SAFETY DATA SHEET 1. Identification Product identifier Air Brake Anti-Freeze & Conditioner Other means of identification Product code 05528, 05555 Recommended use Air brake anti-freeze Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Category 2Flammable liquidsPhysical hazards Category 3Acute toxicity, oralHealth hazards Category 3Acute toxicity, dermal Category 3Acute toxicity, inhalation Category 2Reproductive toxicity Category 1Specific target organ toxicity, single exposure Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Suspected of damaging fertility or the unborn child. Causes damage to organs (eyes, central nervous system). Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. 1 / 9 Material name: Air Brake Anti-Freeze & Conditioner 05528, 05555 Version #: 01 Issue date: 03-24-2015 SDS US Response If swallowed: Immediately call a poison center/doctor. Rinse mouth. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. If exposed or concerned: Get medical attention. In case of fire: Do not use water jet as an extinguisher, as this will spread the fire. Storage Store in a well-ventilated place. Keep container tightly closed. Keep cool. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 67-56-1Methanol 90 - 100 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a POISON CENTER or doctor/physician. Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical advice/attention if you feel unwell. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Most important symptoms/effects, acute and delayed Dizziness. Headache. Nausea, vomiting. Irritation of eyes and mucous membranes. Upper respiratory tract irritation. Skin irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information Take off immediately all contaminated clothing. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire-fighting equipment/instructions In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. General fire hazards Highly flammable liquid and vapor. 2 / 9 Material name: Air Brake Anti-Freeze & Conditioner 05528, 05555 Version #: 01 Issue date: 03-24-2015 SDS US 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewer, basements or confined areas. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not breathe mist or vapor. Avoid contact with eyes, skin, and clothing. Do not taste or swallow. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Wash contaminated clothing before reuse. For product usage instructions, please see the product label. Conditions for safe storage, including any incompatibilities Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. Keep container tightly closed. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 260 mg/m3Methanol (CAS 67-56-1) 200 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 250 ppmMethanol (CAS 67-56-1) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type STEL 325 mg/m3Methanol (CAS 67-56-1) 250 ppm 3 / 9 Material name: Air Brake Anti-Freeze & Conditioner 05528, 05555 Version #: 01 Issue date: 03-24-2015 SDS US US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 260 mg/m3 200 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 15 mg/l Methanol Urine *Methanol (CAS 67-56-1) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Methanol (CAS 67-56-1) Skin designation applies. US - Tennessee OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as: Nitrile. Rubber. Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Colorless. Odor Pungent. Alcoholic. Odor threshold Not available. pH Not available. Melting point/freezing point -144 ?F (-97.8 ?C) estimated Initial boiling point and boiling range 148.5 ?F (64.7 ?C) estimated Flash point 54 ?F (12.2 ?C) Tag Closed Cup Evaporation rate Fast. Flammability (solid, gas) Not available. 4 / 9 Material name: Air Brake Anti-Freeze & Conditioner 05528, 05555 Version #: 01 Issue date: 03-24-2015 SDS US Upper/lower flammability or explosive limits Flammability limit - lower (%) 2.6 % estimated Flammability limit - upper (%) 36 % estimated Vapor pressure 133.2 hPa estimated Vapor density 1.1 (air = 1) Relative density 0.79 Solubility (water) Completely soluble. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 725 ?F (385 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 99.9 % estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Carbon oxides. Formaldehyde. 11. Toxicological information Information on likely routes of exposure Ingestion Toxic if swallowed. Even small amounts (30-250 ml methanol) may be fatal. Symptoms are stomach ache, nausea, vomiting, dullness, visual disorder and blindness. Inhalation Toxic if inhaled. Skin contact Toxic in contact with skin. Eye contact Direct contact with eyes may cause temporary irritation. Symptoms related to the physical, chemical and toxicological characteristics Dizziness. Headache. Nausea, vomiting. Irritation of eyes and mucous membranes. Upper respiratory tract irritation. Skin irritation. Information on toxicological effects Acute toxicity Toxic if inhaled. Toxic in contact with skin. Toxic if swallowed. Test ResultsProduct Species Air Brake Anti-Freeze & Conditioner LD50 Rabbit Dermal Acute 12816.9443 mg/kg estimated LC50 Rat Inhalation 64084.7188 ppm, 4 hours estimated 83.981 mg/l, 4 hours estimated LD50 Human Oral 50.0662 mg/kg estimated Rat 5627.0654 mg/kg estimated LDL0 Human 300.3971 mg/kg estimated * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. 5 / 9 Material name: Air Brake Anti-Freeze & Conditioner 05528, 05555 Version #: 01 Issue date: 03-24-2015 SDS US Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity Suspected of damaging fertility or the unborn child. Specific target organ toxicity - single exposure Causes damage to organs: Eyes. Central nervous system. Even small amounts (30-250 ml methanol) may be fatal. Symptoms are stomach ache, nausea, vomiting, dullness, visual disorder and blindness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be an aspiration hazard. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Product Test ResultsSpecies Air Brake Anti-Freeze & Conditioner Aquatic Acute EC50Crustacea 16121.3125 mg/l, 48 hours estimatedDaphnia LC50Fish 22749.9609 mg/l, 96 hours estimatedFish Components Test ResultsSpecies Methanol (CAS 67-56-1) Aquatic LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Acute EC50Crustacea > 10000 mg/l, 48 hoursWater flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) Methanol -0.77 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from residues / unused products If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. Hazardous waste code D001: Waste Flammable material with a flash point <140 F F003: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent US RCRA Hazardous Waste U List: Reference Methanol (CAS 67-56-1) U154 Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 6 / 9 Material name: Air Brake Anti-Freeze & Conditioner 05528, 05555 Version #: 01 Issue date: 03-24-2015 SDS US 14. Transport information DOT UN1230UN number MethanolUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IB2, T7, TP2Special provisions 150Packaging exceptions 202Packaging non bulk 242Packaging bulk IATA UN1230UN number MethanolUN proper shipping name 3Class Transport hazard class(es) 6.1Subsidiary risk IIPacking group No.Environmental hazards 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only IMDG UN1230UN number METHANOLUN proper shipping name 3Class Transport hazard class(es) 6.1Subsidiary risk IIPacking group No.Marine pollutant Environmental hazards F-E, S-DEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Methanol (CAS 67-56-1) CERCLA Hazardous Substance List (40 CFR 302.4) Methanol (CAS 67-56-1) CERCLA Hazardous Substances: Reportable quantity Methanol (CAS 67-56-1) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. 7 / 9 Material name: Air Brake Anti-Freeze & Conditioner 05528, 05555 Version #: 01 Issue date: 03-24-2015 SDS US Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Methanol (CAS 67-56-1) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Food and Drug Administration (FDA) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance No US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Methanol (CAS 67-56-1) US. Massachusetts RTK - Substance List Methanol (CAS 67-56-1) US. Pennsylvania Worker and Community Right-to-Know Law Methanol (CAS 67-56-1) US. Rhode Island RTK Methanol (CAS 67-56-1) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Developmental toxin Methanol (CAS 67-56-1) Listed: March 16, 2012 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 100 % Consumer products (40 CFR 59, Subpt. C) Not regulated State Consumer products Not regulated VOC content (CA) 100 % VOC content (OTC) 100 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) YesJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory 8 / 9 Material name: Air Brake Anti-Freeze & Conditioner 05528, 05555 Version #: 01 Issue date: 03-24-2015 SDS US Country(s) or region Inventory name On inventory (yes/no)* YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 03-24-2015 Prepared by Allison Cho Version # 01 Further information CRC # 620B HMIS? ratings Health: 2* Flammability: 3 Physical hazard: 0 Personal protection: B NFPA ratings Health: 2 Flammability: 3 Instability: 0 NFPA ratings 02 3 Disclaimer CRC cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user?s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. 9 / 9 Material name: Air Brake Anti-Freeze & Conditioner 05528, 05555 Version #: 01 Issue date: 03-24-2015 SDS US