Revision Date June 2012 Revision 2 Supersedes date May 2009 SDS No. 10018 SAFETY DATA SHEET CYCLO? BRAKE & PARTS CLEAN According to Regulation (EU) No 453/2010 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name CYCLO? BRAKE & PARTS CLEAN Product No. C-32 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Cleaner for brakes and related parts. 1.3. Details of the supplier of the safety data sheet Cyclo Industries Inc.Supplier Regent House Business Centre 24-25 Nutford Place Marble Arch London W1H 5YN 0797 6921836 E mail This email address is being protected from spambots. You need JavaScript enabled to view it. 1.4. Emergency telephone number 001 312 906 6194 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Repr. Cat. 2;R60. Carc. Cat. 3;R40, Repr. Cat. 3;R63. N;R51/53. Human health See section 11 for additional information on health hazards. Environment Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Physical and Chemical Hazards Aerosol containers can explode when heated, due to excessive pressure build-up. 2.2. Label elements Contains TETRACHLOROETHYLENE 1-BROMOPROPANE Detergent Labelling: >= 30% halogenated hydrocarbons Labelling Toxic Dangerous for the environment Risk Phrases R40 Limited evidence of a carcinogenic effect. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 121 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN R60 May impair fertility. R63 Possible risk of harm to the unborn child. Safety Phrases S23 Do not breathe vapour/spray. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S38 In case of insufficient ventilation, wear suitable respiratory equipment. S45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). S53 Avoid exposure - obtain special instructions before use. S57 Use appropriate containment to avoid environmental contamination. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. P11 Restricted to professional users. A1 Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. 2.3. Other hazards This product does not contain any PBT or vPvB substances. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures TETRACHLOROETHYLENE 60-100% CAS-No.: 127-18-4 EC No.: 204-825-9 Classification (67/548/EEC) Carc. Cat. 3;R40 N;R51/53 Classification (EC 1272/2008) Carc. 2 - H351 Aquatic Chronic 2 - H411 1-BROMOPROPANE 5-10% CAS-No.: 106-94-5 EC No.: 203-445-0 Classification (67/548/EEC) F;R11 Repr. Cat. 2;R60 Repr. Cat. 3;R63 Xn;R48/20 Xi;R36/37/38 R67 Classification (EC 1272/2008) Flam. Liq. 2 - H225 Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Repr. 1B - H360FD STOT SE 3 - H335 STOT SE 3 - H336 STOT RE 2 - H373 CO2 PROPELLANT 1-5% CAS-No.: 124-38-9 EC No.: 204-696-9 Classification (67/548/EEC) Not classified. Classification (EC 1272/2008) Not classified. Substance with a Community workplace exposure limit. The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures 122 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN Inhalation Move the exposed person to fresh air at once. Provide rest, warmth and fresh air. Rinse nose and mouth with water. Get medical attention. Ingestion NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get medical attention immediately! Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if any discomfort continues. Eye contact Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues. 4.2. Most important symptoms and effects, both acute and delayed General information The severity of the symptoms described will vary dependant of the concentration and the length of exposure. Inhalation. Vapours may cause drowsiness and dizziness. Ingestion May cause stomach pain or vomiting. Skin contact Prolonged skin contact may cause redness and irritation. Eye contact Prolonged contact may cause redness and/or tearing. 4.3. Indication of any immediate medical attention and special treatment needed Treat Symptomatically. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media This product is not flammable. Use fire-extinguishing media appropriate for surrounding materials. 5.2. Special hazards arising from the substance or mixture Unusual Fire & Explosion Hazards No unusual fire or explosion hazards noted. Specific hazards Fire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). 5.3. Advice for firefighters Special Fire Fighting Procedures Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control. Protective equipment for fire-fighters Self contained breathing apparatus and full protective clothing must be worn in case of fire. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet. 6.2. Environmental precautions Avoid discharge to the aquatic environment. 6.3. Methods and material for containment and cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Do not contaminate water sources or sewer. 6.4. Reference to other sections Wear protective clothing as described in Section 8 of this safety data sheet. See section 11 for additional information on health hazards. 123 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Provide good ventilation. Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists. Pregnant women should not work with the product, if there is the least risk of exposure. 7.2. Conditions for safe storage, including any incompatibilities Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50?C. Keep away from heat, sparks and open flame. 7.3. Specific end use(s) The identified uses for this product are detailed in Section 1.2. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters STD STEL - 15 MinTWA - 8 HrsName Notes 5000 ppm 9150 mg/m3WEL 15000 ppm 27400 mg/m3CO2 PROPELLANT 50 ppm 345 mg/m3WEL 100 ppm 689 mg/m3TETRACHLOROETHYLENE WEL = Workplace Exposure Limit. 8.2. Exposure controls Engineering measures Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of spray. Respiratory equipment No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air contamination exists. Use respiratory equipment with gas filter, type AX. Hand protection Use suitable protective gloves if risk of skin contact. Use protective gloves made of: Polyvinyl alcohol (PVA). or Viton rubber (fluor rubber). Eye protection Wear approved chemical safety goggles where eye exposure is reasonably probable. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Hygiene measures No specific hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals. Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Aerosol. Colour Colourless. Odour Sweetish. Solubility Insoluble in water Initial boiling point and boiling range 121?C Relative density 1.62 @25?C Vapour density (air=1) 4.1 Vapour pressure 13 mm Hg @20?C Flash point N/A Comments Information given concerns the concentrated solution. 9.2. Other information 124 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN Not known. SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity There are no known reactivity hazards associated with this product. 10.2. Chemical stability Stable under normal temperature conditions and recommended use. 10.3. Possibility of hazardous reactions Hazardous Polymerisation Will not polymerise. 10.4. Conditions to avoid Avoid heat, flames and other sources of ignition. Avoid excessive heat for prolonged periods of time. 10.5. Incompatible materials Materials To Avoid Strong oxidising substances. Strong alkalis. Strong acids. 10.6. Hazardous decomposition products Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Other Health Effects Carcinogen Category 3. Toxic to Reproductive Health Category 3. Inhalation In high concentrations, vapours may irritate throat and respiratory system and cause coughing. Ingestion May irritate and cause stomach pain, vomiting and diarrhoea. Skin contact Liquid may irritate skin. Eye contact Splashes may irritate. Specific effects Contains a substance/a group of substances with possible risk of harm to the unborn child and with possible risk of impaired fertility. Contains a substance/a group of substances which may cause cancer. Toxicological information on ingredients. 125 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN 1-BROMOPROPANE (CAS: 106-94-5) Acute toxicity: Acute Toxicity (Oral LD50) > 2000 mg/kg Rat REACH dossier information Conclusive data but not sufficient for classification. Acute Toxicity (Dermal LD50) > 2000 mg/kg Rat REACH dossier information Conclusive data but not sufficient for classification. Acute Toxicity (Inhalation LC50) Not available. Skin Corrosion/Irritation: Dose 0.5ml 24 hr Rabbit Erythema\eschar score No erythema (0). Oedema score No oedema (0). REACH dossier information Not irritating. Respiratory or skin sensitisation: Skin sensitisation Guinea pig maximization test (GPMT): Guinea Pig REACH dossier information Not Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Bacterial Reverse Mutation Test REACH dossier information Positive. Conclusive data but not sufficient for classification. Genotoxicity - In Vivo Chromosome aberration: REACH dossier information Negative. Conclusive data but not sufficient for classification. Carcinogenicity: Carcinogenicity Not available. Reproductive Toxicity: Suspected of damaging fertility. May damage the unborn child. Specific target organ toxicity - repeated exposure: STOT - Repeated exposure NOAEC <2 mg/l/6hr/day Inhalation. Rat REACH dossier information Not classified as a specific target organ toxicant after repeated exposure. 126 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN TETRACHLOROETHYLENE (CAS: 127-18-4) Acute toxicity: Acute Toxicity (Oral LD50) 3835 mg/kg Rat REACH dossier information Conclusive data but not sufficient for classification. Acute Toxicity (Dermal LD50) Not available. Acute Toxicity (Inhalation LC50) 2613 ppm Mouse 4 hours REACH dossier information Conclusive data but not sufficient for classification. Skin Corrosion/Irritation: Dose 0.5ml 4 hr Rabbit Erythema\eschar score Severe erythema (beef redness) to eschar formation preventing grading of erythema (4). Oedema score Very slight oedema -barely perceptible (1). REACH dossier information Irritating. Respiratory or skin sensitisation: Skin sensitisation Local Lymph Node Assay (LLNA) Mouse REACH dossier information Sensitising. Germ cell mutagenicity: Genotoxicity - In Vitro Gene Mutation: REACH dossier information Negative. This substance has no evidence of mutagenic properties. Genotoxicity - In Vivo Chromosome aberration: REACH dossier information Negative. This substance has no evidence of mutagenic properties. Carcinogenicity: Carcinogenicity Not available. Reproductive Toxicity: Reproductive Toxicity - Fertility Two-generation study: NOAEL 100 ppm Inhalation. Rat REACH dossier information This substance has no evidence of toxicity to reproduction. Reproductive Toxicity - Development Maternal toxicity: NOEC 250 ppm Inhalation. Rat REACH dossier information No evidence of reproductive toxicity in animal studies 127 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN Specific target organ toxicity - repeated exposure: STOT - Repeated exposure 390 mg/kg Oral Mouse REACH dossier information Not classified as a specific target organ toxicant after repeated exposure. SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 12.1. Toxicity Ecological information on ingredients. 1-BROMOPROPANE (CAS: 106-94-5) Acute Toxicity - Fish 96 hours 24.3 mg/l Onchorhynchus mykiss (Rainbow trout) REACH dossier information Acute Toxicity - Aquatic Invertebrates EC50 48 hours 99.3 mg/l Daphnia magna REACH dossier information Acute Toxicity - Aquatic Plants NOEC 96 hours 12.4 mg/l Scenedesmus subspicatus REACH dossier information TETRACHLOROETHYLENE (CAS: 127-18-4) Acute Toxicity - Fish LC50 96 hours 5 mg/l Onchorhynchus mykiss (Rainbow trout) REACH dossier information Acute Toxicity - Aquatic Invertebrates EC50 48 hours 8.5 mg/l Daphnia magna REACH dossier information Acute Toxicity - Aquatic Plants EC50 72 hours 3.64 mg/l Freshwater algae REACH dossier information 12.2. Persistence and degradability Degradability The degradability of the product has not been stated. 128 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN Ecological information on ingredients. 1-BROMOPROPANE (CAS: 106-94-5) Phototransformation Not available. Stability (Hydrolysis) pH4 Half-life: 611 hours @25?C REACH dossier information Biodegradation Water Degradation (19.2%%) 28 days REACH dossier information No biodegradation observed under test conditions. TETRACHLOROETHYLENE (CAS: 127-18-4) Phototransformation Not available. Stability (Hydrolysis) pH7 Half-life: 8.8 months @25?C REACH dossier information No biodegradation observed under test conditions. 12.3. Bioaccumulative potential Bioaccumulative potential No data available on bioaccumulation. Ecological information on ingredients. 1-BROMOPROPANE (CAS: 106-94-5) Bioaccumulation factor Not available. Partition coefficient Not available. TETRACHLOROETHYLENE (CAS: 127-18-4) Bioaccumulation factor BCF 49 REACH dossier information Partition coefficient log Pow 2.53 REACH dossier information 12.4. Mobility in soil Mobility: The product is insoluble in water. 129 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN Ecological information on ingredients. 1-BROMOPROPANE (CAS: 106-94-5) Adsorption/Desorption Coefficient Soil log Koc 1.79 REACH dossier information Henry's Law Constant Not available. Surface tension Not available. TETRACHLOROETHYLENE (CAS: 127-18-4) Adsorption/Desorption Coefficient Not available. Henry's Law Constant Not available. Surface tension 32.1 mN/m @20?C REACH dossier information 12.5. Results of PBT and vPvB assessment This product does not contain any PBT or vPvB substances. Ecological information on ingredients. 1-BROMOPROPANE (CAS: 106-94-5) This product does not contain any PBT or vPvB substances. TETRACHLOROETHYLENE (CAS: 127-18-4) Not Classified as PBT/vPvB by current EU criteria. 12.6. Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS General information When handling waste, consideration should be made to the safety precautions applying to handling of the product. Do not puncture or incinerate even when empty. 13.1. Waste treatment methods Recover and reclaim or recycle, if practical. Do not allow runoff to sewer, waterway or ground. Dispose of waste and residues in accordance with local authority requirements. SECTION 14: TRANSPORT INFORMATION 14.1. UN number UN No. (ADR/RID/ADN) 1950 UN No. (IMDG) 1950 UN No. (ICAO) 1950 14.2. UN proper shipping name Proper Shipping Name AEROSOLS (TETRACHLOROETHYLENE) 14.3. Transport hazard class(es) ADR/RID/ADN Class 2 ADR/RID/ADN Class Class 2: Gases ADR Label No. 2.2 & 6.1 1210 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN IMDG Class 2.2 ICAO Class/Division 2.2 ICAO Subsidiary risk 6.1 Transport Labels NON-FLAMMABLE NON-TOXIC GAS 2 6 TOXIC 14.4. Packing group ADR/RID/ADN Packing group N/A IMDG Packing group N/A ICAO Packing group N/A 14.5. Environmental hazards Environmentally Hazardous Substance/Marine Pollutant 14.6. Special precautions for user EMS F-D, S-U 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code No information required. Not relevant SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Statutory Instruments The Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 (S.I 2009 No. 716). Approved Code Of Practice Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 with amendments. 15.2. Chemical Safety Assessment No chemical safety assessment has been carried out. SECTION 16: OTHER INFORMATION Revision Date June 2012 1211 / SDS No. 10018 CYCLO? BRAKE & PARTS CLEAN Revision 2 Supersedes date May 2009 Date June 2012 Risk Phrases In Full Harmful: danger of serious damage to health by prolonged exposure through inhalation.R48/20 Highly flammableR11 Irritating to eyes, respiratory system and skin.R36/37/38 Limited evidence of a carcinogenic effect.R40 May impair fertility.R60 Not classified.NC Possible risk of harm to the unborn child.R63 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.R51/53 Vapours may cause drowsiness and dizziness.R67 Hazard Statements In Full Causes serious eye irritation.H319 Causes skin irritation.H315 Highly flammable liquid and vapour.H225 May cause damage to organs <> through prolonged or repeated exposure.H373 May cause drowsiness or dizziness.H336 May cause respiratory irritation.H335 May damage fertility and suspected of damaging the unborn child.H360Fd May damage fertility or the unborn child.H360FD Suspected of causing cancer.H351 Toxic to aquatic life with long lasting effects.H411 Disclaimer Cyclo Industries Inc provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Cyclo Industries Inc. makes no representations or warranties either expressed or implied, of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, Cyclo Industries Inc. will not be reponsible for damages resulting from use of or reliance upon this information. 1212 /