GRAPHITE DRY LUBRICANT Revision: 01/06/2016 Page: 1/7 SAFETY DATA SHEET OSHA HCS (29 CFR 1910.1200) Classification of the substance or mixture OSHA HCS (29 CFR 1910.1200) Flam. Aerosol 1; Liquefied gas; Skin Irrit. 2; Eye Irrit. 2; STOT SE 3; Asp. Tox. 1 Label elements This product is a consumer product and is labeled in accordance with the US Consumer Product Safety Commission regulations which take precedence over OSHA Hazard Communication labeling. The actual container label will not include the label elements below. The labeling below applies to industrial/professional products. Hazard Symbol Signal word(s) DANGER Hazard Statement(s) Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Precautionary Statement(s) Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Use only outdoors or in a well-ventilated area. Avoid breathing spray. Product identifier Trade Name Graphite Dry Lubricant Product Code Revision Date 8-GS 01/06/2016 Relevant identified uses of the substance or mixture and uses advised against Identified Use(s) Lubricant Company Identification The Blaster Corporation 8500 Sweet Valley Drive Valley View, Ohio 44125 Telephone (216) 901-5800 Fax (216) 901-5801 Website: www.blastercorp.com Emergency telephone number CHEMTREC 24 hr. 1-800-424-9300 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION SECTION 2: HAZARDS IDENTIFICATION GRAPHITE DRY LUBRICANT Revision: 01/06/2016 Page: 2/7 Protect from sunlight and do not expose to temperatures exceeding 50 ?C/122 ?F. Wear protective gloves/eye protection. Wash hands and exposed skin after use. Keep out of reach of children. Other hazards Toxic to aquatic life. Toxic to aquatic life with long lasting effects. Hazardous Ingredient(s) % wt. * CAS No. Hazard classification Petroleum Distillate 30 - 40 Trade Secret Flam. Liq. 2; H225 Asp. Tox. 1; H304 Skin Irrit. 2; H315 STOT SE 3; H336 Aquatic Acute 2; H401 Aquatic Chronic 2; H411 Isopropanol 30 - 35 67-63-0 Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336 Propane 15 - 20 74-98-6 Flam. Gas 1; H220 Liquefied gas; H280 Butane 10 - 15 106-97-8 Flam. Gas 1; H220 Liquefied gas; H280 Additional Information - Substances in the product which may present a health or environmental hazard, or which have been assigned occupational exposure limits, are detailed below.: n-Butanol (CAS No. 71-36-3), <1% Propylene glycol methyl ester (CAS No. 107-98-2) <1% * The exact percentage withheld as a trade secret in accordance with 29 CFR 1910.1200. Description of first aid measures Inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. If breathing is labored, administer oxygen. Call a POISON CENTER/doctor if you feel unwell. Skin Contact Wash affected skin with soap and water. If skin irritation occurs, get medical advice/attention. Take off contaminated clothing and wash it before reuse. Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. Ingestion Do not give anything by mouth to an unconscious person. Seek medical treatment. Do NOT induce vomiting. Most important symptoms and effects, both acute and delayed Aspiration of droplets may cause pulmonary oedema. May cause drowsiness and dizziness. Indication of any immediate medical attention and special treatment needed IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS SECTION 4: FIRST AID MEASURES GRAPHITE DRY LUBRICANT Revision: 01/06/2016 Page: 3/7 Extinguishing Media -Suitable Extinguishing Media Extinguish with carbon dioxide, dry chemical, foam or water spray. -Unsuitable Extinguishing Media Do not use water jet. Special hazards arising from the substance or mixture Highly flammable vapor (flash point below 23?C). Advice for fire-fighters A self contained breathing apparatus and suitable protective clothing should be worn in fire conditions. Keep containers cool by spraying with water if exposed to fire. Personal precautions, protective equipment and emergency procedures Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Take precautionary measures against static discharges. Avoid contact with skin and eyes. Avoid breathing vapors. Environmental precautions Prevent liquid entering sewers, basements and work pits. Collect spillage. Methods and material for containment and cleaning up Cover spills with inert absorbent material. Transfer to a container for disposal or recovery. Reference to other sections None Additional Information None Precautions for safe handling Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Avoid contact with skin and eyes. Use product in a well- ventilated area only. Conditions for safe storage, including any incompatibilities -Storage temperature Store locked up.Keep in a cool, well ventilated place. Protect from sunlight. Store at temperatures not exceeding 50 ?C / 122 ?F. Keep container tightly closed. -Incompatible materials This product should be stored away from sources of strong heat or oxidizing chemicals. Specific end use(s) Lubricant Occupational Exposure Limits SUBSTANCE. CAS No. (8hr TWA) (STEL) Note: PEL (OSHA) TLV (ACGIH) PEL (OSHA) TLV (ACGIH) Alkanes and cycloalkanes (C5 - C8) ----- ----- 1500 mg/m3 ----- ----- ----- Alkanes and cycloalkanes (C9 - C15) ----- ----- 1200 mg/m3 ----- ----- ----- Isopropanol 67-63-0 400 ppm 200 ppm ----- 400 ppm ----- n-Butanol 71-36-3 100 ppm 20 ppm ----- ----- ----- Propylene glycol methyl ester 107-98-2 ----- 50 ppm ----- 100 ppm ----- n-Butane 106-97-8 ----- 250 ppm ----- ----- ----- Propane 74-98-6 1000 ppm Aspyx.# ----- ----- # SECTION 5: FIRE-FIGHTING MEASURES SECTION 6: ACCIDENTAL RELEASE MEASURES SECTION 7: HANDLING AND STORAGE SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION GRAPHITE DRY LUBRICANT Revision: 01/06/2016 Page: 4/7 Recommended monitoring method NIOSH 1550 (Naphthas); NIOSH 1500 (hydrocarbons, B.P. 36 - 126 ?C); NIOSH 1400 (alcohols I); NIOSH 1401 (alcohols II); NIOSH 2554 (Glycol Ethers) Exposure controls Appropriate engineering controls Provide adequate ventilation to ensure that the occupational exposure limit is not exceeded. Personal protection equipment Eye/face protection Wear protective eyewear (goggles, face shield, or safety glasses). Skin protection (Hand protection/ Other) Wear suitable gloves if prolonged skin contact is likely (Butyl rubber) Respiratory protection Normally no personal respiratory protection is necessary. In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards Not normally required. Use gloves with insulation for thermal protection, when needed. Environmental Exposure Controls None known Information on basic physical and chemical properties Appearance Aerosol spray Color. Colorless Odor Mild isopropanol odor Odor Threshold (ppm) Not available pH (Value) Not available Melting Point (?C) / Freezing Point (?C) Not available Boiling point/boiling range (?C): Not available Flash Point (?C) -104 (Propane) Evaporation Rate Not available Flammability (solid, gas) Extremely flammable Explosive Limit Ranges 2.1% - 9.5% v/v (Propane) Vapor pressure (Pascal) ca. 95 x 104 (Propane) Vapor Density (Air=1) ca. 1.56 @ 0?C (Propane) Density (g/ml) Not available Solubility (Water) Not available Solubility (Other) Not available Partition Coefficient (n-Octanol/water) Not available Auto Ignition Point (?C) 450 (Propane) Decomposition Temperature (?C) Not available Kinematic Viscosity (@40?C) 0.49 mm2/sec (Naphtha (petroleum) hydrotreated light) Explosive properties Not explosive. Oxidizing properties Not oxidizing. Other information Not available SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES GRAPHITE DRY LUBRICANT Revision: 01/06/2016 Page: 5/7 Reactivity Stable under normal conditions. Chemical stability Stable. Possibility of hazardous reactions None anticipated. Conditions to avoid Avoid contact with heat and ignition sources. Incompatible materials Strong oxidizing agents; Strong Acids; Aldehydes; Halogens; Amines; Halogenated Hydrocarbons, Alkalis.Do not use with aluminum equipment at temperatures exceeding 120?F. Hazardous decomposition product(s) Carbon monoxide, Carbon dioxide, Acrid smoke Exposure routes: Inhalation, Skin Contact, Eye Contact Information on toxicological effects Petroleum distillate (CAS No. Trade Secret) - By analogy with similar materials: Acute toxicity (calculated / estimated) Oral: LD50 >5000 mg/kg-bw Dermal: LD50 >2000 mg/kg-bw Inhalation: LC0 ?7.6 mg/l (Vapor), 4-hr. rat - May cause drowsiness or dizziness. Irritation/Corrosivity Causes skin irritation. Repeated exposure may cause skin dryness or cracking. Sensitization It is not a skin sensitizer. Repeated dose toxicity Dermal: NOEAL >2000 mg/kg bw (systemic effects) Inhalation: NOAEC = 1.4 mg/l (Vapor) Carcinogenicity It is unlikely to present a carcinogenic hazard to man. NTP IARC ACGIH OSHA NIOSH No. No. No. No. No. Mutagenicity Not to be expected Reproductive toxicity Not to be expected Isopropanol (CAS# 67-63-0): Acute toxicity Oral: LD50 = 5.84 g/kg (rat) Inhalation: LC50 > 1000 ppm (rat) 6 hour(s) Dermal: LD50 = 16.4 ml/kg (rabbit) 24 hour(s) May cause drowsiness or dizziness. Irritation/Corrosivity Irritating to eyes. Sensitization It is not a skin sensitizer. Repeated dose toxicity NOAEL = 5,000 ppm (Inhalation) May cause drowsiness or dizziness. Carcinogenicity It is unlikely to present a carcinogenic hazard to man. NTP IARC ACGIH OSHA NIOSH No. No. No. No. No. Mutagenicity There is no evidence of mutagenic potential. Reproductive toxicity Not available Ecotoxicity Petroleum distillate (CAS No. Trade Secret) - By analogy with similar materials: SECTION 10: STABILITY AND REACTIVITY SECTION 11: TOXICOLOGICAL INFORMATION SECTION 12: ECOLOGICAL INFORMATION GRAPHITE DRY LUBRICANT Revision: 01/06/2016 Page: 6/7 Short term LL50 (96 hour): 8.2 mg/L (fish) EL50 (48 hour): 4.5 mg/L (crustacea) EL50 (72 hour): 3.1 mg/L (algae) Long Term NOELR (21 days): 2.6 mg/L (crustacea; reproduction) NOELR (72 hour): 0.5 mg/L (algae; growth rate) Persistence and degradability According to OECD criteria the product is not readily biodegradable but inherently biodegradable. Bioaccumulative potential The product has no potential for bioaccumulation. Mobility in soil Not available. Results of PBT and vPvB assessment Not classified as PBT or vPvB. Other adverse effects None known. Isopropanol (CAS# 67-63-0): Short term LC50 (96 hour): 10,000 mg/l (Fathead minnow (Pimephales promelas)) LC50 24hour(s): >10,000 mg/l (Daphnia magna) Long Term NOEC: 3.37 ?mol/l (Daphnia magna) (Growth rate) Persistence and degradability Readily biodegradable. Bioaccumulative potential Not available. Mobility in soil Not available. Results of PBT and vPvB assessment Not classified as PBT or vPvB. Other adverse effects None known. Waste treatment methods Disposal should be in accordance with local, state or national legislation. Consult an accredited waste disposal contractor or the local authority for advice. U.S. DOT Sea transport (IMDG) Air transport (ICAO/IATA) UN number 1950 1950 1950 Proper Shipping Name Aerosols, flammable Aerosols, flammable Aerosols, flammable Transport hazard class(es) 2.1 2.1 2.1 Packing group Not applicable Not applicable Not applicable Environmental hazards None assigned None assigned None assigned Special precautions for user None assigned None assigned None assigned Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable Safety, health and environmental regulations/legislation specific for the substance or mixture: TSCA (Toxic Substance Control Act) - Inventory Status: All components listed or polymer exempt. Designated Hazardous Substances and Reportable Quantities (40 CFR 302.4): Chemical Name CAS No. Typical %wt. RQ (Pounds) n-Butanol 71-36-3 0.3 5000 SARA 311/312 - Hazard Categories: Fire Sudden Release Reactivity Immediate (acute) Chronic (delayed) SARA 313 - Toxic Chemicals (40 CFR 372): SECTION 13: DISPOSAL CONSIDERATIONS SECTION 14: TRANSPORT INFORMATION SECTION 15: REGULATORY INFORMATION GRAPHITE DRY LUBRICANT Revision: 01/06/2016 Page: 7/7 Isopropanol 67-63-0 33 n-Butanol 71-36-3 0.5 SARA 302 - Extremely Hazardous Substances(40 CFR 355): Chemical Name CAS No. Typical %wt. TPQ (pounds) None ---- ---- ---- California Proposition 65 List: Chemical Name CAS No. Type of Toxicity None ---- ---- The following sections contain revisions or new statements: 1-16. Date of preparation: June 11, 2015 Hazard Statement(s) and Risk Phrases Listed in: SECTION 2:/ SECTION 3: Hazard Statement(s) - H220: Extremely flammable gas. - H222: Extremely flammable aerosol. - H225: Highly flammable liquid and vapor. - H226: Flammable liquid and vapour. - H280: Contains gas under pressure; may explode if heated. - H302: Harmful if swallowed. - H304: May be fatal if swallowed and enters airways. - H315: Causes skin irritation. - H318: Causes serious eye damage. - H319: Causes serious eye irritation. - H335: May cause respiratory irritation. - H336: May cause drowsiness or dizziness. - H401:Toxic to aquatic life. - H411: Toxic to aquatic life with long lasting effects. Training advice: None. Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use. Chemical Name CAS No. Typical %wt. SECTION 16: OTHER INFORMATION Occupational Exposure Limits SARA 311/312 - Hazard Categories: SARA 313 - Toxic Chemicals (40 CFR 372):