components (NJTSRN 04499600-7374) Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Antioxidant Dermal LD50 estimated to be > 5,000 mg/kg Hydrotreated Heavy Naphtha (Petroleum) Inhalation- Vapor LC50 estimated to be 20 - 50 mg/l Hydrotreated Heavy Naphtha (Petroleum) Dermal Rabbit LD50 > 3,000 mg/kg Antioxidant Ingestion Rat LD50 > 34,000 mg/kg Hydrotreated Heavy Naphtha (Petroleum) Ingestion Rat LD50 > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Methyl Acetate Rabbit No significant irritation Cyclohexane Rabbit Mild irritant Toluene Rabbit Irritant Polychloroprene Human No significant irritation Hydrotreated Heavy Naphtha (Petroleum) Rabbit Irritant Serious Eye Damage/Irritation Name Species Value Methyl Acetate Rabbit Moderate irritant Cyclohexane Rabbit Mild irritant Toluene Rabbit Moderate irritant Polychloroprene Professio nal judgeme nt No significant irritation Hydrotreated Heavy Naphtha (Petroleum) Rabbit No significant irritation Skin Sensitization Name Species Value Methyl Acetate Human Not classified 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 9 of 13 Toluene Guinea pig Not classified Hydrotreated Heavy Naphtha (Petroleum) Guinea pig Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Methyl Acetate In Vitro Not mutagenic Methyl Acetate In vivo Not mutagenic Dimethyl Ether In Vitro Not mutagenic Dimethyl Ether In vivo Not mutagenic Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Hydrotreated Heavy Naphtha (Petroleum) In vivo Not mutagenic Hydrotreated Heavy Naphtha (Petroleum) In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Dimethyl Ether Inhalation Rat Not carcinogenic Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Hydrotreated Heavy Naphtha (Petroleum) Dermal Mouse Some positive data exist, but the data are not sufficient for classification Hydrotreated Heavy Naphtha (Petroleum) Inhalation Human and animal Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Dimethyl Ether Inhalation Not classified for development Rat NOAEL 40,000 ppm during organogenesi s Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9 mg/l 2 generation Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Hydrotreated Heavy Naphtha (Petroleum) Inhalation Not classified for development Rat NOAEL 2.4 mg/l during organogenesi s 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 10 of 13 Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Acetate Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Methyl Acetate Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Methyl Acetate Inhalation blindness Not classified NOAEL Not available Methyl Acetate Ingestion central nervous system depression May cause drowsiness or dizziness NOAEL Not available Dimethyl Ether Inhalation central nervous system depression May cause drowsiness or dizziness Rat LOAEL 10,000 ppm 30 minutes Dimethyl Ether Inhalation cardiac sensitization Some positive data exist, but the data are not sufficient for classification Dog NOAEL 100,000 ppm 5 minutes Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Cyclohexane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Not classified Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Hydrotreated Heavy Naphtha (Petroleum) Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Hydrotreated Heavy Naphtha (Petroleum) Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification NOAEL Not available Hydrotreated Heavy Naphtha (Petroleum) Inhalation nervous system Not classified Dog NOAEL 6.5 mg/l 4 hours Hydrotreated Heavy Naphtha (Petroleum) Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Methyl Acetate Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 1.1 mg/l 28 days Methyl Acetate Inhalation endocrine system | hematopoietic system | liver | immune system | kidney and/or bladder Not classified Rat NOAEL 6.1 mg/l 28 days Dimethyl Ether Inhalation hematopoietic Not classified Rat NOAEL 2 years 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 11 of 13 system 25,000 ppm Dimethyl Ether Inhalation liver Not classified Rat NOAEL 20,000 ppm 30 weeks Cyclohexane Inhalation liver Not classified Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Not classified Rabbit NOAEL 2.7 mg/l 10 weeks Cyclohexane Inhalation hematopoietic system Not classified Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system Not classified Rat NOAEL 8.6 mg/l 30 weeks Toluene Inhalation auditory system | nervous system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Not classified Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Not classified Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Not classified Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Not classified Human NOAEL Not available occupational exposure Toluene Inhalation gastrointestinal tract Not classified Multiple animal species NOAEL 11.3 mg/l 15 weeks Toluene Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 625 mg/kg/day 13 weeks Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Not classified Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Not classified Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day 4 weeks Hydrotreated Heavy Naphtha (Petroleum) Inhalation nervous system Not classified Rat LOAEL 4.6 mg/l 6 months Hydrotreated Heavy Naphtha (Petroleum) Inhalation kidney and/or bladder Not classified Rat LOAEL 1.9 mg/l 13 weeks Hydrotreated Heavy Naphtha (Petroleum) Inhalation respiratory system Not classified Multiple animal species NOAEL 0.6 mg/l 90 days Hydrotreated Heavy Naphtha (Petroleum) Inhalation bone, teeth, nails, and/or hair | blood | liver | muscles Not classified Rat NOAEL 5.6 mg/l 12 weeks Hydrotreated Heavy Naphtha (Petroleum) Inhalation heart Not classified Multiple animal species NOAEL 1.3 mg/l 90 days Aspiration Hazard Name Value Cyclohexane Aspiration hazard 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 12 of 13 Toluene Aspiration hazard Hydrotreated Heavy Naphtha (Petroleum) Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Reproductive toxicity Serious eye damage or eye irritation Simple Asphyxiant Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): 3M? Brand Super Trim Adhesive, PN 08090 08/07/18 __________________________________________________________________________________________ Page 13 of 13 Ingredient C.A.S. No % by Wt Toluene 108-88-3 Trade Secret 3 - 7 Cyclohexane 110-82-7 Trade Secret 10 - 20 15.2. State Regulations Contact 3M for more information. California Proposition 65 Ingredient C.A.S. No. Listing Ethylbenzene 100-41-4 Carcinogen Toluene 108-88-3 Developmental Toxin 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 1 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 2 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 25-3522-7 Version Number: 6.03 Issue Date: 08/07/18 Supercedes Date: 03/08/18 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued.3MMAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE.User is responsible for determining whether the3Mproduct is fit for a particular purpose and suitable for user's method of use or application.Given the variety of factors that can affect the use and application of a3Mproduct, some of which are uniquely within the user's knowledge and control,it is essential that the user evaluate the3Mproduct to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3Mprovides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information,3Mmakes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from3M 3M USA SDSs are available at www.3M.com