SAFETY DATA SEEET 1. Identification Air Brake Anti-Freeze & ConditionerProduct identifier Other means of identification No. 05532 (Item# 1003822)Product Code Air brake anti-freezeRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: CRC Industries, Inc.Company name 885 Louis Dr.Address Warminster, PA 18974 US Telephone 215-674-4300General Information 800-521-3168Technical Assistance 800-272-4620Customer Service 800-424-9300 (US)24-Eour Emergency 703-527-3887 (International)(CEEMTREC) www.crcindustries.comWebsite 2. Eazard(s) identification Category 2Flammable liquidsPhysical hazards Category 3Acute toxicity, oralEealth hazards Category 3Acute toxicity, dermal Category 3Acute toxicity, inhalation Category 2Reproductive toxicity (fertility) Category 1 (central nervous system, eyes)Specific target organ toxicity, single exposure Not classified.Environmental hazards Not classified.OSEA defined hazards Label elements Signal word Danger Eazard statement Highly flammable liquid and vapor. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Suspected of damaging fertility. Causes damage to organs (central nervous system, eyes). Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe vapors. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. 1 / 9 Material name: Air Brake Anti-Freeze & Conditioner No. 05532 (Item# 1003822) Version #: 02 Revision date: 04-09-2018 Issue date: 03-24-2015 SDS US Response If swallowed: Immediately call a poison center/doctor. Rinse mouth. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Call a poison center/doctor if you feel unwell. Wash contaminated clothing before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor. If exposed: Call a poison center/doctor. In case of fire: Do not use water jet as an extinguisher, as this will spread the fire. Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Eazard(s) not otherwise classified (ENOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 67-56-1methanol 90 - 100 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a POISON CENTER or doctor/physician. Inhalation Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical advice/attention if you feel unwell. Get medical attention if irritation develops and persists. Wash contaminated clothing before reuse. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Ingestion Narcosis. Headache. Dizziness. Nausea, vomiting. Behavioral changes. Decrease in motor functions. Direct contact with eyes may cause temporary irritation. Most important symptoms/effects, acute and delayed Methanol is metabolized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic symptoms, their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol administration is indicated in symptomatic patients or at blood methanol concentrations above 20 ?g/dl. Methanol is effectively removed by hemodialysis. Fomepizole (4-methylpyrazole) is an effective antagonist of alcohol dehydrogenase, and may be used as an antidote in the treatment of methanol poisoning. Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Take off immediately all contaminated clothing. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Water fog. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media 2 / 9 Material name: Air Brake Anti-Freeze & Conditioner No. 05532 (Item# 1003822) Version #: 02 Revision date: 04-09-2018 Issue date: 03-24-2015 SDS US Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. Use standard firefighting procedures and consider the hazards of other involved materials. Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods Highly flammable liquid and vapor.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not breathe vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Take precautionary measures against static discharge. Use only non-sparking tools. This product is miscible in water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. Environmental precautions 7. Eandling and storage Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. Use non-sparking tools and explosion-proof equipment. Do not breathe vapor. Do not taste or swallow. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Wash contaminated clothing before reuse. Observe good industrial hygiene practices. For product usage instructions, see the product label. Precautions for safe handling Keep away from heat, sparks and open flame. Eliminate sources of ignition. Avoid spark promoters. Store in a cool, dry place out of direct sunlight. Keep container tightly closed. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSEA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 260 mg/m3methanol (CAS 67-56-1) 200 ppm 3 / 9 Material name: Air Brake Anti-Freeze & Conditioner No. 05532 (Item# 1003822) Version #: 02 Revision date: 04-09-2018 Issue date: 03-24-2015 SDS US US. ACGIE Threshold Limit Values ValueComponents Type STEL 250 ppmmethanol (CAS 67-56-1) TWA 200 ppm US. NIOSE: Pocket Guide to Chemical Eazards ValueComponents Type STEL 325 mg/m3methanol (CAS 67-56-1) 250 ppm TWA 260 mg/m3 200 ppm Biological limit values ACGIE Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 15 mg/l Methanol Urine *methanol (CAS 67-56-1) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation methanol (CAS 67-56-1) Can be absorbed through the skin. US - Minnesota Eaz Subs: Skin designation applies methanol (CAS 67-56-1) Skin designation applies. US - Tennessee OELs: Skin designation methanol (CAS 67-56-1) Can be absorbed through the skin. US ACGIE Threshold Limit Values: Skin designation methanol (CAS 67-56-1) Can be absorbed through the skin. US NIOSE Pocket Guide to Chemical Eazards: Skin designation methanol (CAS 67-56-1) Can be absorbed through the skin. Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear protective gloves such as: Nitrile. Rubber.Eand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Liquid.Form Colorless.Color Pungent. Alcoholic.Odor Odor threshold Not available. pE Not available. Melting point/freezing point -144 ?F (-97.8 ?C) estimated 4 / 9 Material name: Air Brake Anti-Freeze & Conditioner No. 05532 (Item# 1003822) Version #: 02 Revision date: 04-09-2018 Issue date: 03-24-2015 SDS US Initial boiling point and boiling range 148.5 ?F (64.7 ?C) estimated Flash point 54 ?F (12.2 ?C) Setaflash Evaporation rate Fast. Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 2.6 % estimated Flammability limit - upper (%) 36 % estimated Vapor pressure 133.2 hPa estimated Vapor density 1.1 (air = 1) Relative density 0.79 Solubility(ies) Solubility (water) Completely soluble. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 725 ?F (385 ?C) estimated Decomposition temperature Not available. Percent volatile 99.9 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Avoid heat, sparks, open flames and other ignition sources. Contact with incompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials Carbon oxides. Formaldehyde.Eazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Toxic if inhaled. May cause damage to organs by inhalation. Skin contact Toxic in contact with skin. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Toxic if swallowed. Even small amounts (30-250 ml methanol) may be fatal. Symptoms are stomach ache, nausea, vomiting, dullness, visual disorder and blindness. Symptoms related to the physical, chemical and toxicological characteristics Narcosis. Headache. Dizziness. Nausea, vomiting. Behavioral changes. Decrease in motor functions. Information on toxicological effects Acute toxicity Toxic if inhaled. Toxic in contact with skin. Toxic if swallowed. Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Direct contact with eyes may cause temporary irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity Not classifiable as to carcinogenicity to humans. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. 5 / 9 Material name: Air Brake Anti-Freeze & Conditioner No. 05532 (Item# 1003822) Version #: 02 Revision date: 04-09-2018 Issue date: 03-24-2015 SDS US OSEA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. Suspected of damaging fertility.Reproductive toxicity Specific target organ toxicity - single exposure Causes damage to organs (central nervous system, eyes). Even small amounts (30-250 ml methanol) may be fatal. Symptoms are stomach ache, nausea, vomiting, dullness, visual disorder and blindness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test ResultsSpecies methanol (CAS 67-56-1) Aquatic LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Acute EC50Crustacea > 10000 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) No data is available on the degradability of any ingredients in the mixture. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) methanol -0.77 No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations D001: Waste Flammable material with a flash point <140 F F003: Waste Non-halogenated Solvent - Spent Non-halogenated Solvent Eazardous waste code US RCRA Eazardous Waste U List: Reference methanol (CAS 67-56-1) U154 Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contaminated packaging This material and its container must be disposed of as hazardous waste. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose in accordance with all applicable regulations. Disposal instructions 14. Transport information DOT UN1230UN number Methanol, solution (methanol RQ = 5007 LBS), Limited QuantityUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIPacking group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IB2, T7, TP2Special provisions 150Packaging exceptions 6 / 9 Material name: Air Brake Anti-Freeze & Conditioner No. 05532 (Item# 1003822) Version #: 02 Revision date: 04-09-2018 Issue date: 03-24-2015 SDS US 202Packaging non bulk 242Packaging bulk IATA UN1230UN number Methanol, Limited QuantityUN proper shipping name 3Class Transport hazard class(es) 6.1Subsidiary risk IIPacking group 3LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed with restrictions.Passenger and cargo aircraft Other information Allowed with restrictions.Cargo aircraft only IMDG UN1230UN number METHANOL, Limited QuantityUN proper shipping name 3Class Transport hazard class(es) 6.1Subsidiary risk IIPacking group No.Marine pollutant Environmental hazards F-E, S-DEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. OSEA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance methanol (CAS 67-56-1) CERCLA Eazardous Substance List (40 CFR 302.4) methanol (CAS 67-56-1) Listed. CERCLA Eazardous Substances: Reportable quantity methanol (CAS 67-56-1) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Other federal regulations Clean Air Act (CAA) Section 112 Eazardous Air Pollutants (EAPs) List methanol (CAS 67-56-1) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) Not regulated.Food and Drug Administration (FDA) 7 / 9 Material name: Air Brake Anti-Freeze & Conditioner No. 05532 (Item# 1003822) Version #: 02 Revision date: 04-09-2018 Issue date: 03-24-2015 SDS US Superfund Amendments and Reauthorization Act of 1986 (SARA) Flammable (gases, aerosols, liquids, or solids) Acute toxicity (any route of exposure) Reproductive toxicity Specific target organ toxicity (single or repeated exposure) Hazard not otherwise classified (HNOC) Classified hazard categories SARA 302 Extremely hazardous substance Not listed. SARA 313 (TRI reporting) Chemical name % by wt.CAS number methanol 90 - 10067-56-1 US state regulations US. New Jersey Worker and Community Right-to-Know Act methanol (CAS 67-56-1) US. Massachusetts RTK - Substance List methanol (CAS 67-56-1) US. Pennsylvania Worker and Community Right-to-Know Law methanol (CAS 67-56-1) US. Rhode Island RTK methanol (CAS 67-56-1) California Proposition 65 Reproductive Harm - www.P65Warnings.ca.govWARNING: California Proposition 65 - CRT: Listed date/Developmental toxin methanol (CAS 67-56-1) Listed: March 16, 2012 US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) methanol (CAS 67-56-1) Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 100 % Not regulatedConsumer products (40 CFR 59, Subpt. C) State Not regulatedConsumer products VOC content (CA) 100 % VOC content (OTC) 100 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) YesJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesTaiwan Taiwan Toxic Chemical Substances (TCS) 8 / 9 Material name: Air Brake Anti-Freeze & Conditioner No. 05532 (Item# 1003822) Version #: 02 Revision date: 04-09-2018 Issue date: 03-24-2015 SDS US Country(s) or region Inventory name On inventory (yes/no)* YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 03-24-2015Issue date 04-09-2018Revision date Allison YoonPrepared by Version # 02 CRC # 620B/1002661Further information The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC's knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries, Inc.. Disclaimer This document has undergone significant changes and should be reviewed in its entirety.Revision information 9 / 9 Material name: Air Brake Anti-Freeze & Conditioner No. 05532 (Item# 1003822) Version #: 02 Revision date: 04-09-2018 Issue date: 03-24-2015 SDS US