SAFETY DATA SHEET 1. Identification Glass CleanerProduct identifier Other means of identification 05401Product code Glass cleanerRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information CRC Industries, Inc.Company name 885 Louis Dr.Address Warminster, PA 18974 US Telephone 215-674-4300General Information 800-521-3168Technical Assistance 800-272-4620Customer Service 800-424-9300 (US)24-Hour Emergency 703-527-3887 (International)(CHEMTREC) www.crcindustries.comWebsite 2. Hazard(s) identification Liquefied gasGases under pressurePhysical hazards Not classified.Health hazards Category 3Hazardous to the aquatic environment, acute hazard Environmental hazards Category 3Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Harmful to aquatic life with long lasting effects. Precautionary statement Prevention Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 49?C/120?F. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use. Avoid release to the environment. Response Wash hands after handling. Storage Protect from sunlight. Store in a well-ventilated place. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) None known. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 7732-18-5water 80 - 90 1 / 10 Material name: Glass Cleaner 05401 Version #: 02 Revision date: 05-11-2017 Issue date: 04-22-2015 SDS US CAS number %Chemical name Common name and synonyms 68476-86-8liquefied petroleum gas 5 - 10 111-76-22-butoxyethanol 1 - 3 64-17-5ethanol 1 - 3 7664-41-7ammonia < 1 67-56-1methanol < 0.2 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Move to fresh air. Call a physician if symptoms develop or persist.Inhalation Wash off with soap and water. Get medical attention if irritation develops and persists.Skin contact Rinse with water. Get medical attention if irritation develops and persists.Eye contact Call a POISON CENTER or doctor/physician.Ingestion Direct contact with eyes may cause temporary irritation.Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically.Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media Pressurized container may rupture when exposed to heat or flame. During fire, gases hazardous to health may be formed. Specific hazards arising from the chemical Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Contents under pressure. Pressurized container may rupture when exposed to heat or flame.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). This product is miscible in water. Prevent product from entering drains. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Environmental precautions 7. Handling and storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not get in eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Precautions for safe handling 2 / 10 Material name: Glass Cleaner 05401 Version #: 02 Revision date: 05-11-2017 Issue date: 04-22-2015 SDS US Level 1 Aerosol. Contents under pressure. Do not expose to heat or store at temperatures above 120?F/49?C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 240 mg/m32-butoxyethanol (CAS 111-76-2) 50 ppm PEL 35 mg/m3ammonia (CAS 7664-41-7) 50 ppm PEL 1900 mg/m3ethanol (CAS 64-17-5) 1000 ppm PEL 260 mg/m3methanol (CAS 67-56-1) 200 ppm US. ACGIH Threshold Limit Values ValueComponents Type TWA 20 ppm2-butoxyethanol (CAS 111-76-2) STEL 35 ppmammonia (CAS 7664-41-7) TWA 25 ppm STEL 1000 ppmethanol (CAS 64-17-5) STEL 250 ppmmethanol (CAS 67-56-1) TWA 200 ppm US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 24 mg/m32-butoxyethanol (CAS 111-76-2) 5 ppm STEL 27 mg/m3ammonia (CAS 7664-41-7) 35 ppm TWA 18 mg/m3 25 ppm TWA 1900 mg/m3ethanol (CAS 64-17-5) 1000 ppm STEL 325 mg/m3methanol (CAS 67-56-1) 250 ppm TWA 260 mg/m3 200 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine *2-butoxyethanol (CAS 111-76-2) 15 mg/l Methanol Urine *methanol (CAS 67-56-1) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. methanol (CAS 67-56-1) Can be absorbed through the skin. 3 / 10 Material name: Glass Cleaner 05401 Version #: 02 Revision date: 05-11-2017 Issue date: 04-22-2015 SDS US US - Minnesota Haz Subs: Skin designation applies 2-butoxyethanol (CAS 111-76-2) Skin designation applies. methanol (CAS 67-56-1) Skin designation applies. US - Tennessee OELs: Skin designation 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. methanol (CAS 67-56-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation methanol (CAS 67-56-1) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. methanol (CAS 67-56-1) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear protective gloves such as: Nitrile. Rubber.Hand protection Wear suitable protective clothing.Other If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Aerosol.Form Clear.Color Ammoniacal.Odor Odor threshold Not available. pH 10.5 Melting point/freezing point Not available. Initial boiling point and boiling range 212 ?F (100 ?C) estimated Flash point None. Evaporation rate Slow. Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 1.3 % estimated Flammability limit - upper (%) 25 % estimated Vapor pressure 280.3 hPa estimated Vapor density > 1 (air = 1) Relative density 0.97 estimated Solubility (water) Soluble. 4 / 10 Material name: Glass Cleaner 05401 Version #: 02 Revision date: 05-11-2017 Issue date: 04-22-2015 SDS US Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 446 ?F (230 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 99.6 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Heat, flames and sparks. Contact with incompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials Carbon oxides. Aldehydes. Ketones. Organic acids.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Not known. Test ResultsComponents Species 2-butoxyethanol (CAS 111-76-2) Dermal Acute LD50 Rabbit > 2000 mg/kg Oral LD50 Rat 1300 mg/kg ammonia (CAS 7664-41-7) Inhalation Acute LC50 Rat 2000 ppm, 4 Hours Oral LD50 Rat 350 mg/kg ethanol (CAS 64-17-5) Dermal Acute LD50 Rabbit 20 g/kg Inhalation LC50 Rat 8000 mg/l, 4 hours Oral LD50 Rat 6.2 g/kg 5 / 10 Material name: Glass Cleaner 05401 Version #: 02 Revision date: 05-11-2017 Issue date: 04-22-2015 SDS US Test ResultsComponents Species methanol (CAS 67-56-1) Dermal Acute LD50 Rabbit 12800 mg/kg Inhalation LC50 Rat 64000 ppm, 4 hours Oral * Estimates for product may be based on additional component data not shown. LD50 Rat 5628 mg/kg Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Direct contact with eyes may cause temporary irritation.Serious eye damage/eye irritation Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity Not classifiable as to carcinogenicity to humans. IARC Monographs. Overall Evaluation of Carcinogenicity 2-butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not classified. Chronic effects May be harmful if absorbed through skin. Prolonged inhalation may be harmful. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information Harmful to aquatic life with long lasting effects.Ecotoxicity Components Test ResultsSpecies 2-butoxyethanol (CAS 111-76-2) Aquatic Acute EC50Crustacea 1550 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish >= 1000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) ammonia (CAS 7664-41-7) Aquatic LC50Fish 0.43 - 0.47 mg/l, 96 hoursChinook salmon (Oncorhynchus tshawytscha) ethanol (CAS 64-17-5) Aquatic Acute EC50Crustacea 7.7 - 11.2 mg/l, 48 hoursWater flea (Daphnia magna) 6 / 10 Material name: Glass Cleaner 05401 Version #: 02 Revision date: 05-11-2017 Issue date: 04-22-2015 SDS US Components Test ResultsSpecies LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas) methanol (CAS 67-56-1) Aquatic EC50Crustacea > 10000 mg/l, 48 hoursWater flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50Fish > 100 mg/l, 96 hoursFathead minnow (Pimephales promelas) Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 2-butoxyethanol 0.81, log Pow ethanol -0.31 methanol -0.77 No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Empty container can be recycled. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Disposal of waste from residues / unused products Not regulated.Hazardous waste code Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT UN1950UN number Aerosols, non-flammable, Limited QuantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk 2.2Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, non-flammable, Limited QuantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group 2LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed with restrictions.Passenger and cargo aircraft Other information Allowed with restrictions.Cargo aircraft only IMDG UN1950UN number AEROSOLS, LIMITED QUANTITYUN proper shipping name 7 / 10 Material name: Glass Cleaner 05401 Version #: 02 Revision date: 05-11-2017 Issue date: 04-22-2015 SDS US 2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Marine pollutant Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 15. Regulatory information All components are on the U.S. EPA TSCA Inventory List. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance 2-butoxyethanol (CAS 111-76-2) CERCLA Hazardous Substance List (40 CFR 302.4) 2-butoxyethanol (CAS 111-76-2) Listed. CERCLA Hazardous Substances: Reportable quantity Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace ethanol (CAS 64-17-5) Low priority Not regulated.Food and Drug Administration (FDA) Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No Section 311/312 Hazard categories NoSARA 302 Extremely hazardous substance US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) 2-butoxyethanol (CAS 111-76-2) ammonia (CAS 7664-41-7) liquefied petroleum gas (CAS 68476-86-8) methanol (CAS 67-56-1) US. New Jersey Worker and Community Right-to-Know Act 2-butoxyethanol (CAS 111-76-2) ammonia (CAS 7664-41-7) 8 / 10 Material name: Glass Cleaner 05401 Version #: 02 Revision date: 05-11-2017 Issue date: 04-22-2015 SDS US ethanol (CAS 64-17-5) methanol (CAS 67-56-1) US. Massachusetts RTK - Substance List 2-butoxyethanol (CAS 111-76-2) ammonia (CAS 7664-41-7) ethanol (CAS 64-17-5) methanol (CAS 67-56-1) US. Pennsylvania Worker and Community Right-to-Know Law 2-butoxyethanol (CAS 111-76-2) ammonia (CAS 7664-41-7) ethanol (CAS 64-17-5) methanol (CAS 67-56-1) US. Rhode Island RTK 2-butoxyethanol (CAS 111-76-2) ammonia (CAS 7664-41-7) ethanol (CAS 64-17-5) methanol (CAS 67-56-1) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance methyl isobutyl ketone (CAS 108-10-1) Listed: November 4, 2011 US - California Proposition 65 - CRT: Listed date/Developmental toxin methanol (CAS 67-56-1) Listed: March 16, 2012 methyl isobutyl ketone (CAS 108-10-1) Listed: March 28, 2014 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 9.6 % CompliantConsumer products (40 CFR 59, Subpt. C) State This product is regulated as a Glass Cleaner (aerosol). This product is compliant for use in all 50 states. Consumer products VOC content (CA) 9.6 % VOC content (OTC) 9.6 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 04-22-2015Issue date 9 / 10 Material name: Glass Cleaner 05401 Version #: 02 Revision date: 05-11-2017 Issue date: 04-22-2015 SDS US 05-11-2017Revision date Allison ChoPrepared by Version # 02 CRC # 411AFurther information Health: 1 Flammability: 0 Physical hazard: 0 Personal protection: B HMIS? ratings Health: 1 Flammability: 0 Instability: 0 NFPA ratings NFPA ratings 01 0 The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC's knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries, Inc.. Disclaimer This document has undergone significant changes and should be reviewed in its entirety.Revision Information 10 / 10 Material name: Glass Cleaner 05401 Version #: 02 Revision date: 05-11-2017 Issue date: 04-22-2015 SDS US