SAFETY DATA SHEET 1. Identification Product identifier Super White? Multi-Purpose Lithium Grease Other means of identification Product code SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Recommended use Multi-purpose grease Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Not classified.Physical hazards Category 1Sensitization, skinHealth hazards Category 3Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Warning Hazard statement May cause an allergic skin reaction. Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Avoid breathing vapors. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. Avoid release to the environment. Response If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Wash contaminated clothing before reuse. Storage Store away from incompatible materials. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) None known. 3. Composition/information on ingredients Mixtures 1 / 8 Material name: Super White? Multi-Purpose Lithium Grease SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015 SDS US CAS number %Chemical name Common name and synonyms 64742-52-5Distillates (petroleum), hydrotreated heavy naphthenic 80 - 90 1314-13-2Zinc oxide 3 - 5 57855-77-3Calcium bis(dinonylnaphthalenesulphonate) < 1 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. If breathing is difficult, trained personnel should give oxygen. Do not use mouth-to-mouth method if victim inhaled the substance. Call a physician if symptoms develop or persist. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Drink 1 or 2 glasses of water. Never give anything by mouth to a victim who is unconscious or is having convulsions. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. If ingestion of a large amount does occur, call a poison control center immediately. Most important symptoms/effects, acute and delayed Irritation of eyes and mucous membranes. May cause an allergic skin reaction. Rash. Skin irritation. Dermatitis. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Use fire-extinguishing media appropriate for surrounding materials. Unsuitable extinguishing media None known. Specific hazards arising from the chemical During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up The product is immiscible with water and will spread on the water surface. Stop the flow of material, if this is without risk. Collect spill using a vacuum cleaner with a HEPA filter. Avoid dust formation. Place all material into loosely covered plastic containers for later disposal. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewer, basements or confined areas. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Avoid contact with eyes, skin, and clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. Use care in handling/storage. For product usage instructions, please see the product label. 2 / 8 Material name: Super White? Multi-Purpose Lithium Grease SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015 SDS US Conditions for safe storage, including any incompatibilities Keep container tightly closed. Store away from incompatible materials (see Section 10 of the SDS). Store in a cool, dry place out of direct sunlight. Store in a well-ventilated place. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents FormType PEL 5 mg/m3 Mist.Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) 2000 mg/m3 500 ppm PEL 15 mg/m3 Total dust.Titanium dioxide (CAS 13463-67-7) PEL 5 mg/m3 Respirable fraction.Zinc oxide (CAS 1314-13-2) 5 mg/m3 Fume. 15 mg/m3 Total dust. US. ACGIH Threshold Limit Values ValueComponents FormType TWA 5 mg/m3 Inhalable fraction.Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) TWA 10 mg/m3Titanium dioxide (CAS 13463-67-7) STEL 10 mg/m3 Respirable fraction.Zinc oxide (CAS 1314-13-2) TWA 2 mg/m3 Respirable fraction. US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents FormType Ceiling 1800 mg/m3Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) STEL 10 mg/m3 Mist. TWA 5 mg/m3 Mist. Ceiling 15 mg/m3 Dust.Zinc oxide (CAS 1314-13-2) STEL 10 mg/m3 Fume. TWA 5 mg/m3 Dust. 5 mg/m3 Fume. Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as: Nitrile. Neoprene. Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. 3 / 8 Material name: Super White? Multi-Purpose Lithium Grease SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015 SDS US 9. Physical and chemical properties Appearance Physical state Solid. Form Grease. Color White. Odor Petroleum. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 680 ?F (360 ?C) estimated Flash point 475 ?F (246.1 ?C) Cleveland Open Cup Evaporation rate Very slow. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Vapor pressure 1066.6 hPa estimated Vapor density > 5 (air = 1) Relative density 0.9 Solubility (water) Insoluble. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 500 ?F (260 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) 145 - 185 cSt (104 ?F (40 ?C)) Percent volatile Not available. Other information Pour point 0 ?F (-17.8 ?C) 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Carbon oxides. Metal oxides. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Health injuries are not known or expected under normal use. Skin contact May cause an allergic skin reaction. Eye contact Direct contact with eyes may cause temporary irritation. Symptoms related to the physical, chemical and toxicological characteristics Rash. Irritation of eyes and mucous membranes. Skin irritation. May cause an allergic skin reaction. Dermatitis. Information on toxicological effects 4 / 8 Material name: Super White? Multi-Purpose Lithium Grease SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015 SDS US Acute toxicity May cause an allergic skin reaction. Test ResultsProduct Species Super White? Multi-Purpose Lithium Grease LD50 Rabbit Dermal Acute > 2000 mg/kg LD50 Rat Oral > 5000 mg/kg * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory sensitization Not available. Skin sensitization May cause an allergic skin reaction. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity Not likely, due to the form of the product. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not likely, due to the form of the product. Chronic effects Prolonged exposure may cause chronic effects. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. Product Test ResultsSpecies Super White? Multi-Purpose Lithium Grease Aquatic Acute EC50Crustacea 3.3075 mg/l, 48 hours estimatedDaphnia LC50Fish 37.1245 ppm, 96 hours estimatedFish Components Test ResultsSpecies Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) Aquatic EC50Crustacea 1000 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 5000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Titanium dioxide (CAS 13463-67-7) Acute EC50Other 5.83 mg/l, 72 hoursPseudokirchnerella subcapitata Chronic NOECOther 0.984 mg/l, 72 hoursPseudokirchnerella subcapitata Aquatic Acute LC50Crustacea 3 mg/l, 48 hoursCeriodaphnia dubia 5.5 ppm, 48 hoursWater flea (Daphnia magna) LC50Fish 1000 mg/l, 96 hoursFathead minnow (Pimephales promelas) 5 / 8 Material name: Super White? Multi-Purpose Lithium Grease SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015 SDS US Components Test ResultsSpecies Zinc oxide (CAS 1314-13-2) Aquatic Acute EC50Crustacea 0.098 mg/l, 48 hoursWater flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50Fish 1.1 ppm, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Persistence and degradability Not readily biodegradable. Bioaccumulative potential No data available. Bioconcentration factor (BCF) Titanium dioxide 352 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from residues / unused products This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 ? 261.33). Empty containers may be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code Not regulated. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Zinc oxide (CAS 1314-13-2) CERCLA Hazardous Substance List (40 CFR 302.4) Zinc oxide (CAS 1314-13-2) CERCLA Hazardous Substances: Reportable quantity Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. 6 / 8 Material name: Super White? Multi-Purpose Lithium Grease SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015 SDS US Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Food and Drug Administration (FDA) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance No US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Titanium dioxide (CAS 13463-67-7) Zinc oxide (CAS 1314-13-2) US. Massachusetts RTK - Substance List Titanium dioxide (CAS 13463-67-7) Zinc oxide (CAS 1314-13-2) US. Pennsylvania Worker and Community Right-to-Know Law Zinc oxide (CAS 1314-13-2) Titanium dioxide (CAS 13463-67-7) US. Rhode Island RTK Zinc oxide (CAS 1314-13-2) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 100 % Consumer products (40 CFR 59, Subpt. C) Not regulated State Consumer products Not regulated VOC content (CA) < 0.1 % VOC content (OTC) < 0.1 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) YesJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) 7 / 8 Material name: Super White? Multi-Purpose Lithium Grease SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015 SDS US Country(s) or region Inventory name On inventory (yes/no)* YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 01-19-2015 Prepared by Allison Cho Version # 01 Further information Not available. HMIS? ratings Health: 1 Flammability: 1 Physical hazard: 0 Personal protection: B NFPA ratings Health: 1 Flammability: 1 Instability: 0 NFPA ratings 01 1 Disclaimer CRC cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user?s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. 8 / 8 Material name: Super White? Multi-Purpose Lithium Grease SL3150, SL3151, SL3155, SL3159, SL3360, SL3361 Version #: 01 Issue date: 01-19-2015 SDS US