SAFETY DATA SHEET 1. Identification Tannery? Vintage? Leather Cleaner and ConditionerProduct identifier Other means of identification 40144 (Item #1006071)Product code Leather cleanerRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: CRC Industries, Inc.Company name 885 Louis Dr.Address Warminster, PA 18974 US Telephone 215-674-4300General Information 800-521-3168Technical Assistance 800-272-4620Customer Service 800-424-9300 (US)24-Hour Emergency 703-527-3887 (International)(CHEMTREC) www.crcindustries.comWebsite 2. Hazard(s) identification Liquefied gasGases under pressurePhysical hazards Not classified.Health hazards Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Precautionary statement Prevention Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 49?C/120?F. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. Observe good industrial hygiene practices. Response Wash hands after handling. Storage Protect from sunlight. Store in a well-ventilated place. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) None known. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 7732-18-5water 60 - 70 68476-86-8liquefied petroleum gas 10 - 20 1 / 9 Material name: Tannery? Vintage? Leather Cleaner and Conditioner 40144 (Item #1006071) Version #: 02 Revision date: 07-06-2017 Issue date: 06-01-2015 SDS US CAS number %Chemical name Common name and synonyms 64742-48-9naphtha (petroleum), hydrotreated heavy 5 - 10 8042-47-5white mineral oil (petroleum) 3 - 5 111-76-22-butoxyethanol 1 - 3 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Move to fresh air. Call a physician if symptoms develop or persist.Inhalation Rinse skin with water/shower. Get medical attention if irritation develops and persists.Skin contact Rinse with water. Get medical attention if irritation develops and persists.Eye contact IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do not induce vomiting. Ingestion Direct contact with eyes may cause temporary irritation.Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically.Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media Pressurized container may rupture when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Contents under pressure. Pressurized container may rupture when exposed to heat or flame.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many vapors are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground.Environmental precautions 7. Handling and storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not get in eyes, on skin, or on clothing. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. For product usage instructions, see the product label. Precautions for safe handling 2 / 9 Material name: Tannery? Vintage? Leather Cleaner and Conditioner 40144 (Item #1006071) Version #: 02 Revision date: 07-06-2017 Issue date: 06-01-2015 SDS US Level 1 Aerosol. Contents under pressure. Do not expose to heat or store at temperatures above 120?F/49?C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents FormType PEL 240 mg/m32-butoxyethanol (CAS 111-76-2) 50 ppm PEL 400 mg/m3naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) 100 ppm PEL 5 mg/m3 Mist.white mineral oil (petroleum) (CAS 8042-47-5) US. ACGIH Threshold Limit Values ValueComponents FormType TWA 20 ppm2-butoxyethanol (CAS 111-76-2) TWA 5 mg/m3 Inhalable fraction.white mineral oil (petroleum) (CAS 8042-47-5) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents FormType TWA 24 mg/m32-butoxyethanol (CAS 111-76-2) 5 ppm TWA 400 mg/m3naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) 100 ppm STEL 10 mg/m3 Mist.white mineral oil (petroleum) (CAS 8042-47-5) TWA 5 mg/m3 Mist. Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine *2-butoxyethanol (CAS 111-76-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennessee OELs: Skin designation 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. 3 / 9 Material name: Tannery? Vintage? Leather Cleaner and Conditioner 40144 (Item #1006071) Version #: 02 Revision date: 07-06-2017 Issue date: 06-01-2015 SDS US Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear protective gloves such as: Nitrile. Rubber.Hand protection Wear suitable protective clothing.Other If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Aerosol.Form Milky white.Color Leather.Odor Odor threshold Not available. pH 10.1 Melting point/freezing point -103 ?F (-75 ?C) estimated Initial boiling point and boiling range 212 ?F (100 ?C) estimated Flash point None (Tag Closed Cup) Evaporation rate Slow. Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 0.7 % estimated Flammability limit - upper (%) 23.5 % estimated Vapor pressure 893.7 hPa estimated Vapor density > 1 (air = 1) Relative density 0.88 Solubility (water) Soluble. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 446 ?F (230 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 94.1 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Heat, flames and sparks. Contact with incompatible materials.Conditions to avoid 4 / 9 Material name: Tannery? Vintage? Leather Cleaner and Conditioner 40144 (Item #1006071) Version #: 02 Revision date: 07-06-2017 Issue date: 06-01-2015 SDS US Strong oxidizing agents.Incompatible materials Carbon oxides. Aldehydes. Ketones. Organic acids.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Ingestion of small quantities is not expected to cause health effects. Ingestion of large amounts may produce gastrointestinal disturbances including irritation, nausea, and diarrhea. Symptoms related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Test ResultsComponents Species 2-butoxyethanol (CAS 111-76-2) Dermal Acute LD50 Rabbit > 2000 mg/kg Oral LD50 Rat 1300 mg/kg naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Dermal Acute LD50 Rabbit > 5000 mg/kg Inhalation LC50 Rat 61 mg/l, 4 Hours Oral LD50 Rat > 5000 mg/kg white mineral oil (petroleum) (CAS 8042-47-5) Dermal Acute LD50 Rabbit > 2000 mg/kg Oral * Estimates for product may be based on additional component data not shown. LD50 Rat > 5000 mg/kg Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Direct contact with eyes may cause temporary irritation.Serious eye damage/eye irritation Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. white mineral oil (petroleum) (CAS 8042-47-5) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. 5 / 9 Material name: Tannery? Vintage? Leather Cleaner and Conditioner 40144 (Item #1006071) Version #: 02 Revision date: 07-06-2017 Issue date: 06-01-2015 SDS US US. National Toxicology Program (NTP) Report on Carcinogens Not listed. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not likely, due to the form of the product. Chronic effects May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test ResultsSpecies 2-butoxyethanol (CAS 111-76-2) Aquatic Acute EC50Crustacea 1550 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish >= 1000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) Aquatic EC50Crustacea 2.7 - 5.1 mg/l, 48 hoursWater flea (Daphnia pulex) LC50Fish 8.8 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) 8.8 mg/l, 96 hours * Estimates for product may be based on additional component data not shown. white mineral oil (petroleum) (CAS 8042-47-5) Aquatic Acute LC50Fish > 10000 mg/l, 96 hoursFish No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 2-butoxyethanol 0.81, log Pow white mineral oil (petroleum) > 4, log Pow No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Empty container can be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Disposal of waste from residues / unused products Not regulated.Hazardous waste code Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 6 / 9 Material name: Tannery? Vintage? Leather Cleaner and Conditioner 40144 (Item #1006071) Version #: 02 Revision date: 07-06-2017 Issue date: 06-01-2015 SDS US 14. Transport information DOT UN1950UN number Aerosols, non-flammable, Limited QuantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk 2.2Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, non-flammable, Limited QuantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group 2LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed with restrictions.Passenger and cargo aircraft Other information Allowed with restrictions.Cargo aircraft only IMDG UN1950UN number Aerosols, non-flammable, Limited QuantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Marine pollutant Environmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance 2-butoxyethanol (CAS 111-76-2) CERCLA Hazardous Substance List (40 CFR 302.4) 2-butoxyethanol (CAS 111-76-2) Listed. CERCLA Hazardous Substances: Reportable quantity Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. 7 / 9 Material name: Tannery? Vintage? Leather Cleaner and Conditioner 40144 (Item #1006071) Version #: 02 Revision date: 07-06-2017 Issue date: 06-01-2015 SDS US Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) Not regulated.Food and Drug Administration (FDA) Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No Section 311/312 Hazard categories NoSARA 302 Extremely hazardous substance US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) 2-butoxyethanol (CAS 111-76-2) liquefied petroleum gas (CAS 68476-86-8) naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) US. New Jersey Worker and Community Right-to-Know Act 2-butoxyethanol (CAS 111-76-2) naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) US. Massachusetts RTK - Substance List 2-butoxyethanol (CAS 111-76-2) naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) white mineral oil (petroleum) (CAS 8042-47-5) US. Pennsylvania Worker and Community Right-to-Know Law 2-butoxyethanol (CAS 111-76-2) white mineral oil (petroleum) (CAS 8042-47-5) US. Rhode Island RTK 2-butoxyethanol (CAS 111-76-2) naphtha (petroleum), hydrotreated heavy (CAS 64742-48-9) white mineral oil (petroleum) (CAS 8042-47-5) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance 1,3-dichloropropene (CAS 542-75-6) Listed: January 1, 1989 diethanolamine (CAS 111-42-2) Listed: June 22, 2012 methylene chloride (CAS 75-09-2) Listed: April 1, 1988 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 33.9 % Not regulatedConsumer products (40 CFR 59, Subpt. C) State This product is regulated as a Leather Care Product (aerosol). This product is compliant for use in all 50 states. Consumer products VOC content (CA) 29 % VOC content (OTC) 29 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustralia Australian Inventory of Chemical Substances (AICS) NoCanada Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) 8 / 9 Material name: Tannery? Vintage? Leather Cleaner and Conditioner 40144 (Item #1006071) Version #: 02 Revision date: 07-06-2017 Issue date: 06-01-2015 SDS US Country(s) or region Inventory name On inventory (yes/no)* NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 06-01-2015Issue date 07-06-2017Revision date Allison YoonPrepared by Version # 02 CRC # 671/1002707Further information Health: 1 Flammability: 1 Physical hazard: 0 Personal protection: B HMIS? ratings Health: 1 Flammability: 1 Instability: 0 NFPA ratings NFPA ratings 01 1 The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC's knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries, Inc.. Disclaimer Product and Company Identification: Product Codes Composition/information on ingredients: Component information Fire-fighting measures: Suitable extinguishing media Handling and storage: Precautions for safe handling Physical & Chemical Properties: Multiple Properties Stability and reactivity: Hazardous decomposition products Toxicological information: Aspiration hazard Toxicological information: Ingestion Ecological Information: Ecotoxicity Transport Information: Proper Shipping Name/Packing Group Other information, including date of preparation or last revision: Disclaimer Other information, including date of preparation or last revision: Further information GHS: Classification Revision Information 9 / 9 Material name: Tannery? Vintage? Leather Cleaner and Conditioner 40144 (Item #1006071) Version #: 02 Revision date: 07-06-2017 Issue date: 06-01-2015 SDS US