SDS - SuperClean Degreaser and SuperClean Foaming Degreaser Preparation Date: 03/08/2016 1 Safety Data Sheet Section 1 ? Identification Product Identifier: SuperClean Degreaser and Foaming Degreaser Other means of Identification: Cleaning Solution Name and Address of Responsible Parties: SuperClean Brands, LLC 1380 Corporate Center Curve, Suite 107 Eagan, MN 55121 Information Telephone #: 1-651-365-7500 24 Hr. Emergency Telephone Number: 1-800-424-9300 Contract Number: CCN644158 Section 2 ? Hazards Identification Classification of the Chemical: Clear light purple liquid. Citrus odor. This material is classified as hazardous under OSHA regulations (29 CFR 1910.1200) (Hazcom 2012). Hazardous classification: Corrosive to Metals ? Category 1 Skin irritation ? Category 2 Eye irritation ? Category 2A Label elements: Signal Word: Warning Hazard Statements: Corrosive liquid. May cause skin irritation. May cause serious eye irritation. Precautionary Statements: Keep only in original container. Store in corrosive resistant container with inner liner. Absorb spillage to prevent material damage. Wash hands thoroughly after handling. If on Skin: Wash with plenty of soap and water. SDS - SuperClean Degreaser and SuperClean Foaming Degreaser Preparation Date: 03/08/2016 2 Section 2 ? Hazards Identification (Continued) If skin irritation occurs get medical advice/attention. Take off contaminated clothing and wash before reuse. Wear protective gloves. Wear eye protection such as goggles or safety glasses with side shields. If in eyes: Rinse cautiously with water for 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists get medical advice/attention. Do not eat, drink or smoke when using this product. If swallowed: Immediately call a poison center/physician. Rinse mouth. Dispose of contents/container in accordance with local, state, federal or international regulations. Hazard Pictogram(s): Other Hazards not otherwise classified: This product contains 7% ingredients of an unknown acute toxicity. See section 11 for more information. Section 3 ? Composition/Information on Ingredients Chemical Name, Common Name CAS # Concentration wt/wt(*) Sodium Metasilicate 6834-92-0 <5 Sodium hydroxide 1310-73-2 <5 Surfactant, blend Trade secret 1-10 * Note: The exact concentrations of the chemical(s) above are being withheld as a trade secret. SDS - SuperClean Degreaser and SuperClean Foaming Degreaser Preparation Date: 03/08/2016 3 Section 4 ? First-Aid Measures Description of first aid measures: Inhalation: If inhaled remove victim to fresh air and keep at rest. Call a poison center or physician if you feel unwell. Skin contact: Wash with plenty of soap and water. Take off contaminated clothing and wash before reuse. If skin irritation occurs get medical advice/attention. Eye contact: If product gets in eyes flush with water for at least 15 minutes. If eye irritation persists seek medical advice/attention. Ingestion: Do NOT induce vomiting unless instructed by medical personal. Never give anything by mouth to an unconscious person. Get medical attention. Most important symptoms and effects, both acute and delayed: May cause skin irritation. May cause serious eye irritation. Ingestion may cause gastrointestinal irritation, nausea, vomiting, diarrhea and burns to the mouth, throat and esophagus. Indication of any immediate medical attention and special treatment needed: Treat symptomatically. Section 5 ? Fire-Fighting Measures Extinguishing media: Suitable extinguishing media: Water fog, Carbon dioxide, Dry chemical, Foam. Unsuitable extinguishing media: Not available. Special hazards arising from the substance or mixture: None known. Flammability classification: Not flammable by OSHA/WHMIS criteria. Hazardous combustion products: Carbon oxides, other unidentified organic compounds. Special protective equipment and precautions for firefighters: Protective equipment for fire-fighters: Firefighters should wear proper protective equipment (Bunker gear) and self-contained breathing apparatus with full face operated in positive pressure mode. SDS - SuperClean Degreaser and SuperClean Foaming Degreaser Preparation Date: 03/08/2016 4 Section 6 ? Accidental Release Measures Personal precautions, protective equipment and emergency procedures: All persons dealing with the clean-up should the appropriate chemically protective equipment. Keep people away from and upwind of spill/leak. Restrict access to area until completion of clean-up. Methods and materials for containment and clean up: If possible, prevention measures should be taken to stop any chemical from entering the ground water system. Ventilate the area. Scoop up material and place into suitable container(s). Dispose of according to local, state and federal regulations. Section 7 ? Handling and Storage Precautions for safe handling: Obtain special instructions before use. Do not handle until all safety precautions have been read and understand. Wear protective gloves and eye/face protection. Adequate ventilation should be supplied. Avoid prolonged contact with skin, eyes and clothing. Keep away from heat. Keep container tightly closed. Conditions for safe storage: Store in cool, dry and well ventilated place. Containers should be clearly identified, clear of obstructions and accessible only to authorized personnel. Have appropriate fire extinguishers/sprinkler system in place. Spill clean-up equipment should be in or near storage area. Incompatible materials: Strong oxidizers, Strong acids. Section 8 ? Exposure Controls/Personal Protection Exposure limits: Chemical Name ACGIH-TLV OSHA-PEL Sodium Metasilicate Not Available 5mg/m3 (TWA) Sodium hydroxide 2mg/m3 2mg/m3 Surfactant, blend Not Available Not Available Exposure controls: Ventilation and Engineering Measures: Use in well ventilated area. Apply technical measures to comply with occupational exposure limits if needed. Respiratory Measures: If airborne concentrations are above the permissible exposure limit, use NIOSH approved respirators. SDS - SuperClean Degreaser and SuperClean Foaming Degreaser Preparation Date: 03/08/2016 5 Section 8 ? Exposure Controls/Personal Protection (Continued) Skin Protection: Wear protective gloves. Where extensive exposure to the product is possible, use resistant apron/suit and boots. Eye/Face Protection: Goggles or safety glasses with side shields. Other Protective Equipment: Ensure that eyewash stations and a safety shower are close to the workstation(s). General Hygiene Considerations: Avoid prolonged contact with eyes, skin and clothing. Do not eat or drink when using this product. Wash hands after handling. Remove and wash all contaminated clothing before re-use. Handle in accordance with good industrial hygiene and safety practice. Section 9 ? Physical and Chemical Properties Appearance: Clear light purple liquid. Odor: Citrus Odor Odor threshold: Not available PH: 12.5 -13.8 Melting/Freezing pointing: ~ -3C (26.6F) Boiling point and boiling range: >100C (212F) Flash point: >93.3C (199.4F) Evaporation point (Butyl Acetate=1): Not available. Flammability (method determination): Not available. Lower flammability limit (% by vol.): Not available. Upper flammability limit (% by vol.): Not available. Vapor pressure: Not available. Vapor density: Not available. Relative density: 1.00 ? 1.05 Solubility in water: Complete. Partition Coefficient (n-octanol/water): Not available. Auto ignition temperature: Not available. Decomposition temperature: Not available. Viscosity: Not available. Volatiles (% by wt) = 0% Volatile organic compounds: Not available. Other physical/chemical comments: No addition information. Section 10 ? Stability and Reactivity Reactivity: Not normally reactive. Chemical stability: Stable under normal conditions. SDS - SuperClean Degreaser and SuperClean Foaming Degreaser Preparation Date: 03/08/2016 6 Section 10 ? Stability and Reactivity (Continued) Possibility of hazardous reactions: Hazardous polymerization does not occur. Conditions to avoid: Heat. Contact with incompatible materials. Incompatible materials: Strong oxidizers, Strong acids. Avoid contact with glass. Hazardous decomposition products: Carbon oxides. Section 11 ? Toxicological Information Information on routes of exposure: Routes of entry - Inhalation: YES Routes of entry - Skin & Eye: YES Routes of entry - Ingestion: YES Routes of entry - Skin Absorption: YES Potential Health Effects: Signs and symptoms of short term exposure: Signs and symptoms: Inhalation ? May cause respiratory irritation. Signs and symptoms: Ingestion ? Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Larger amounts may cause burns to the throat and esophagus. Signs and symptoms: Skin ? May cause irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Signs and symptoms: Eyes ? May cause serious irritation. Potential Chronic Health Effects: None known. Mutagenicity: Not hazardous by OSHA/WHMIS criteria. Carcinogenicity: No components are listed as carcinogens by ACGIH, IARC, OSHA or NTP. Reproductive effects: Not hazardous by OSHA/WHMIS criteria. Sensitization to material: No data available to indicate product may be a sensitizer. Specific target organ effects: Not Available. SDS - SuperClean Degreaser and SuperClean Foaming Degreaser Preparation Date: 03/08/2016 7 Section 11 ? Toxicological Information (Continued) Medical conditions aggravated by overexposure: Pre-existing skin and eye conditions. Toxicological data: The calculated ATE value for this mixture is well above classification parameters. ATE (oral) = 21,690mg/kg Chemical Name LD50-Oral Dermal Sodium Metasilicate 847mg/kg (Rat) Not Available Sodium hydroxide 500mg/kg (Rabbit) Not Available Surfactant, blend Not Available Not Available Section 12 ? Ecological Information Ecotoxicity: This product itself has not been tested. Mobility is soil: This product itself has not been tested. Persistence and degradability: This product itself has not been tested. Bioaccumulation potential: This product itself has not been tested. Other adverse environmental effects: None Known. Section 13 ? Disposal Information Handling for disposal: Handle in accordance with good industrial hygiene and safety practice. Refer to protective measures listed in sections 7 and 8. Methods of disposal: Dispose in accordance with all applicable federal, state, provincial and local regulation. Contact your federal, state, provincial and local authorities for specific rules. Section 14 ? Transportation Information US 49 CFR/DOT. Ground Transportation? UN No.: UN3266 UN Proper shipping name: Corrosive liquid, basic, inorganic, N.O.S., (sodium hydroxide, sodium metasilicate). Transport hazard class: 8 Packing group: II ERG: 154 Special Transportation Notes: May be shipped as Limited Quantity by ground per provisions of CFR 49 173.154 (b). SDS - SuperClean Degreaser and SuperClean Foaming Degreaser Preparation Date: 03/08/2016 8 Section 15 ? Regulatory Information US Federal Information: TSCA: All listed ingredients appear on the Toxic Substances Control Act. US CERCLA Reportable quantity (RQ): Sodium hydroxide 1,000 lbs. SARA Title III: Sec. 302, Extremely Hazardous Substances, 40 CFR 355: No extremely hazardous substances are present in this material. SARA Title III: Sec. 311 and 312, MSDS Requirements, 40 CFR 370 Hazard Classes: Reactive Hazard, Acute Health Hazard, Chronic Health Hazard. Under SARA Section 311 and 312, the EPA has established threshold quantities for the reporting of hazardous chemicals. The current thresholds are 500 pounds for the threshold planning quantity (TPQ), whichever is lower, for extremely hazardous substances and 10,000 pounds for all other hazardous chemicals. SARA Title III: Sec. 313, Toxic Chemicals Notification, 40 CFR 372: No components are present in this material. State Regulations: California Proposition 65: This product does not contain a chemical known to the State of California to cause, birth defects or other reproductive harm. International Information: Canadian Environmental Protection Act (CEPA) information: All ingredients listed appear on the Domestic Substances List (DSL). Section 16 ? Other Information HMIS ? Hazardous Materials Identification System Health -2 Flammability -1 Physical Hazard -1 PPE ?B NFPA ? National Fire Protection Association Health -2 Flammability -1 Reactivity -1 Abbreviations legend: ACGIH: American Conference of Governmental Industrial Hygienist CAS: Chemical abstract Services CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act of 1980 CFR: Code of Federal Regulations CSA: Canadian Standards Association DOT: Department of Transportation ECOTOX: U.S. EPA Ecotoxicology Database EINECS: European Inventory of Existing Commercial chemical Substances SDS - SuperClean Degreaser and SuperClean Foaming Degreaser Preparation Date: 03/08/2016 9 Section 16 ? Other Information (Continued) EPA: Environmental Protection agency HSDB: Hazardous Substances database IARC: International Agency for Research on Cancer IBC: Intermediate Bulk Container IUCLID: International Uniform Chemical Information Database LC: Lethal Concentration LD: Lethal Dose NIOSH: National Institute of Occupational Safety and Health NTP: National Toxicology Program OECD: Organization for Economic Cooperation and Development PEL: Permissible exposure limit RCRA: Resource Conservation and Recovery Act RTECS: Registry of Toxic Effects of Chemical Substances SARA: Superfund Amendments and Reauthorization Act SDS: Safety Data Sheet STEL: Short Term Exposure Limit TDG: Canadian Transportation of Dangerous Goods Act & Regulations TLV: Threshold Limit Values TWA: Time Weighted Average WHMIS: Workplace Hazardous Materials Identification System Disclaimer The information continued herein is based on the manufactures? own study and the work of others, implied, as to the accuracy, completeness or adequacy of the information contained herein, and neither the provider nor the manufacturer (nor the agents, directors, officers, contractors or employees of either) are liable to any party for any damages of any nature, including direct, special or consequential damages arising out of or in connection with the accuracy, completeness, adequacy or furnishing of any information in this SDS, or in any other way related (directly or indirectly) to this SDS. The information provided on this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for the safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any other process. Version: 1.0 ? Initial Release Version 2.0 ? Corrected Pictogram Information End of Document