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SAFETY DATA SHEET 1. Identification HydroForce? Foaming Citrus All Purpose CleanerProduct identifier Other means of identification 14400Product code General purpose cleanerRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Liquefied gasGases under pressurePhysical hazards Category 1Serious eye damage/eye irritationHealth hazards Category 1Sensitization, skin Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Contains gas under pressure; may explode if heated. May cause an allergic skin reaction. Causes serious eye damage. Toxic to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 49?C/120?F. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves and eye/face protection. Avoid release to the environment. Response If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical attention. Wash contaminated clothing before reuse. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Storage Protect from sunlight. Store in a well-ventilated place. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. 1 / 9 Material name: HydroForce? Foaming Citrus All Purpose Cleaner 14400 Version #: 03 Revision date: 11-15-2016 Issue date: 07-16-2015 SDS US Hazard(s) not otherwise classified (HNOC) None known. 3. Composition/information on ingredients Mixtures CAS numberCommon name and synonymsChemical name % 7732-18-5water 80 - 90 68476-86-8liquefied petroleum gas 3 - 5 34590-94-8dipropylene glycol monomethyl ether 1 - 3 8028-48-6orange, sweet, ext. 1 - 3 68439-50-9ethoxylated alcohol < 1 64-02-8tetrasodium ethylenediaminetetraacetate < 1 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Move to fresh air. Call a physician if symptoms develop or persist.Inhalation Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. Eye contact In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth.Ingestion Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. May cause an allergic skin reaction. Dermatitis. Rash. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media None known.Unsuitable extinguishing media Pressurized container may rupture when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Contents under pressure. Pressurized container may rupture when exposed to heat or flame.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Prevent product from entering drains. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up 2 / 9 Material name: HydroForce? Foaming Citrus All Purpose Cleaner 14400 Version #: 03 Revision date: 11-15-2016 Issue date: 07-16-2015 SDS US Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not get this material in contact with eyes. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Precautions for safe handling Level 1 Aerosol. Contents under pressure. Do not expose to heat or store at temperatures above 120?F/49?C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection This mixture has no ingredients that have PEL, TLV, or other recommended exposure limit.Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 600 mg/m3dipropylene glycol monomethyl ether (CAS 34590-94-8) 100 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 150 ppmdipropylene glycol monomethyl ether (CAS 34590-94-8) TWA 100 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type STEL 900 mg/m3dipropylene glycol monomethyl ether (CAS 34590-94-8) 150 ppm TWA 600 mg/m3 100 ppm No biological exposure limits noted for the ingredient(s).Biological limit values Exposure guidelines US - California OELs: Skin designation dipropylene glycol monomethyl ether (CAS 34590-94-8) Can be absorbed through the skin. US - Tennessee OELs: Skin designation dipropylene glycol monomethyl ether (CAS 34590-94-8) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation dipropylene glycol monomethyl ether (CAS 34590-94-8) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation dipropylene glycol monomethyl ether (CAS 34590-94-8) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) dipropylene glycol monomethyl ether (CAS 34590-94-8) Can be absorbed through the skin. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Appropriate engineering controls 3 / 9 Material name: HydroForce? Foaming Citrus All Purpose Cleaner 14400 Version #: 03 Revision date: 11-15-2016 Issue date: 07-16-2015 SDS US Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles) and a face shield.Eye/face protection Skin protection Wear protective gloves such as: Nitrile. Rubber.Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Aerosol.Form Light yellow.Color Citrus.Odor Odor threshold Not available. pH 10.9 Melting point/freezing point -140.8 ?F (-96 ?C) estimated Initial boiling point and boiling range 212 ?F (100 ?C) estimated Flash point None (Tag Closed Cup) Evaporation rate Slow. Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 0.7 % estimated Flammability limit - upper (%) 25 % estimated Vapor pressure 259.1 hPa estimated Vapor density > 1 (air = 1) Relative density 0.98 estimated Solubility (water) Soluble. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 404.6 ?F (207 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 96.9 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Heat, flames and sparks. Contact with incompatible materials.Conditions to avoid Strong oxidizing agents. Strong reducing agents. Strong acids. Strong bases. Peroxides. Halogens. Vinyl chloride. Iodine pentafluoride. Incompatible materials 4 / 9 Material name: HydroForce? Foaming Citrus All Purpose Cleaner 14400 Version #: 03 Revision date: 11-15-2016 Issue date: 07-16-2015 SDS US Aldehydes. Ketones. Organic acids. Carbon oxides. Potassium oxide.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact May cause an allergic skin reaction. Eye contact Causes serious eye damage. Ingestion Health injuries are not known or expected under normal use. Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Permanent eye damage including blindness could result. May cause an allergic skin reaction. Dermatitis. Rash. Information on toxicological effects Acute toxicity Not known. Test ResultsComponents Species dipropylene glycol monomethyl ether (CAS 34590-94-8) Dermal Acute LD50 Rabbit 9510 mg/kg Inhalation LC50 Rat 552 ppm Oral LD50 Rat 5135 mg/kg orange, sweet, ext. (CAS 8028-48-6) Dermal Acute LD50 Rabbit > 5 g/kg tetrasodium ethylenediaminetetraacetate (CAS 64-02-8) Oral Acute * Estimates for product may be based on additional component data not shown. LD50 Rat > 2000 mg/kg Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Causes serious eye damage.Serious eye damage/eye irritation Respiratory sensitization Not a respiratory sensitizer. May cause an allergic skin reaction.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Not listed. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. 5 / 9 Material name: HydroForce? Foaming Citrus All Purpose Cleaner 14400 Version #: 03 Revision date: 11-15-2016 Issue date: 07-16-2015 SDS US Chronic effects Prolonged exposure may cause chronic effects. 12. Ecological information Toxic to aquatic life. Harmful to aquatic life with long lasting effects.Ecotoxicity Components Test ResultsSpecies dipropylene glycol monomethyl ether (CAS 34590-94-8) Aquatic Acute EC50Crustacea > 5000 mg/l, 48 hoursDaphnia LC50Fish 10000 mg/l, 96 hoursFathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. tetrasodium ethylenediaminetetraacetate (CAS 64-02-8) Aquatic LC50Fish 472 - 500 mg/l, 96 hoursBluegill (Lepomis macrochirus) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) orange, sweet, ext. 4.23 No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Empty container can be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Disposal of waste from residues / unused products Not regulated.Hazardous waste code Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contaminated packaging 14. Transport information DOT UN1950UN number Aerosols, non-flammable, Limited QuantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk 2.2Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, non-flammable, Limited QuantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group 2LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 6 / 9 Material name: HydroForce? Foaming Citrus All Purpose Cleaner 14400 Version #: 03 Revision date: 11-15-2016 Issue date: 07-16-2015 SDS US Allowed with restrictions.Passenger and cargo aircraft Other information Allowed with restrictions.Cargo aircraft only IMDG UN1950UN number AEROSOLS, Limited QuantityUN proper shipping name 2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Not listed. CERCLA Hazardous Substances: Reportable quantity Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) Not regulated.Food and Drug Administration (FDA) Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No Section 311/312 Hazard categories NoSARA 302 Extremely hazardous substance US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) liquefied petroleum gas (CAS 68476-86-8) US. New Jersey Worker and Community Right-to-Know Act dipropylene glycol monomethyl ether (CAS 34590-94-8) US. Massachusetts RTK - Substance List dipropylene glycol monomethyl ether (CAS 34590-94-8) 7 / 9 Material name: HydroForce? Foaming Citrus All Purpose Cleaner 14400 Version #: 03 Revision date: 11-15-2016 Issue date: 07-16-2015 SDS US US. Pennsylvania Worker and Community Right-to-Know Law ammonia (CAS 7664-41-7) dipropylene glycol monomethyl ether (CAS 34590-94-8) sodium hydroxide (CAS 1310-73-2) US. Rhode Island RTK ammonia (CAS 7664-41-7) dipropylene glycol monomethyl ether (CAS 34590-94-8) sodium hydroxide (CAS 1310-73-2) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance formaldehyde (CAS 50-00-0) Listed: January 1, 1988 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 7.7 % CompliantConsumer products (40 CFR 59, Subpt. C) State This product is regulated as a General Purpose Cleaner (aerosol). This product is compliant for use in all 50 states. Consumer products VOC content (CA) 7.7 % VOC content (OTC) 7.7 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustralia Australian Inventory of Chemical Substances (AICS) NoCanada Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 07-16-2015Issue date 11-15-2016Revision date Allison ChoPrepared by Version # 03 CRC # 450CFurther information Health: 3 Flammability: 1 Physical hazard: 0 Personal protection: D HMIS? ratings Health: 3 Flammability: 1 Instability: 0 NFPA ratings 8 / 9 Material name: HydroForce? Foaming Citrus All Purpose Cleaner 14400 Version #: 03 Revision date: 11-15-2016 Issue date: 07-16-2015 SDS US NFPA ratings 03 1 The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC's knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries, Inc.. Disclaimer This document has undergone significant changes and should be reviewed in its entirety.Revision Information 9 / 9 Material name: HydroForce? Foaming Citrus All Purpose Cleaner 14400 Version #: 03 Revision date: 11-15-2016 Issue date: 07-16-2015 SDS US