SAFETY DATA SHEET 1. Identification Product identifier Wasp & Hornet Killer Plus? Other means of identification Product code 14010 Registration number EPA: 55809-3 Recommended use Wasp and hornet insecticide Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Compressed gasGases under pressure Category 2Skin corrosion/irritationHealth hazards Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazard Category 1Hazardous to the aquatic environment, acute hazard Environmental hazards Category 1Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Causes skin irritation. May cause drowsiness or dizziness. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Avoid breathing mist or vapor. Wash thoroughly after handling. Wear protective gloves. Avoid release to the environment. 1 / 9 Material name: Wasp & Hornet Killer Plus? 14010 Version #: 01 Issue date: 03-11-2015 SDS US Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash with plenty of water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. Collect spillage. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) None known. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 64742-47-8Distillates (petroleum), hydrotreated light 90 - 100 124-38-9Carbon dioxide 1 - 3 7696-12-0Tetramethrin 0.2 26002-80-2d-Phenothrin 0.1 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Remove contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Continue rinsing. Remove contact lenses, if present and easy to do. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Never give anything by mouth to a victim who is unconscious or is having convulsions. Most important symptoms/effects, acute and delayed May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause pulmonary edema and pneumonitis. Skin irritation. May cause redness and pain. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Dry chemicals. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. Pressurized container may rupture when exposed to heat or flame. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may rupture when exposed to heat or flame. 2 / 9 Material name: Wasp & Hornet Killer Plus? 14010 Version #: 01 Issue date: 03-11-2015 SDS US 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Prevent entry into waterways, sewer, basements or confined areas. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Conditions for safe storage, including any incompatibilities Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 9000 mg/m3Carbon dioxide (CAS 124-38-9) 5000 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 30000 ppmCarbon dioxide (CAS 124-38-9) TWA 5000 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type STEL 54000 mg/m3Carbon dioxide (CAS 124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm TWA 100 mg/m3Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Biological limit values No biological exposure limits noted for the ingredient(s). 3 / 9 Material name: Wasp & Hornet Killer Plus? 14010 Version #: 01 Issue date: 03-11-2015 SDS US Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as: Neoprene. Nitrile. Other Wear appropriate chemical resistant clothing. Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Clear. Odor Petroleum. Odor threshold Not available. pH Not available. Melting point/freezing point -72.4 ?F (-58 ?C) estimated Initial boiling point and boiling range 336 ?F (168.9 ?C) estimated Flash point 205 ?F (96.1 ?C) Pensky-Martens Closed Cup Evaporation rate Slow. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) 0.5 % estimated Flammability limit - upper (%) 5.5 % estimated Vapor pressure 1637.3 hPa estimated Vapor density > 2 (air = 1) Relative density 0.82 estimated Solubility (water) Negligible. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 410 ?F (210 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 95.8 % estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 4 / 9 Material name: Wasp & Hornet Killer Plus? 14010 Version #: 01 Issue date: 03-11-2015 SDS US Conditions to avoid Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Strong acids. Strong bases. Hazardous decomposition products Carbon oxides. 11. Toxicological information Information on likely routes of exposure Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Direct contact with eyes may cause temporary irritation. Symptoms related to the physical, chemical and toxicological characteristics May cause drowsiness and dizziness. Headache. Nausea, vomiting. Aspiration may cause pulmonary edema and pneumonitis. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. Test ResultsProduct Species Wasp & Hornet Killer Plus? LD50 Rabbit Dermal Acute 2093.4304 mg/kg estimated LC50 Rat Inhalation 5.356 mg/l, 4 Hours estimated LD50 Rat Oral 5138.2534 mg/kg estimated * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Product Test ResultsSpecies Wasp & Hornet Killer Plus? Aquatic Acute EC50Crustacea 54.8358 mg/l, 48 hours estimatedDaphnia 5 / 9 Material name: Wasp & Hornet Killer Plus? 14010 Version #: 01 Issue date: 03-11-2015 SDS US Product Test ResultsSpecies LC50Fish 1.5721 mg/l, 96 hours estimatedFish Components Test ResultsSpecies Distillates (petroleum), hydrotreated light (CAS 64742-47-8) Aquatic Acute LC50Fish 2.2 mg/l, 96 hoursBluegill (Lepomis macrochirus) Tetramethrin (CAS 7696-12-0) Aquatic Acute EC50Crustacea 0.11 mg/l, 48 hoursWater flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50Fish 0.0037 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) Tetramethrin 4.58 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from residues / unused products This product is not a RCRA hazardous waste (See 40 CFR Part 261.20 ? 261.33). If empty: Place in trash or offer for recycling this container. If partly filled: Call your local solid waste agency for disposal instructions. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code Not regulated. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Environmental hazards 10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 6 / 9 Material name: Wasp & Hornet Killer Plus? 14010 Version #: 01 Issue date: 03-11-2015 SDS US Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only IMDG UN1950UN number AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANTUN proper shipping name 2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group YesMarine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance d-Phenothrin (CAS 26002-80-2) Tetramethrin (CAS 7696-12-0) CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. CERCLA Hazardous Substances: Reportable quantity Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Food and Drug Administration (FDA) Not regulated. US EPA Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) FIFRA Information This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. Signal word Warning. Hazard statement Harmful if absorbed through skin. Causes moderate eye irritation. This product is registered in all 50 United States and Puerto Rico. This product is not registered outside of the United States and Puerto Rico. 7 / 9 Material name: Wasp & Hornet Killer Plus? 14010 Version #: 01 Issue date: 03-11-2015 SDS US Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance No US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act Carbon dioxide (CAS 124-38-9) Distillates (petroleum), hydrotreated light (CAS 64742-47-8) d-Phenothrin (CAS 26002-80-2) Tetramethrin (CAS 7696-12-0) US. Massachusetts RTK - Substance List Carbon dioxide (CAS 124-38-9) US. Pennsylvania Worker and Community Right-to-Know Law Carbon dioxide (CAS 124-38-9) Distillates (petroleum), hydrotreated light (CAS 64742-47-8) US. Rhode Island RTK d-Phenothrin (CAS 26002-80-2) Tetramethrin (CAS 7696-12-0) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 96.5 % Consumer products (40 CFR 59, Subpt. C) Not regulated State Consumer products This product is regulated as a Wasp and Hornet Insecticide. This product is compliant for use in all 50 states. VOC content (CA) 1.4 % VOC content (OTC) 1.4 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustralia Australian Inventory of Chemical Substances (AICS) NoCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 8 / 9 Material name: Wasp & Hornet Killer Plus? 14010 Version #: 01 Issue date: 03-11-2015 SDS US 16. Other information, including date of preparation or last revision Issue date 03-11-2015 Prepared by Allison Cho Version # 01 Further information CRC # 431J HMIS? ratings Health: 2 Flammability: 3 Physical hazard: 0 Personal protection: B NFPA ratings Health: 2 Flammability: 3 Instability: 0 NFPA ratings 02 3 Disclaimer CRC cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user?s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. 9 / 9 Material name: Wasp & Hornet Killer Plus? 14010 Version #: 01 Issue date: 03-11-2015 SDS US