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SAFETY DATA SEEET 1. Identification Valve-Kleen? Oil Treatment Valve n Lifter CleanerProduct identifier Other means of identification No. 05331 (Item# 1003770)Product Code Engine valve and lieter cleanerRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: CRC Industries, Inc.Company name 885 Louis Dr.Address Warminster, PA 18974 US Telephone 215-674-4300General Information 800-521-3168Technical Assistance 800-272-4620Customer Service 800-424-9300 (US)24-Eour Emergency 703-527-3887 (International)(CEEMTREC) www.crcindustries.comWebsite 2. Eazard(s) identification Category 3Flammable liquidsPhysical hazards Category 4Acute toxicity, dermalEealth hazards Category 4Acute toxicity, inhalation Category 2Skin corrosion/irritation Category 2ASerious eye damage/eye irritation Category 2Carcinogenicity Category 2Reproductive toxicity (the unborn child) Category 3 respiratory tract irritationSpecieic target organ toxicity, single exposure Category 2 (central nervous system, ears, kidney, liver, peripheral nervous system) Specieic target organ toxicity, repeated exposure Category 1Aspiration hazard Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3Hazardous to the aquatic environment, long-term hazard Not classieied.OSEA defined hazards Label elements Signal word Danger Eazard statement Flammable liquid and vapor. May be eatal ie swallowed and enters airways. Harmeul in contact with skin. Causes skin irritation. Causes serious eye irritation. Harmeul ie inhaled. May cause respiratory irritation. Suspected oe causing cancer. Suspected oe damaging the unborn child. May cause damage to organs (central nervous system, ears, kidney, liver, peripheral nervous system) through prolonged or repeated exposure. Toxic to aquatic liee. Harmeul to aquatic liee with long lasting eeeects. 1 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US Precautionary statement Prevention Obtain special instructions beeore use. Do not handle until all saeety precautions have been read and understood. Keep away erom heat/sparks/open elames/hot sureaces. - No smoking. Keep container tightly closed. Use explosion-prooe electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe mist or vapor. Use with adequate ventilation. Open doors and windows or use other means to ensure a eresh air supply during use and while product is drying. Ie you experience any symptoms listed on this label, increase ventilation or leave the area. Wash thoroughly aeter handling. Wear protective gloves/protective clothing/eye protection/eace protection. Avoid release to the environment. Response Ie swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Ie on skin (or hair): Take oee immediately all contaminated clothing. Rinse skin with water/shower. Ie skin irritation occurs: Get medical advice/attention. Take oee contaminated clothing and wash beeore reuse. Ie inhaled: Remove person to eresh air and keep comeortable eor breathing. Call a poison center/doctor ie you eeel unwell. Ie in eyes: Rinse cautiously with water eor several minutes. Remove contact lenses, ie present and easy to do. Continue rinsing. Ie eye irritation persists: Get medical advice/attention. Ie exposed or concerned: Get medical advice/attention. In case oe eire: Do not use water jet as an extinguisher, as this will spread the eire. Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose oe contents/container in accordance with local/regional/national regulations. Eazard(s) not otherwise classified (ENOC) Static accumulating elammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause elash eire or explosion. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 1330-20-7xylene 30 - 40 64742-70-7paraeein oils (petroleum), catalytic dewaxed heavy 20 - 30 100-41-4ethylbenzene 10 - 20 64742-71-8paraeein oils (petroleum), catalytic dewaxed light 10 - 20 108-88-3toluene 3 - 5 98-82-8cumene < 1 Specieic chemical identity and/or percentage oe composition has been withheld as a trade secret. 4. First-aid measures Remove victim to eresh air and keep at rest in a position comeortable eor breathing. Oxygen or artieicial respiration ie needed. Call a POISON CENTER or doctor/physician ie you eeel unwell. Inhalation Take oee immediately all contaminated clothing. Rinse skin with water/shower. Get medical advice/attention ie you eeel unwell. Ie skin irritation occurs: Get medical advice/attention. Wash contaminated clothing beeore reuse. Skin contact Immediately elush eyes with plenty oe water eor at least 15 minutes. Remove contact lenses, ie present and easy to do. Continue rinsing. Get medical attention ie irritation develops and persists. Eye contact Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ie vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Ingestion Aspiration may cause pulmonary edema and pneumonitis. Narcosis. Behavioral changes. Decrease in motor eunctions. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Edema. Jaundice. Prolonged exposure may cause chronic eeeects. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While elushing, remove clothes which do not adhere to aeeected area. Call an ambulance. Continue elushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Take oee all contaminated clothing immediately. IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware oe the material(s) involved, and take precautions to protect themselves. Show this saeety data sheet to the doctor in attendance. Wash contaminated clothing beeore reuse. General information 2 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US 5. Fire-fighting measures Water eog. Foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used eor small eires only. Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the eire.Unsuitable extinguishing media Vapors may eorm explosive mixtures with air. Vapors may travel considerable distance to a source oe ignition and elash back. This product is a poor conductor oe electricity and can become electrostatically charged. Ie sueeicient charge is accumulated, ignition oe elammable mixtures can occur. Static electricity accumulation may be signieicantly increased by the presence oe small quantities oe water or other contaminants. Material will eloat and may ignite on sureace oe water. During eire, gases hazardous to health may be eormed. Specific hazards arising from the chemical Sele-contained breathing apparatus and eull protective clothing must be worn in case oe eire.Special protective equipment and precautions for firefighters In case oe eire and/or explosion do not breathe eumes. Move containers erom eire area ie you can do so without risk. Fire fighting equipment/instructions Flammable liquid and vapor.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away erom and upwind oe spill/leak. Eliminate all ignition sources (no smoking, elares, sparks, or elames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces beeore entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised ie signieicant spillages cannot be contained. For personal protection, see section 8 oe the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, elares, sparks, or elames in immediate area). Keep combustibles (wood, paper, oil, etc.) away erom spilled material. Take precautionary measures against static discharge. Use only non-sparking tools. This product is miscible in water. Prevent product erom entering drains. Small Spills: Absorb with earth, sand or other non-combustible material and transeer to containers eor later disposal. Wipe up with absorbent material (e.g. cloth, eleece). Clean sureace thoroughly to remove residual contamination. Never return spills to original containers eor re-use. Put material in suitable, covered, labeled containers. For waste disposal, see section 13 oe the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Ineorm appropriate managerial or supervisory personnel oe all environmental releases. Prevent eurther leakage or spillage ie saee to do so. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. Environmental precautions 7. Eandling and storage Obtain special instructions beeore use. Do not handle until all saeety precautions have been read and understood. Do not handle, store or open near an open elame, sources oe heat or sources oe ignition. Protect material erom direct sunlight. Explosion-prooe general and local exhaust ventilation. Minimize eire risks erom elammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Take precautionary measures against static discharges. Use non-sparking tools and explosion-prooe equipment. Do not breathe mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. When using, do not eat, drink or smoke. Pregnant or breasteeeding women must not handle this product. Should be handled in closed systems, ie possible. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly aeter handling. Avoid release to the environment. Wash contaminated clothing beeore reuse. Observe good industrial hygiene practices. For product usage instructions, see the product label. Precautions for safe handling Keep away erom heat, sparks and open elame. Eliminate sources oe ignition. Avoid spark promoters. Store in a cool, dry place out oe direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away erom incompatible materials (see Section 10 oe the SDS). Conditions for safe storage, including any incompatibilities 3 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US 8. Exposure controls/personal protection Occupational exposure limits US. OSEA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents FormType PEL 245 mg/m3cumene (CAS 98-82-8) 50 ppm PEL 435 mg/m3ethylbenzene (CAS 100-41-4) 100 ppm PEL 5 mg/m3 Mist.paraeein oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) PEL 5 mg/m3 Mist.paraeein oils (petroleum), catalytic dewaxed light (CAS 64742-71-8) PEL 435 mg/m3xylene (CAS 1330-20-7) 100 ppm US. OSEA Table Z-2 (29 CFR 1910.1000) ValueComponents Type Ceiling 300 ppmtoluene (CAS 108-88-3) TWA 200 ppm US. ACGIE Threshold Limit Values ValueComponents FormType TWA 50 ppmcumene (CAS 98-82-8) TWA 20 ppmethylbenzene (CAS 100-41-4) TWA 5 mg/m3 Inhalable eraction.paraeein oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) TWA 5 mg/m3 Inhalable eraction.paraeein oils (petroleum), catalytic dewaxed light (CAS 64742-71-8) TWA 20 ppmtoluene (CAS 108-88-3) STEL 150 ppmxylene (CAS 1330-20-7) TWA 100 ppm US. NIOSE: Pocket Guide to Chemical Eazards ValueComponents FormType TWA 245 mg/m3cumene (CAS 98-82-8) 50 ppm STEL 545 mg/m3ethylbenzene (CAS 100-41-4) 125 ppm TWA 435 mg/m3 100 ppm STEL 10 mg/m3 Mist.paraeein oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) TWA 5 mg/m3 Mist. STEL 10 mg/m3 Mist.paraeein oils (petroleum), catalytic dewaxed light (CAS 64742-71-8) TWA 5 mg/m3 Mist. STEL 560 mg/m3toluene (CAS 108-88-3) 150 ppm TWA 375 mg/m3 100 ppm STEL 655 mg/m3xylene (CAS 1330-20-7) 150 ppm TWA 435 mg/m3 100 ppm 4 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US Biological limit values ACGIE Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 0.15 g/g Sum oe mandelic acid and phenylglyoxylic acid Creatinine in urine *ethylbenzene (CAS 100-41-4) 0.3 mg/g o-Cresol, with hydrolysis Creatinine in urine *toluene (CAS 108-88-3) 0.03 mg/l Toluene Urine * 0.02 mg/l Toluene Blood * 1.5 g/g Methylhippuric acids Creatinine in urine *xylene (CAS 1330-20-7) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation cumene (CAS 98-82-8) Can be absorbed through the skin. toluene (CAS 108-88-3) Can be absorbed through the skin. US - Minnesota Eaz Subs: Skin designation applies cumene (CAS 98-82-8) Skin designation applies. toluene (CAS 108-88-3) Skin designation applies. US - Tennessee OELs: Skin designation cumene (CAS 98-82-8) Can be absorbed through the skin. US NIOSE Pocket Guide to Chemical Eazards: Skin designation cumene (CAS 98-82-8) Can be absorbed through the skin. US. OSEA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) cumene (CAS 98-82-8) Can be absorbed through the skin. Explosion-prooe general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. Ie applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. Ie exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash eacilities and emergency shower should be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear saeety glasses with side shields (or goggles).Eye/face protection Skin protection Wear protective gloves such as: Nitrile. Neoprene.Eand protection Wear appropriate chemical resistant clothing.Other Ie engineering controls are not eeasible or ie exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a sele-contained breathing apparatus in coneined spaces and eor emergencies. Air monitoring is needed to determine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing aeter handling the material and beeore eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Liquid.Form Yellow.Color Solvent.Odor Odor threshold Not available. pE Not available. Melting point/freezing point -52.6 ?F (-47 ?C) estimated 5 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US Initial boiling point and boiling range 278.6 ?F (137 ?C) estimated Flash point 82 ERROR An error occured when reading table hmtx java.io.EOFException at org.apache.fontbox.ttf.MemoryTTFDataStream.readSignedShort(MemoryTTFDataStream.java:139) at org.apache.fontbox.ttf.HorizontalMetricsTable.initData(HorizontalMetricsTable.java:62) at org.apache.fontbox.ttf.TrueTypeFont.initializeTable(TrueTypeFont.java:280) at org.apache.fontbox.ttf.AbstractTTFParser.parseTables(AbstractTTFParser.java:128) at org.apache.fontbox.ttf.TTFParser.parseTables(TTFParser.java:80) at org.apache.fontbox.ttf.AbstractTTFParser.parseTTF(AbstractTTFParser.java:109) at org.apache.fontbox.ttf.AbstractTTFParser.parseTTF(AbstractTTFParser.java:84) at org.apache.pdfbox.pdmodel.font.PDTrueTypeFont.getTTFFont(PDTrueTypeFont.java:632) at org.apache.pdfbox.pdmodel.font.PDTrueTypeFont.getFontWidth(PDTrueTypeFont.java:673) at org.apache.pdfbox.pdmodel.font.PDSimpleFont.getFontWidth(PDSimpleFont.java:231) at org.apache.pdfbox.util.PDFStreamEngine.processEncodedText(PDFStreamEngine.java:411) at org.apache.pdfbox.util.operator.ShowText.process(ShowText.java:50) at org.apache.pdfbox.util.PDFStreamEngine.processOperator(PDFStreamEngine.java:557) at org.apache.pdfbox.util.PDFStreamEngine.processSubStream(PDFStreamEngine.java:268) at org.apache.pdfbox.util.PDFStreamEngine.processSubStream(PDFStreamEngine.java:235) at org.apache.pdfbox.util.PDFStreamEngine.processStream(PDFStreamEngine.java:215) at org.apache.pdfbox.util.PDFTextStripper.processPage(PDFTextStripper.java:460) at org.apache.pdfbox.util.PDFTextStripper.processPages(PDFTextStripper.java:385) at org.apache.pdfbox.util.PDFTextStripper.writeText(PDFTextStripper.java:344) at org.apache.tika.parser.pdf.PDF2XHTML.process(PDF2XHTML.java:130) at org.apache.tika.parser.pdf.PDFParser.parse(PDFParser.java:149) at org.apache.tika.parser.CompositeParser.parse(CompositeParser.java:281) at org.apache.tika.parser.CompositeParser.parse(CompositeParser.java:281) at org.apache.tika.parser.AutoDetectParser.parse(AutoDetectParser.java:120) at org.apache.tika.cli.TikaCLI$OutputType.process(TikaCLI.java:180) at org.apache.tika.cli.TikaCLI.process(TikaCLI.java:459) at org.apache.tika.cli.TikaCLI.main(TikaCLI.java:137) ERROR An error occured when reading table hmtx java.io.EOFException at org.apache.fontbox.ttf.MemoryTTFDataStream.readSignedShort(MemoryTTFDataStream.java:139) at org.apache.fontbox.ttf.HorizontalMetricsTable.initData(HorizontalMetricsTable.java:62) at org.apache.fontbox.ttf.TrueTypeFont.initializeTable(TrueTypeFont.java:280) at org.apache.fontbox.ttf.TrueTypeFont.getHorizontalMetrics(TrueTypeFont.java:204) at org.apache.fontbox.ttf.AbstractTTFParser.parseTables(AbstractTTFParser.java:167) at org.apache.fontbox.ttf.TTFParser.parseTables(TTFParser.java:80) at org.apache.fontbox.ttf.AbstractTTFParser.parseTTF(AbstractTTFParser.java:109) at org.apache.fontbox.ttf.AbstractTTFParser.parseTTF(AbstractTTFParser.java:84) at org.apache.pdfbox.pdmodel.font.PDTrueTypeFont.getTTFFont(PDTrueTypeFont.java:632) at org.apache.pdfbox.pdmodel.font.PDTrueTypeFont.getFontWidth(PDTrueTypeFont.java:673) at org.apache.pdfbox.pdmodel.font.PDSimpleFont.getFontWidth(PDSimpleFont.java:231) at org.apache.pdfbox.util.PDFStreamEngine.processEncodedText(PDFStreamEngine.java:411) at org.apache.pdfbox.util.operator.ShowText.process(ShowText.java:50) at org.apache.pdfbox.util.PDFStreamEngine.processOperator(PDFStreamEngine.java:557) at org.apache.pdfbox.util.PDFStreamEngine.processSubStream(PDFStreamEngine.java:268) at org.apache.pdfbox.util.PDFStreamEngine.processSubStream(PDFStreamEngine.java:235) at org.apache.pdfbox.util.PDFStreamEngine.processStream(PDFStreamEngine.java:215) at org.apache.pdfbox.util.PDFTextStripper.processPage(PDFTextStripper.java:460) at org.apache.pdfbox.util.PDFTextStripper.processPages(PDFTextStripper.java:385) at org.apache.pdfbox.util.PDFTextStripper.writeText(PDFTextStripper.java:344) at org.apache.tika.parser.pdf.PDF2XHTML.process(PDF2XHTML.java:130) at org.apache.tika.parser.pdf.PDFParser.parse(PDFParser.java:149) at org.apache.tika.parser.CompositeParser.parse(CompositeParser.java:281) at org.apache.tika.parser.CompositeParser.parse(CompositeParser.java:281) at org.apache.tika.parser.AutoDetectParser.parse(AutoDetectParser.java:120) at org.apache.tika.cli.TikaCLI$OutputType.process(TikaCLI.java:180) at org.apache.tika.cli.TikaCLI.process(TikaCLI.java:459) at org.apache.tika.cli.TikaCLI.main(TikaCLI.java:137) ERROR An error occured when reading table hmtx java.io.EOFException at org.apache.fontbox.ttf.MemoryTTFDataStream.readSignedShort(MemoryTTFDataStream.java:139) at org.apache.fontbox.ttf.HorizontalMetricsTable.initData(HorizontalMetricsTable.java:62) at org.apache.fontbox.ttf.TrueTypeFont.initializeTable(TrueTypeFont.java:280) at org.apache.fontbox.ttf.TrueTypeFont.getHorizontalMetrics(TrueTypeFont.java:204) at org.apache.fontbox.ttf.TrueTypeFont.getAdvanceWidth(TrueTypeFont.java:346) at org.apache.pdfbox.pdmodel.font.PDTrueTypeFont.getFontWidth(PDTrueTypeFont.java:677) at org.apache.pdfbox.pdmodel.font.PDSimpleFont.getFontWidth(PDSimpleFont.java:231) at org.apache.pdfbox.util.PDFStreamEngine.processEncodedText(PDFStreamEngine.java:411) at org.apache.pdfbox.util.operator.ShowText.process(ShowText.java:50) at org.apache.pdfbox.util.PDFStreamEngine.processOperator(PDFStreamEngine.java:557) at org.apache.pdfbox.util.PDFStreamEngine.processSubStream(PDFStreamEngine.java:268) at org.apache.pdfbox.util.PDFStreamEngine.processSubStream(PDFStreamEngine.java:235) at org.apache.pdfbox.util.PDFStreamEngine.processStream(PDFStreamEngine.java:215) at org.apache.pdfbox.util.PDFTextStripper.processPage(PDFTextStripper.java:460) at org.apache.pdfbox.util.PDFTextStripper.processPages(PDFTextStripper.java:385) at org.apache.pdfbox.util.PDFTextStripper.writeText(PDFTextStripper.java:344) at org.apache.tika.parser.pdf.PDF2XHTML.process(PDF2XHTML.java:130) at org.apache.tika.parser.pdf.PDFParser.parse(PDFParser.java:149) at org.apache.tika.parser.CompositeParser.parse(CompositeParser.java:281) at org.apache.tika.parser.CompositeParser.parse(CompositeParser.java:281) at org.apache.tika.parser.AutoDetectParser.parse(AutoDetectParser.java:120) at org.apache.tika.cli.TikaCLI$OutputType.process(TikaCLI.java:180) at org.apache.tika.cli.TikaCLI.process(TikaCLI.java:459) at org.apache.tika.cli.TikaCLI.main(TikaCLI.java:137) ?F (27.8 ?C) Setaelash Evaporation rate Fast. Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 1 % estimated Flammability limit - upper (%) 12.8 % estimated Vapor pressure 13.3 hPa estimated Vapor density > 1 (air = 1) Relative density 0.86 Solubility(ies) Solubility (water) Negligible. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 500 ?F (260 ?C) estimated Decomposition temperature Not available. Percent volatile 73.2 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions oe use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions oe normal use.Possibility of hazardous reactions Avoid heat, sparks, open elames and other ignition sources. Contact with incompatible materials.Conditions to avoid Strong acids. Strong oxidizing agents. Halogens.Incompatible materials Carbon oxides.Eazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Harmeul ie inhaled. May cause damage to organs through prolonged or repeated exposure by inhalation. Skin contact Harmeul in contact with skin. Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion Droplets oe the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Symptoms related to the physical, chemical and toxicological characteristics Aspiration may cause pulmonary edema and pneumonitis. Narcosis. Behavioral changes. Decrease in motor eunctions. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. Edema. Jaundice. Information on toxicological effects Acute toxicity May be eatal ie swallowed and enters airways. Harmeul ie inhaled. Harmeul in contact with skin. Test ResultsComponents Species cumene (CAS 98-82-8) Oral Acute LD50 Rat 1400 mg/kg ethylbenzene (CAS 100-41-4) Inhalation Acute LC50 Rat 17.2 mg/l, 4 hours 6 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US Test ResultsComponents Species Oral LD50 Rat 3500 mg/kg paraeein oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) Dermal Acute LD50 Rabbit > 2000 mg/kg Oral LD50 Rat > 5000 mg/kg paraeein oils (petroleum), catalytic dewaxed light (CAS 64742-71-8) Dermal Acute LD50 Rabbit > 2000 mg/kg Oral LD50 Rat > 5000 mg/kg toluene (CAS 108-88-3) Inhalation Acute LC50 Rat 12.5 mg/l, 4 hours xylene (CAS 1330-20-7) Oral Acute LD50 Rat 3500 mg/kg Causes skin irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity Suspected oe causing cancer. IARC Monographs. Overall Evaluation of Carcinogenicity cumene (CAS 98-82-8) 2B Possibly carcinogenic to humans. ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans. paraeein oils (petroleum), catalytic dewaxed light (CAS 64742-71-8) 3 Not classieiable as to carcinogenicity to humans. toluene (CAS 108-88-3) 3 Not classieiable as to carcinogenicity to humans. xylene (CAS 1330-20-7) 3 Not classieiable as to carcinogenicity to humans. OSEA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens cumene (CAS 98-82-8) Reasonably Anticipated to be a Human Carcinogen. Components in this product have been shown to cause birth deeects and reproductive disorders in laboratory animals. Suspected oe damaging the unborn child. Reproductive toxicity Specific target organ toxicity - single exposure May cause respiratory irritation. Specific target organ toxicity - repeated exposure May cause damage to organs (central nervous system, ears, kidney, liver, peripheral nervous system) through prolonged or repeated exposure. Aspiration hazard May be eatal ie swallowed and enters airways. Ie aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation may be harmeul. Prolonged exposure may cause chronic eeeects. 7 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US 12. Ecological information Toxic to aquatic liee. Harmeul to aquatic liee with long lasting eeeects.Ecotoxicity Components Test ResultsSpecies cumene (CAS 98-82-8) Aquatic EC50Crustacea 3.55 - 11.29 mg/l, 48 hoursBrine shrimp (Artemia sp.) LC50Fish 2.7 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) ethylbenzene (CAS 100-41-4) Aquatic Acute EC50Crustacea 1.8 mg/l, 48 hoursDaphnia magna LC50Fish 5.1 mg/l, 96 hoursFish paraeein oils (petroleum), catalytic dewaxed light (CAS 64742-71-8) Aquatic Acute EC50Crustacea > 100 mg/l, 48 hoursDaphnia toluene (CAS 108-88-3) Acute EC50Other 433 mg/l, 96 hoursPseudokirchnerella subcapitata 12.5 mg/l, 72 hours Aquatic Acute EC50Crustacea 6 mg/l, 48 hoursWater elea (Daphnia magna) LC50Fish 5.5 mg/l, 96 hoursCoho salmon,silver salmon (Oncorhynchus kisutch) xylene (CAS 1330-20-7) Aquatic LC50Fish 6.702 - 10.032 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Acute EC50Crustacea 3.82 mg/l, 48 hoursDaphnia magna No data is available on the degradability oe any ingredients in the mixture. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) cumene 3.66 ethylbenzene 3.15 toluene 2.73 xylene 3.12 - 3.2 Bioconcentration factor (BCF) ethylbenzene 1 toluene 90 xylene 23.99 No data available.Mobility in soil Other adverse effects No other adverse environmental eeeects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected erom this component. 13. Disposal considerations Ie discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Disposal instructions D001: Waste Flammable material with a elash point <140 FEazardous waste code 8 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US Since emptied containers may retain product residue, eollow label warnings even aeter container is emptied. Empty containers should be taken to an approved waste handling site eor recycling or disposal. Contaminated packaging 14. Transport information DOT UN1993UN number Flammable liquids, n.o.s. (xylene RQ = 260 LBS, ethylbenzene RQ = 5537 LBS), Limited Quantity UN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk 3Label(s) IIIPacking group Read saeety instructions, SDS and emergency procedures beeore handling.Special precautions for user B1, B52, IB3, T4, TP1, TP29Special provisions 150Packaging exceptions 203Packaging non bulk 242Packaging bulk IATA UN1993UN number Flammable liquid, n.o.s. (xylene, ethylbenzene), Limited QuantityUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIIPacking group 3LERG Code Read saeety instructions, SDS and emergency procedures beeore handling.Special precautions for user Allowed with restrictions.Passenger and cargo aircraft Other information Allowed with restrictions.Cargo aircraft only IMDG UN1993UN number FLAMMABLE LIQUID, N.O.S. (xylene, ethylbenzene), Limited QuantityUN proper shipping name 3Class Transport hazard class(es) -Subsidiary risk IIIPacking group No.Marine pollutant Environmental hazards F-E, S?-E?EmS Read saeety instructions, SDS and emergency procedures beeore handling.Special precautions for user 15. Regulatory information This product is a "Hazardous Chemical" as deeined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. OSEA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance cumene (CAS 98-82-8) ethylbenzene (CAS 100-41-4) toluene (CAS 108-88-3) xylene (CAS 1330-20-7) CERCLA Eazardous Substance List (40 CFR 302.4) cumene (CAS 98-82-8) Listed. ethylbenzene (CAS 100-41-4) Listed. 9 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US toluene (CAS 108-88-3) Listed. xylene (CAS 1330-20-7) Listed. CERCLA Eazardous Substances: Reportable quantity cumene (CAS 98-82-8) 5000 LBS ethylbenzene (CAS 100-41-4) 1000 LBS toluene (CAS 108-88-3) 1000 LBS xylene (CAS 1330-20-7) 100 LBS Spills or releases resulting in the loss oe any ingredient at or above its RQ require immediate notieication to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Other federal regulations Clean Air Act (CAA) Section 112 Eazardous Air Pollutants (EAPs) List ethylbenzene (CAS 100-41-4) toluene (CAS 108-88-3) xylene (CAS 1330-20-7) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number toluene (CAS 108-88-3) 6594 Drug Enforcement Administration (DEA). List 1 n 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) toluene (CAS 108-88-3) 35 %WV DEA Exempt Chemical Mixtures Code Number toluene (CAS 108-88-3) 594 Not regulated.Food and Drug Administration (FDA) Superfund Amendments and Reauthorization Act of 1986 (SARA) Flammable (gases, aerosols, liquids, or solids) Acute toxicity (any route oe exposure) Skin corrosion or irritation Serious eye damage or eye irritation Carcinogenicity Reproductive toxicity Specieic target organ toxicity (single or repeated exposure) Aspiration hazard Hazard not otherwise classieied (HNOC) Classified hazard categories SARA 302 Extremely hazardous substance Not listed. YesSARA 311/312 Eazardous chemical SARA 313 (TRI reporting) Chemical name % by wt.CAS number cumene < 198-82-8 ethylbenzene 10 - 20100-41-4 toluene 3 - 5108-88-3 xylene 30 - 401330-20-7 US state regulations US. New Jersey Worker and Community Right-to-Know Act cumene (CAS 98-82-8) ethylbenzene (CAS 100-41-4) toluene (CAS 108-88-3) xylene (CAS 1330-20-7) US. Massachusetts RTK - Substance List cumene (CAS 98-82-8) ethylbenzene (CAS 100-41-4) paraeein oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) paraeein oils (petroleum), catalytic dewaxed light (CAS 64742-71-8) toluene (CAS 108-88-3) xylene (CAS 1330-20-7) 10 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US US. Pennsylvania Worker and Community Right-to-Know Law cumene (CAS 98-82-8) ethylbenzene (CAS 100-41-4) paraeein oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) paraeein oils (petroleum), catalytic dewaxed light (CAS 64742-71-8) toluene (CAS 108-88-3) xylene (CAS 1330-20-7) US. Rhode Island RTK cumene (CAS 98-82-8) ethylbenzene (CAS 100-41-4) paraeein oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) paraeein oils (petroleum), catalytic dewaxed light (CAS 64742-71-8) toluene (CAS 108-88-3) xylene (CAS 1330-20-7) California Proposition 65 Cancer and Reproductive Harm - www.P65Warnings.ca.govWARNING: California Proposition 65 - CRT: Listed date/Carcinogenic substance acetaldehyde (CAS 75-07-0) Listed: April 1, 1988 benzene (CAS 71-43-2) Listed: February 27, 1987 cumene (CAS 98-82-8) Listed: April 6, 2010 ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 naphthalene (CAS 91-20-3) Listed: April 19, 2002 California Proposition 65 - CRT: Listed date/Developmental toxin benzene (CAS 71-43-2) Listed: December 26, 1997 toluene (CAS 108-88-3) Listed: January 1, 1991 California Proposition 65 - CRT: Listed date/Male reproductive toxin benzene (CAS 71-43-2) Listed: December 26, 1997 US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) cumene (CAS 98-82-8) ethylbenzene (CAS 100-41-4) paraeein oils (petroleum), catalytic dewaxed heavy (CAS 64742-70-7) paraeein oils (petroleum), catalytic dewaxed light (CAS 64742-71-8) toluene (CAS 108-88-3) xylene (CAS 1330-20-7) Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 99.3 % Not regulatedConsumer products (40 CFR 59, Subpt. C) State Not regulatedConsumer products VOC content (CA) 60.4 % VOC content (OTC) 60.4 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory oe Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory oe Existing Chemical Substances in China (IECSC) YesEurope European Inventory oe Existing Commercial Chemical Substances (EINECS) NoEurope European List oe Notieied Chemical Substances (ELINCS) NoJapan Inventory oe Existing and New Chemical Substances (ENCS) 11 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US Country(s) or region Inventory name On inventory (yes/no)* YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory oe Chemicals and Chemical Substances (PICCS) YesTaiwan Taiwan Toxic Chemical Substances (TCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components oe this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components oe the product are not listed or exempt erom listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 02-05-2018Issue date Allison YoonPrepared by Version # 01 CRC # 601A/1002637Further information Health: 2* Flammability: 3 Physical hazard: 0 Personal protection: B EMIS? ratings Health: 2 Flammability: 3 Instability: 0 NFPA ratings NFPA ratings 02 3 The ineormation contained in this document applies to this specieic material as supplied. It may not be valid eor this material ie it is used in combination with any other materials. This ineormation is accurate to the best oe CRC's knowledge or obtained erom sources believed by CRC to be accurate. Beeore using any product, read all warnings and directions on the label. For eurther clarieication oe any ineormation contained on this (M)SDS consult your supervisor, a health & saeety proeessional, or CRC Industries, Inc.. Disclaimer This document has undergone signieicant changes and should be reviewed in its entirety.Revision information 12 / 12 Material name: Valve-Kleen? Oil Treatment Valve & Lieter Cleaner No. 05331 (Item# 1003770) Version #: 01 Issue date: 02-05-2018 SDS US