SAFETY DATA SHEET 1. Identification Product identifier QC-82? Pro-Strength Degreaser Other means of identification Product code 05482 Recommended use General purpose degreaser Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Liquefied gasGases under pressurePhysical hazards Category 2ASerious eye damage/eye irritationHealth hazards Category 2Specific target organ toxicity, repeated exposure Category 3Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 49 ?C/120 ?F. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Do not breathe gas, mist or vapor. Wash hands thoroughly after handling. Wear eye/face protection. Avoid release to the environment. Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Get medical advice/attention if you feel unwell. Storage Protect from sunlight. Store in a well-ventilated place. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information 15.08% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 15.53% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 1 / 8 Material name: QC-82? Pro-Strength Degreaser 2370 Version #: 01 Issue date: 11-21-2013 SDS US 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 7732-18-5Water 70 - 80 68476-86-8Liquefied Petroleum Gas 5 - 10 ProprietarySurfactant 5 - 10 111-76-22-Butoxyethanol 3 - 5 6132-04-3Trisodium citrate dihydrate 3 - 5 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact Rinse skin with water/shower. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Most important symptoms/effects, acute and delayed Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water. Unsuitable extinguishing media None known. Specific hazards arising from the chemical Contents under pressure. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800 meters (1/2 mile) in all directions. ALWAYS stay away from tanks engulfed in flame. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. In the event of fire, cool tanks with water spray. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not breathe gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Collect spillage. Dike far ahead of spill for later disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Prevent entry into waterways, sewer, basements or confined areas. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 2 / 8 Material name: QC-82? Pro-Strength Degreaser 2370 Version #: 01 Issue date: 11-21-2013 SDS US 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor. Do not breathe gas. Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label. Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Contents under pressure. Do not expose to heat or store at temperatures above 120?F/49?C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep out of the reach of children. 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 240 mg/m32-Butoxyethanol (CAS 111-76-2) 50 ppm US. ACGIH Threshold Limit Values ValueComponents Type TWA 20 ppm2-Butoxyethanol (CAS 111-76-2) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 24 mg/m32-Butoxyethanol (CAS 111-76-2) 5 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine *2-Butoxyethanol (CAS 111-76-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-Butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennesse OELs: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as nitrile or rubber. Other Wear appropriate chemical resistant clothing. 3 / 8 Material name: QC-82? Pro-Strength Degreaser 2370 Version #: 01 Issue date: 11-21-2013 SDS US Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Light yellow. Odor Mild. Odor threshold Not available. pH 9.1 Melting point/freezing point -103 ?F (-75 ?C) estimated Initial boiling point and boiling range 212 ?F (100 ?C) estimated Flash point None (Tag Closed Cup) Evaporation rate Slow. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) 1.3 % estimated Flammability limit - upper (%) 10.6 % estimated Vapor pressure 278 hPa estimated Vapor density Not available. Relative density 1.04 estimated Solubility (water) Soluble. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 302 ?F (150 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 87.2 % estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Heat, flames and sparks. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Carbon oxides. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. May cause damage to organs by inhalation. Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Causes serious eye irritation. Symptoms related to the physical, chemical and toxicological characteristics Symptoms may include stinging, tearing, redness, swelling, and blurred vision. 4 / 8 Material name: QC-82? Pro-Strength Degreaser 2370 Version #: 01 Issue date: 11-21-2013 SDS US Information on toxicological effects Acute toxicity Causes eye irritation. Test ResultsProduct Species QC-82? Pro-Strength Degreaser LD50 Rabbit Dermal Acute 4508.5723 mg/kg estimated LC50 Rat Inhalation 9667.0244 ppm, 4 hours estimated 68.2245 mg/l, 4 hours estimated LD50 Rat Oral 4712.3774 mg/kg estimated * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure May cause damage to organs through prolonged or repeated exposure. Aspiration hazard Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. May cause damage to organs through prolonged or repeated exposure. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected. Product Test ResultsSpecies QC-82? Pro-Strength Degreaser Acute EC50Crustacea 11.1767 mg/l, 48 hours estimatedDaphnia LC50Fish 36.3294 mg/l, 96 hours estimatedFish Components Test ResultsSpecies 2-Butoxyethanol (CAS 111-76-2) Aquatic Acute EC50Crustacea 1550 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish > 1000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Surfactant (CAS Proprietary) Acute EC50Crustacea 1 - 10 mg/l, 48 hoursDaphnia LC50Fish 1 - 10 mg/l, 96 hoursFish 5 / 8 Material name: QC-82? Pro-Strength Degreaser 2370 Version #: 01 Issue date: 11-21-2013 SDS US Components Test ResultsSpecies * Estimates for product may be based on additional component data not shown. Trisodium citrate dihydrate (CAS 6132-04-3) Aquatic EC50Crustacea 655 - 825.9 mg/l, 48 hoursWater flea (Ceriodaphnia dubia) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) 2-Butoxyethanol 0.81, log Pow Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from residues / unused products The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Empty container can be recycled. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national regulations. Hazardous waste code Not regulated. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1950UN number Aerosols, non-flammable, limited quantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk 2.2Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, non-flammable, limited quantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Environmental hazards 2LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only IMDG UN1950UN number AEROSOLS, LIMITED QUANTITYUN proper shipping name 2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 6 / 8 Material name: QC-82? Pro-Strength Degreaser 2370 Version #: 01 Issue date: 11-21-2013 SDS US 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance 2-Butoxyethanol (CAS 111-76-2) CERCLA Hazardous Substance List (40 CFR 302.4) 2-Butoxyethanol (CAS 111-76-2) CERCLA Hazardous Substances: Reportable quantity Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Food and Drug Administration (FDA) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance No US state regulations US. New Jersey RTK - Substances: Listed substance 2-Butoxyethanol (CAS 111-76-2) US. Massachusetts RTK - Substance List 2-Butoxyethanol (CAS 111-76-2) US. Pennsylvania RTK - Hazardous Substances 2-Butoxyethanol (CAS 111-76-2) US. Rhode Island RTK 2-Butoxyethanol (CAS 111-76-2) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 9.7 % Consumer products (40 CFR 59, Subpt. C) Not regulated State Consumer products This product is regulated as a General Purpose Degreaser (aerosol). This product is compliant for use in all 50 states. VOC content (CA) 9.7 % VOC content (OTC) 9.7 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustralia Australian Inventory of Chemical Substances (AICS) 7 / 8 Material name: QC-82? Pro-Strength Degreaser 2370 Version #: 01 Issue date: 11-21-2013 SDS US Country(s) or region Inventory name On inventory (yes/no)* YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 11-21-2013 Prepared by Allison Cho Version # 01 Further information CRC # 692A HMIS? ratings Health: 2* Flammability: 1 Physical hazard: 0 Personal protection: B NFPA ratings Health: 2 Flammability: 1 Instability: 0 Disclaimer The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. 8 / 8 Material name: QC-82? Pro-Strength Degreaser 2370 Version #: 01 Issue date: 11-21-2013 SDS US