SAFETY DATA SHEET 1. Identification Product identifier Dry PTFE Lube Other means of identification Product code 03044 Recommended use Dry film lubricant Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Liquefied gasGases under pressure Category 2Skin corrosion/irritationHealth hazards Category 2Serious eye damage/eye irritation Category 2Reproductive toxicity (fertility) Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 2Specific target organ toxicity, repeated exposure Category 1Aspiration hazard Category 2Hazardous to the aquatic environment, long-term hazard Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of damaging fertility. May cause damage to organs (nervous system, upper respiratory tract, skin, eyes) through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. 1 / 10 Material name: Dry PTFE Lube 03044 Version #: 01 Issue date: 01-19-2015 SDS US Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Do not breathe gas. Do not breathe mist or vapor. Wash thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. If exposed or concerned: Get medical attention. Collect spillage. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 68476-86-8Liquefied Petroleum Gas 40 - 50 67-63-0Isopropyl alcohol 20 - 30 64742-49-0Naphtha (petroleum), hydrotreated light 10 - 20 107-83-52-Methylpentane 5 - 10 110-54-3n-Hexane 1 - 3 5593-70-4Titanium tetrabutanolate 1 - 3 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important symptoms/effects, acute and delayed May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. 2 / 10 Material name: Dry PTFE Lube 03044 Version #: 01 Issue date: 01-19-2015 SDS US Unsuitable extinguishing media None known. Specific hazards arising from the chemical Contents under pressure. Pressurized container may rupture when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not breathe gas. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewer, basements or confined areas. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor. Do not breathe gas. Avoid contact with eyes, skin, and clothing. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Conditions for safe storage, including any incompatibilities Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 3 / 10 Material name: Dry PTFE Lube 03044 Version #: 01 Issue date: 01-19-2015 SDS US 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 980 mg/m3Isopropyl alcohol (CAS 67-63-0) 400 ppm PEL 1800 mg/m3n-Hexane (CAS 110-54-3) 500 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 1000 ppm2-Methylpentane (CAS 107-83-5) TWA 500 ppm STEL 400 ppmIsopropyl alcohol (CAS 67-63-0) TWA 200 ppm TWA 50 ppmn-Hexane (CAS 110-54-3) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type Ceiling 1800 mg/m32-Methylpentane (CAS 107-83-5) 510 ppm TWA 350 mg/m3 100 ppm STEL 1225 mg/m3Isopropyl alcohol (CAS 67-63-0) 500 ppm TWA 980 mg/m3 400 ppm TWA 180 mg/m3n-Hexane (CAS 110-54-3) 50 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 40 mg/l Acetone Urine *Isopropyl alcohol (CAS 67-63-0) 0.4 mg/l 2,5-Hexanedio n, without hydrolysis Urine *n-Hexane (CAS 110-54-3) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation n-Hexane (CAS 110-54-3) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation n-Hexane (CAS 110-54-3) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC). Viton?. Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. 4 / 10 Material name: Dry PTFE Lube 03044 Version #: 01 Issue date: 01-19-2015 SDS US Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Hazy white. Odor Alcoholic. Odor threshold Not available. pH Not available. Melting point/freezing point -244.7 ?F (-153.7 ?C) estimated Initial boiling point and boiling range 118.4 ?F (48 ?C) estimated Flash point < 20 ?F (< -6.7 ?C) Tag Closed Cup Evaporation rate Fast. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) 1 % estimated Flammability limit - upper (%) 12 % estimated Vapor pressure 2242.3 hPa estimated Vapor density > 1 (air = 1) Relative density 0.65 estimated Solubility (water) Negligible. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 437 ?F (225 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 97.8 % estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Heat, flames and sparks. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Isocyanates. Chlorine. Hazardous decomposition products Carbon oxides. 11. Toxicological information Information on likely routes of exposure Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Inhalation May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting. 5 / 10 Material name: Dry PTFE Lube 03044 Version #: 01 Issue date: 01-19-2015 SDS US Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Symptoms related to the physical, chemical and toxicological characteristics May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. Test ResultsProduct Species Dry PTFE Lube LD50 Rabbit Dermal Acute 8058.0591 mg/kg estimated LC50 Rat Inhalation 41844.3203 ppm, 4 hours estimated 72.2197 mg/l, 4 hours estimated LD50 Rat Oral 7403.8032 mg/kg estimated * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity Suspected of damaging fertility. Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure May cause damage to organs through prolonged or repeated exposure. Aspiration hazard May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Chronic effects May cause damage to organs through prolonged or repeated exposure. 12. Ecological information Ecotoxicity Toxic to aquatic life with long lasting effects. Product Test ResultsSpecies Dry PTFE Lube Aquatic LC50Fish 5597.1743 mg/l, 96 hours estimatedFish Acute EC50Crustacea 35198.5547 mg/l, 48 hours estimatedDaphnia Components Test ResultsSpecies Isopropyl alcohol (CAS 67-63-0) Aquatic Acute EC50Crustacea 7550 - 13299 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 3200 mg/l, 96 hoursFathead minnow (Pimephales promelas) 6 / 10 Material name: Dry PTFE Lube 03044 Version #: 01 Issue date: 01-19-2015 SDS US Components Test ResultsSpecies * Estimates for product may be based on additional component data not shown. n-Hexane (CAS 110-54-3) Aquatic LC50Fish 2.101 - 2.981 mg/l, 96 hoursFathead minnow (Pimephales promelas) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Methylpentane 3.74 Isopropyl alcohol 0.05 n-Hexane 3.9 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from residues / unused products If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code D001: Waste Flammable material with a flash point <140 F Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, flammable, Limited QuanittyUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Environmental hazards 10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only IMDG UN1950UN number AEROSOLS, LIMITED QUANTITYUN proper shipping name 7 / 10 Material name: Dry PTFE Lube 03044 Version #: 01 Issue date: 01-19-2015 SDS US 2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance n-Hexane (CAS 110-54-3) CERCLA Hazardous Substance List (40 CFR 302.4) n-Hexane (CAS 110-54-3) CERCLA Hazardous Substances: Reportable quantity n-Hexane (CAS 110-54-3) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List n-Hexane (CAS 110-54-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Food and Drug Administration (FDA) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance No US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act 2-Methylpentane (CAS 107-83-5) Isopropyl alcohol (CAS 67-63-0) n-Hexane (CAS 110-54-3) US. Massachusetts RTK - Substance List 2-Methylpentane (CAS 107-83-5) Isopropyl alcohol (CAS 67-63-0) n-Hexane (CAS 110-54-3) US. Pennsylvania Worker and Community Right-to-Know Law Isopropyl alcohol (CAS 67-63-0) 2-Methylpentane (CAS 107-83-5) 8 / 10 Material name: Dry PTFE Lube 03044 Version #: 01 Issue date: 01-19-2015 SDS US n-Hexane (CAS 110-54-3) US. Rhode Island RTK n-Hexane (CAS 110-54-3) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 98 % Consumer products (40 CFR 59, Subpt. C) Not regulated State Consumer products Not regulated VOC content (CA) 98 % VOC content (OTC) 98 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 01-19-2015 Prepared by Allison Cho Version # 01 Further information CRC # 670-670A HMIS? ratings Health: 2* Flammability: 4 Physical hazard: 0 Personal protection: B NFPA ratings Health: 2 Flammability: 4 Instability: 0 NFPA ratings 02 4 9 / 10 Material name: Dry PTFE Lube 03044 Version #: 01 Issue date: 01-19-2015 SDS US Disclaimer CRC cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user?s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. 10 / 10 Material name: Dry PTFE Lube 03044 Version #: 01 Issue date: 01-19-2015 SDS US