SAFETY DATA SHEET 1. Identification Natural Degreaser? Citrus-Based DegreaserProduct identifier Other means of identification 14005Product code General purpose degreaserRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Compressed gasGases under pressure Category 2Skin corrosion/irritationHealth hazards Category 2ASerious eye damage/eye irritation Category 1BSensitization, skin Category 3 respiratory tract irritationSpecific target organ toxicity, single exposure Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Category 2Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/eye protection/face protection. Avoid release to the environment. 1 / 9 Material name: Natural Degreaser? Citrus-Based Degreaser 14005 Version #: 01 Issue date: 04-28-2015 SDS US Response If on skin: Wash with plenty of water. If skin irritation or rash occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Collect spillage. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) None known. 3. Composition/information on ingredients Mixtures CAS number %Common name and synonymsChemical name 29911-27-1Dipropylene glycol monopropyl ether (dpmp) 60 - 70 88917-22-0Dipropylene glycol monomethyl ether acetate 20 - 30 5989-27-5d-Limonene 5 - 10 124-38-9Carbon dioxide 3 - 5 68956-56-9Dipentene 1 - 3 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Inhalation Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Wash contaminated clothing before reuse. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact If ingestion of a large amount does occur, call a poison control center immediately. Rinse mouth.Ingestion Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media Contents under pressure. Pressurized container may rupture when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. General fire hazards 2 / 9 Material name: Natural Degreaser? Citrus-Based Degreaser 14005 Version #: 01 Issue date: 04-28-2015 SDS US 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many vapors are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Environmental precautions 7. Handling and storage Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. For product usage instructions, please see the product label. Precautions for safe handling Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 9000 mg/m3Carbon dioxide (CAS 124-38-9) 5000 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 30000 ppmCarbon dioxide (CAS 124-38-9) TWA 5000 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type STEL 54000 mg/m3Carbon dioxide (CAS 124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm 3 / 9 Material name: Natural Degreaser? Citrus-Based Degreaser 14005 Version #: 01 Issue date: 04-28-2015 SDS US US. AIHA Workplace Environmental Exposure Level (WEEL) Guides ValueComponents Type TWA 165.5 mg/m3d-Limonene (CAS 5989-27-5) 30 ppm No biological exposure limits noted for the ingredient(s).Biological limit values Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear protective gloves such as: Nitrile. Viton?. Polyvinyl chloride (PVC).Hand protection Wear appropriate chemical resistant clothing.Other If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Aerosol.Form Water-white.Color Citrus.Odor Odor threshold Not available. pH Not available. Melting point/freezing point -139.9 ?F (-95.5 ?C) estimated Initial boiling point and boiling range 304 ?F (151.1 ?C) estimated Flash point 150 ?F (65.6 ?C) Tag Closed Cup Evaporation rate Slow. Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 0.7 % estimated Flammability limit - upper (%) 5.4 % estimated Vapor pressure 2076.9 hPa estimated Vapor density > 1 (air = 1) Relative density 0.95 estimated Solubility (water) Negligible. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 401 ?F (205 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. 4 / 9 Material name: Natural Degreaser? Citrus-Based Degreaser 14005 Version #: 01 Issue date: 04-28-2015 SDS US Percent volatile 96.4 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Conditions to avoid Strong acids. Strong bases. Strong oxidizing agents.Incompatible materials Aldehydes. Ketones. Organic acids. Carbon oxides.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation May cause irritation to the respiratory system. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. May cause an allergic skin reaction. Eye contact Causes serious eye irritation. Ingestion Swallowing small amounts during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. May cause gastrointestinal irritation. Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause respiratory irritation. Skin irritation. May cause redness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Information on toxicological effects Acute toxicity May cause an allergic skin reaction. May cause respiratory irritation. Test ResultsProduct Species Natural Degreaser? Citrus-Based Degreaser Dermal Acute LD50 Rabbit 2305 mg/kg estimated Inhalation LC50 Rat 24 mg/l, 4 Hours estimated Oral * Estimates for product may be based on additional component data not shown. LD50 Rat 2147 mg/kg estimated Causes skin irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eye irritation Respiratory sensitization Not a respiratory sensitizer. May cause an allergic skin reaction.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity d-Limonene (CAS 5989-27-5) 3 Not classifiable as to carcinogenicity to humans. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure May cause respiratory irritation. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 5 / 9 Material name: Natural Degreaser? Citrus-Based Degreaser 14005 Version #: 01 Issue date: 04-28-2015 SDS US 12. Ecological information Toxic to aquatic life with long lasting effects.Ecotoxicity Product Test ResultsSpecies Natural Degreaser? Citrus-Based Degreaser Aquatic LC50Fish 8.5631 mg/l, 96 hours estimatedFish Acute EC50Crustacea 159.6211 mg/l, 48 hours estimatedDaphnia Components Test ResultsSpecies Dipropylene glycol monomethyl ether acetate (CAS 88917-22-0) Aquatic Acute LC50Crustacea 2701 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 151 mg/l, 96 hoursFathead minnow (Pimephales promelas) 111 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Dipropylene glycol monopropyl ether (dpmp) (CAS 29911-27-1) Aquatic Acute EC50Crustacea > 100 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish > 100 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) d-Limonene (CAS 5989-27-5) Aquatic EC50Crustacea 69.6 mg/l, 48 hoursWater flea (Daphnia pulex) * Estimates for product may be based on additional component data not shown. LC50Fish 0.619 - 0.796 mg/l, 96 hoursFathead minnow (Pimephales promelas) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) Dipropylene glycol monomethyl ether acetate 0.61 OECD 107 Dipropylene glycol monopropyl ether (dpmp) 0.87 OECD 107 d-Limonene 4.232 No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Disposal of waste from residues / unused products D001: Waste Flammable material with a flash point <140 FHazardous waste code Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contaminated packaging 14. Transport information DOT UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 6 / 9 Material name: Natural Degreaser? Citrus-Based Degreaser 14005 Version #: 01 Issue date: 04-28-2015 SDS US 2.1Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group YesEnvironmental hazards 10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only IMDG UN1950UN number AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANTUN proper shipping name 2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group YesMarine pollutant Environmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Not listed. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. CERCLA Hazardous Substances: Reportable quantity Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) 7 / 9 Material name: Natural Degreaser? Citrus-Based Degreaser 14005 Version #: 01 Issue date: 04-28-2015 SDS US Not regulated.Food and Drug Administration (FDA) Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Section 311/312 Hazard categories NoSARA 302 Extremely hazardous substance US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Carbon dioxide (CAS 124-38-9) US. Massachusetts RTK - Substance List Carbon dioxide (CAS 124-38-9) US. Pennsylvania Worker and Community Right-to-Know Law Carbon dioxide (CAS 124-38-9) US. Rhode Island RTK None. US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 97 % Not regulatedConsumer products (40 CFR 59, Subpt. C) State This product is regulated as a General Purpose Degreaser (aerosol). This product is compliant for use in all 50 states. Consumer products VOC content (CA) 9.7 % VOC content (OTC) 9.7 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) YesEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 04-28-2015Issue date Allison ChoPrepared by 8 / 9 Material name: Natural Degreaser? Citrus-Based Degreaser 14005 Version #: 01 Issue date: 04-28-2015 SDS US Version # 01 CRC # 598EFurther information Health: 1 Flammability: 3 Physical hazard: 0 Personal protection: B HMIS? ratings Health: 1 Flammability: 3 Instability: 0 NFPA ratings NFPA ratings 01 3 The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. Disclaimer 9 / 9 Material name: Natural Degreaser? Citrus-Based Degreaser 14005 Version #: 01 Issue date: 04-28-2015 SDS US