JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 12/20/2016 Supersedes:04/08/2016 Version: 1.2 20/12/2016 EN (English US) 1/6 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. Product code : 4625 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Engine Stop Leak 1.3. Details of the supplier of the safety data sheet Technical Chemical Company P.O. BOX 139 Cleburne, Texas 76033 T 817-645-6088 1.4. Emergency telephone number Emergency number : CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Asp. Tox. 1 H304 Full text of H statements : see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H304 - May be fatal if swallowed and enters airways Precautionary statements (GHS-US) : P301+P310 - If swallowed: Immediately call a poison control center, doctor,physician, P331 - Do NOT induce vomiting P405 - Store locked up P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. 2.3. Other hazards Other hazards not contributing to the classification : None under normal conditions. 2.4. Unknown acute toxicity (GHS US) No data available SECTION 3: Composition/Information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Distillates (Petroleum), Hydrotreated Heavy Naphthenic (CAS No) 64742-52-5 >= 95 Asp. Tox. 1, H304 Diisodecyl Adipate (CAS No) 27178-16-1 1 - 5 Not classified The exact percentage is a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 20/12/2016 EN (English US) 2/6 First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause irritation or asthma-like symptoms. Symptoms/injuries after skin contact : May cause slight irritation . Itching. Red skin. Skin rash/inflammation. Symptoms/injuries after eye contact : May cause slight eye irritation . Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Separate working clothes from town clothes. Launder separately. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Always wash hands after handling the product. Remove contaminated clothes. Wash affected areas thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 20/12/2016 EN (English US) 3/6 7.3. Specific end use(s) Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? MIST 8 HOURS USA OSHA OSHA PEL (TWA) (mg/m?) 5 mg/m? MIST 8 HOURS 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods . Ensure good ventilation of the work station. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear respiratory protection. Consumer exposure controls : Avoid contact during pregnancy/while nursing. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. Color : Red. Odor : Petroleum-like odour. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : 0 ?C Freezing point : No data available Boiling point : > 100 ?C Flash point : 174 ?C Auto-ignition temperature : 315 ?C Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : < 0.011 kPa Relative vapor density at 20 ?C : No data available Relative density : 0.9 Solubility : Insoluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : 19.5 cSt @ 40 deg C Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosion limits : No data available 9.2. Other information VOC content : < 1 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 20/12/2016 EN (English US) 4/6 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) LD50 oral rat > 5000 mg/kg body weight Diisodecyl Adipate (27178-16-1) LD50 oral rat 20500 mg/kg (Rat) LD50 dermal rat > 5000 mg/kg (Rat) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Based on available data, the classification criteria are not met Carcinogenicity : Not classified Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) IARC group 3 Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : May be fatal if swallowed and enters airways. Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : May cause irritation or asthma-like symptoms. Symptoms/injuries after skin contact : May cause slight irritation . Itching. Red skin. Skin rash/inflammation. Symptoms/injuries after eye contact : May cause slight eye irritation . Inflammation/damage of the eye tissue. Irritation of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. SECTION 12: Ecological information 12.1. Toxicity No additional information available 12.2. Persistence and degradability JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. Persistence and degradability Not established. Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) Persistence and degradability Not established. Diisodecyl Adipate (27178-16-1) Persistence and degradability Biodegradability in water: no data available. 12.3. Bioaccumulative potential JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. Bioaccumulative potential Not established. Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) Bioaccumulative potential Not established. JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 20/12/2016 EN (English US) 5/6 Diisodecyl Adipate (27178-16-1) Bioaccumulative potential No bioaccumulation data available. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. . Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. Hazardous waste due to toxicity. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN US DOT (ground): Not regulated, ICAO/IATA (air): Not Regulated, IMO/IMDG (water): Not Regulated, Not applicable 14.2. UN proper shipping name Proper Shipping Name (DOT) : Not regulated 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) SARA Section 311/312 Hazard Classes Delayed (chronic) health hazard 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Carc.Cat.2; R45 Full text of R-phrases: see section 16 15.2.2. National regulations No additional information available JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 20/12/2016 EN (English US) 6/6 15.3. US State regulations JOHNSEN'S ENGINE OIL STOP LEAK 12 FL.OZ. U.S. - California - Proposition 65 - Carcinogens List No U.S. - California - Proposition 65 - Developmental Toxicity No U.S. - California - Proposition 65 - Reproductive Toxicity - Female No U.S. - California - Proposition 65 - Reproductive Toxicity - Male No Distillates (Petroleum), Hydrotreated Heavy Naphthenic (64742-52-5) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Non-significant risk level (NSRL) No No No No Diisodecyl Adipate (27178-16-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male Non-significant risk level (NSRL) No No No No SECTION 16: Other information Indication of changes : Revision - See : *. Other information : None. Full text of H-phrases: ------ H304 May be fatal if swallowed and enters airways NFPA health hazard : 1 - Exposure could cause irritation but only minor residual injury even if no treatment is given. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 1 Slight Hazard Physical : 0 Minimal Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC The Supplier identified in Section 1 of this MSDS has evaluated this product and certifies it to be labeled and packaged in compliance with the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product Safety Commission, and where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have been tested in accordance with the latest protocols. No other testing is required to certify compliance with the above. The date of manufacture is stamped on the product Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied.