JOHNSEN'S DUSTER R152A 10 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 03/09/2017 Supersedes:09/02/2015 Version: 1.2 09/03/2017 EN (English US) 1/8 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Trade name : JOHNSEN'S DUSTER R152A 10 OZ. CAS No : 75-37-6 Product code : 4607 Formula : C2H4F2 Synonyms : 1,1-difluoroethane / 1,1-Difluoroethane (refrigerant gas R 152a) / algofrene type 67 / difluoroethane / dymel 152 / dymel 152A / ethane, 1,1-difluoro- / ethylene fluoride (=1,1- difluoroethane) / ethylidene difluoride / ethylidene fluoride / FC 152A / fluorocarbon 152A / freon 152 / freon 152A / genetron 100 / genetron 152 / genetron 152A / halocarbon R 152A / HCFC- 152a / HCFC-152A / HFC-152a / hydrofluorocarbon 152A / refrigerant 152A 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Aerosol Duster 1.3. Details of the supplier of the safety data sheet Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Liquefied gas H280 Full text of H statements : see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS04 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H280 - Contains gas under pressure; may explode if heated Precautionary statements (GHS-US) : P410+P403 - Protect from sunlight. Store in a well-ventilated place P251 - Pressurized container: Do not pierce or burn, even after use P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F 2.3. Other hazards Other hazards not contributing to the classification : In accordance with aerosol flammability definitions, this product is non-flammable. However, the pressurized liquified gas is extremely flammable. Using this product in an upside-down position, or shaking while using, can cause liquid product to be expelled. The information pertaining to flash point below applies to the liquefied gas. Contact with liquid may cause cold burns/frostbite. Contains gas under pressure; may explode if heated. Asphyxiant in high concentrations. Intentional misuse and inhalation abuse may cause cardiac or central nervous systems effects. Warning. May Cause frostbite in contact with skin. (Liquid form can be ejected if the aerosol can is not held upright during use.) Warning. This product dispenses liquid. Liquid may drip onto skin causing frostbite, blistering, red skin. WARNING. 2.4. Unknown acute toxicity (GHS US) No data available SECTION 3: Composition/Information on ingredients 3.1. Substance Name Product identifier % GHS-US classification 1,1-Difluoroethane, Liquefied, Under Pressure (Main constituent) (CAS No) 75-37-6 > 99 Liquefied gas, H280 Full text of H-phrases: see section 16 JOHNSEN'S DUSTER R152A 10 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/03/2017 EN (English US) 2/8 3.2. Mixture Not applicable The exact percentage is a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with laboured breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. Never give alcohol to drink. First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. First-aid measures after skin contact : Rinse with water. In case of frostbites: Wash immediately with lots of water (15 minutes)/shower. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital. First-aid measures after eye contact : Rinse with water. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists. First-aid measures after ingestion : Not applicable. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Contains refrigerated gas; may cause cryogenic burns or injury. Symptoms/injuries after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Dizziness. Slight irritation. Headache. Nausea. Vomiting. Coordination disorders. Disturbances of consciousness. Disturbances of heart rate. Symptoms/injuries after skin contact : Frostbites. Symptoms/injuries after eye contact : No data available. Symptoms/injuries after ingestion : Not applicable. Chronic symptoms : No effects known. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water spray. BC powder. Carbon dioxide. Unsuitable extinguishing media : No unsuitable extinguishing media known. 5.2. Special hazards arising from the substance or mixture Fire hazard : DIRECT FIRE HAZARD. Extremely flammable. Gas/vapour flammable with air within explosion limits. INDIRECT FIRE HAZARD. May build up electrostatic charges: risk of ignition. May be ignited by sparks. Gas/vapour spreads at floor level: ignition hazard. Explosion hazard : DIRECT EXPLOSION HAZARD. Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD. Heat may cause pressure rise in tanks/drums: explosion risk. may be ignited by sparks. Reactivity : On heating/burning: release of toxic and corrosive gases/vapours e.g.: hydrofluoric acid, carbonylfluoride. Reacts violently with (strong) oxidizers. 5.3. Advice for firefighters Firefighting instructions : If no hazard for/from the surroundings: controlled burning. If hazardous substances are nearby: consider extinguishment. Extinguish only if gas supply/leak can be shut afterwards. Cool tanks/drums with water spray/remove them into safety. Physical explosion risk: extinguish/cool from behind cover. Do not move the load if exposed to heat. After cooling: persistant risk of physical explosion. Dilute toxic gases with water spray. Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus. Other information : NFPA Aerosol Level 1. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. 6.1.1. For non-emergency personnel Protective equipment : Insulating gloves. Protective goggles. Protective clothing. Large spills/in enclosed spaces: compressed air apparatus. See "Material-Handling" to select protective clothing. JOHNSEN'S DUSTER R152A 10 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/03/2017 EN (English US) 3/8 Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Seal off low-lying areas. Close doors and windows of adjacent premises. Stop engines and no smoking. No naked flames or sparks. Spark- and explosionproof appliances and lighting equipment. Avoid ingress of water in the containers. Wash contaminated clothes. 6.1.2. For emergency responders No additional information available 6.2. Environmental precautions Prevent spreading in sewers. 6.3. Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to select material of containers. Plug the leak, cut off the supply. Dam up the liquid spill. Tip the container on one side to stop the leakage. Try to reduce evaporation. Measure the concentration of the explosive gas-air mixture. Dilute/disperse combustible gas/vapour with water curtain. Provide equipment/receptacles with earthing. Do not spray water on unheated tank walls. Do not use compressed air for pumping over spills. Methods for cleaning up : Damaged/cooled tanks must be emptied. Do not use compressed air for pumping over spills. See "Material-handling" for suitable container materials. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling. 6.4. Reference to other sections No additional information available SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling : Comply with the legal requirements. Clean contaminated clothing. Handle uncleaned empty containers as full ones. Thoroughly clean/dry the installation before use. Do not use compressed air for pumping over. Use spark-/explosionproof appliances and lighting system. Take precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Observe normal hygiene standards. Measure the concentration in the air regularly. Measure the oxygen concentration in the air. Work under local exhaust/ventilation. Hygiene measures : Do not eat, drink or smoke when using this product. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Wash affected areas thoroughly after handling. Wash contaminated clothing before reuse. Always wash hands after handling the product. Remove contaminated clothes. Separate working clothes from town clothes. Launder separately. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Comply with applicable regulations. Storage conditions : Do not expose to temperatures exceeding 50 ?C/ 122 ?F. Incompatible materials : Direct sunlight. Storage temperature : < 50 ?C Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources. Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. Storage area : Ventilation at floor level. Fireproof storeroom. Provide for an automatic sprinkler system. Provide for a tub to collect spills. Provide the tank with earthing. Keep out of direct sunlight. Meet the legal requirements. Special rules on packaging : SPECIAL REQUIREMENTS: with pressure relief valve. clean. correctly labelled. meet the legal requirements. Packaging materials : SUITABLE MATERIAL: steel. stainless steel. monel steel. lead. aluminium. copper. tin. 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station. Personal protective equipment : Gloves. Safety glasses. JOHNSEN'S DUSTER R152A 10 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/03/2017 EN (English US) 4/8 Materials for protective clothing : GIVE GOOD RESISTANCE: butyl rubber. leather. neoprene. polyethylene. PVC. Hand protection : Insulated gloves. Eye protection : Safety glasses. Skin and body protection : Protective clothing. Respiratory protection : High vapour/gas concentration: self-contained respirator. Maintain oxygen levels above 19.5% in the workplace. Use supplied air respiratory protection if oxygen levels are below 19.5% or during emergency response to a release of this product. Environmental exposure controls : Avoid release to the environment. Consumer exposure controls : Avoid contact during pregnancy/while nursing. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas Appearance : Liquefied gas. Molecular mass : 66.05 g/mol Color : Colourless. Odor : Odourless. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : -117 ?C Freezing point : No data available Boiling point : -25 ?C Flash point : < -50 ?C Critical temperature : 114 ?C Auto-ignition temperature : 455 ?C Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 5100 hPa (20 ?C) Vapor pressure at 50 ?C : 11700 hPa (50 ?C) Critical pressure : 44960 hPa Relative vapor density at 20 ?C : 2.3 Relative density : 1.0 @ -25 deg C Specific gravity / density : 1004 kg/m? @ -25 deg C Solubility : Poorly soluble in water. Soluble in organic solvents. Water: 0.54 g/100ml @ 0 deg C Log Pow : 0.75 (Experimental value) Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : 0.37 Pa.s @ -31 deg C Explosive properties : No data available Oxidizing properties : No data available Explosion limits : 4 - 19 vol % 112 - 518 g/m? 9.2. Other information VOC content : 100 % VOC Exempt Gas group : Liquefied gas Other properties : Gas/vapour heavier than air at 20?C. May generate electrostatic charges. SECTION 10: Stability and reactivity 10.1. Reactivity On heating/burning: release of toxic and corrosive gases/vapours e.g.: hydrofluoric acid, carbonylfluoride. Reacts violently with (strong) oxidizers. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No additional information available JOHNSEN'S DUSTER R152A 10 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/03/2017 EN (English US) 5/8 10.4. Conditions to avoid No additional information available 10.5. Incompatible materials No additional information available 10.6. Hazardous decomposition products No additional information available SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified JOHNSEN'S DUSTER R152A 10 OZ. ( \f )75-37-6 LC50 inhalation rat (mg/l) 176 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) > 437500 ppm/4h Mortality in 2/6 at 43.75% and 1/6 at 38.3%. At ? 17.52% lethargy, laboured breathing, reduced responsiveness to sound were observed. At 6.64% only hyperaemia and shallow breathing were observed. Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Symptoms/injuries after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Dizziness. Slight irritation. Headache. Nausea. Vomiting. Coordination disorders. Disturbances of consciousness. Disturbances of heart rate. Symptoms/injuries after skin contact : Frostbites. Symptoms/injuries after eye contact : No data available. Symptoms/injuries after ingestion : Not applicable. Chronic symptoms : No effects known. SECTION 12: Ecological information 12.1. Toxicity Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Included in the list of fluorinated greenhouse gases (Regulation (EC) No 842/2006). TA-Luft Klasse 5.2.5. Ecology - water : Mild water pollutant (surface water). No data available on ecotoxicity. 12.2. Persistence and degradability JOHNSEN'S DUSTER R152A 10 OZ. (75-37-6) Persistence and degradability Biodegradability in water: no data available. 12.3. Bioaccumulative potential JOHNSEN'S DUSTER R152A 10 OZ. (75-37-6) Log Pow 0.75 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available JOHNSEN'S DUSTER R152A 10 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/03/2017 EN (English US) 6/8 SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Refer to manufacturer/supplier for information on recovery/ recycling. Additional information : LWCA (the Netherlands): KGA category 06. Hazardous waste according to Directive 2008/98/EC. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): UN1950, Aerosols, Flammable, 2.1, Limited Quantity ICAO/IATA (air): UN1950, Aerosols, Flammable, 2.1 , Limited Quantity IMO/IMDG (water): UN1950, Aerosols, Flammable, 2.1 , Limited Quantity Special Provisions: N82 - See 173.306 of this subchapter for classification criteria for flammable aerosols Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : Aerosols, Flammable Flammable, (each not exceeding 1 L capacity) Class (DOT) : 2.1 - Class 2.1 - Flammable gas 49 CFR 173.115 Hazard labels (DOT) : 2.1 - Flammable gas DOT Special Provisions (49 CFR 172.102) : N82 - See 173.306 of this subchapter for classification criteria for flammable aerosols DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Packaging Non Bulk (49 CFR 173.xxx) : None DOT Packaging Bulk (49 CFR 173.xxx) : None 14.3. Additional information Emergency Response Guide (ERG) Number : 126 Other information : No supplementary information available. Special transport precautions : DOT-SP 11516: In accordance with this special permit, this product is not subject to labeling requirements unless offered for transportation by air. This product is not subject to placarding requirements. Outside packaging must be marked with proper shipping description and 'DOT- SP 11516'. Overland transport Class (ADR) : 2 - Gases Hazard identification number (Kemler No.) : 23 Classification code (ADR) : 2F Hazard labels (ADR) : 2.1 - Flammable gases Orange plates : Tunnel restriction code (ADR) : B/D Transport by sea DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel JOHNSEN'S DUSTER R152A 10 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/03/2017 EN (English US) 7/8 DOT Vessel Stowage Other : 25 - Shade from radiant heat,87 - Stow ??separated from?? Class 1 (explosives) except Division 14,126 - Segregation same as for Class 9, miscellaneous hazardous materials EmS-No. (1) : F-D EmS-No. (2) : S-U Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 75 kg DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 150 kg SECTION 15: Regulatory information 15.1. US Federal regulations JOHNSEN'S DUSTER R152A 10 OZ. (75-37-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Fire hazard Sudden release of pressure hazard Immediate (acute) health hazard 15.2. International regulations CANADA JOHNSEN'S DUSTER R152A 10 OZ. (75-37-6) WHMIS Classification Class A - Compressed Gas Class B Division 5 - Flammable Aerosol EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Flam. Gas 1 H220 Press. Gas Full text of hazard classes and H-statements : see section 16 Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] F+; R12 Full text of R-phrases: see section 16 15.2.2. National regulations No additional information available 15.3. US State regulations JOHNSEN'S DUSTER R152A 10 OZ. (75-37-6) U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No State or local regulations U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Massachusetts - Right To Know List SECTION 16: Other information Full text of H-phrases: ------ H280 Contains gas under pressure; may explode if heated NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 4 - Will rapidly or completely vaporize at normal pressure and temperature, or is readily dispersed in air and will burn readily. JOHNSEN'S DUSTER R152A 10 OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/03/2017 EN (English US) 8/8 NFPA reactivity : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 4 Severe Hazard Physical : 1 Slight Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this SDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.