05/12/2014Revision: Page: 1 Fuel Stabilizer SAFETY DATA SHEET 08/15/2013Supersedes Revision: according to Regulation (EC) No. 1907/2006 as amended by (EC) No. 1272/2008 C290, C2921.1 Product Code: Fuel Stabilizer Product Name: CYCLO INDUSTRIES, INC.Company Name: 902 SOUTH US HIGHWAY 1 JUPITER, FL 33477 First Aid EmergencyEmergency Contact: (800)752-7869 CHEMTREC (703) 527-3887 (800)424-9300 First Aid Emergency (Outside U.S.)Information: (312)906-6194 (800)843-7813 Phone Number: www.cyclo.comWeb site address: Section 1. Identification of the Substance/Mixture and of the Company/Undertaking 1.3 Details of the Supplier of the Safety Data Sheet: 1.2 Relevant identified uses of the substance or mixture and uses advised against: 1.4 Emergency telephone number: Section 2. Hazards Identification Acute Toxicity: Inhalation, Category 4 Acute Toxicity: Oral, Category 4 Acute Toxicity: Skin, Category 4 Skin Corrosion/Irritation, Category 2 Serious Eye Damage/Eye Irritation, Category 2A Skin Sensitization, Category 1 Carcinogenicity, Category 2 Aquatic Toxicity (Acute), Category 1 Aquatic Toxicity (Chronic), Category 1 Flammable Liquids, Category 4 2.1 Classification of the Substance or Mixture: 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP]: 2.1.2 Classification according to Directive 1999/45/EC: P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. GHS Precaution Phrases: H332: Harmful if inhaled. H302: Harmful if swallowed. H312: Harmful in contact with skin. H315: Causes skin irritation. H319: Causes serious eye irritation. H317: May cause an allergic skin reaction. H335: May cause respiratory irritation. H351: Suspected of causing cancer. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects. GHS Hazard Phrases: 2.2 Label Elements: 2.2.1 Labeling according to Regulation (EC) No 1272/2008 [CLP]: WarningGHS Signal Word: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 05/12/2014Revision: Page: 2 Fuel Stabilizer SAFETY DATA SHEET 08/15/2013Supersedes Revision: P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P280: Wear protective gloves/protective clothing/eye protection/face protection. P362+364: Take off contaminated clothing and wash it before reuse. P272: Contaminated work clothing should not be allowed out of the workplace. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P281: Use personal protective equipment as required. P273: Avoid release to the environment. P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P363: Wash contaminated clothing before reuse. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309+311: Call a POISON CENTER or doctor/physician if exposed or you feel unwell. GHS Response Phrases: P501: Dispose of contents/container in accordance with local/regional/national/international regulation. P405: Store locked up. GHS Storage and Disposal Phrases: 2.2.2 Labeling according to Directive 1999/45/EC: 2.3 Ingestion: Nausea, vomiting, diarrhea. Inhalation: Shortness of breath, dizziness, fainting. Skin: Redness or burning sensation. Eyes: Irritation and tearing. Adverse Human Health Effects and Symptoms: Hazard Rating System: Instability Special Hazard Health Flammability 1 2 0 CAS # Hazardous Components (Chemical Name)/ REACH Registration No. Section 3. Composition/Information on Ingredients Concentration EC No./ EC Index No. Risk Phrases/ GHS Classification 68476-30-2 Fuel oil, no. 2 78.0 -98.0 % 270-671-4 649-225-00-1 Xn; R40 Carcinogen 2: H351 1330-20-7 Xylene (mixed isomers) < 1.0 % 215-535-7 601-022-00-9 Xn; R10-20/21-38 Flam. Liq. 3: H226 Acute Tox.(D) 4: H312 Skin Corr. 2: H315 Acute Tox.(I) 4: H332 128-39-2 Butyl phenol, (2,6-Di-t-) < 1.0 % 204-884-0 NA N;Xi; R43-51/53-36/37/38 Skin Corr. 2: H315 Aquatic (A) 1: H400 Aquatic (C) 1: H410 94-91-7 Phenol,2,2'-(1-methyl-1,2-ethanediyl)bis(nitrilomethyl idyne)bis- < 1.0 % 202-374-2 NA No phrases apply. Flam. Liq. 3: H226 Acute Tox.(O) 4: H302 Skin Sens. 1: H317 Skin Corr. 2: H315 Eye Damage 2A: H319 MIRS MSDS, (c) A V Systems, Inc. Multi-region format 05/12/2014Revision: Page: 3 Fuel Stabilizer SAFETY DATA SHEET 08/15/2013Supersedes Revision: Aquatic (C) 3: H412 100-41-4 Ethylbenzene < 0.2 % 202-849-4 601-023-00-4 F; Xn; R11-20 Flam. Liq. 2: H225 Acute Tox.(I) 4: H332 732-26-3 2,4,6-Tri-tert-butylphenol < 0.018 % 211-989-5 NA Xn;N; R22-43-50/53-36/37/38 Eye Damage 2A: H319 Aquatic (A) 1: H400 Aquatic (C) 1: H410 Section 4. First Aid Measures If swallowed, do not induce vomiting. If affected person is fully conscious, give one glass of water to drink. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of skin contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If in eyes, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call physician immediately if adverse reaction occurs. Description of First Aid Measures: 4.1 Aspiration hazard if swallowed. Delayed symptoms of chemical pneumonitis may occur after moderate physical exertion. Observe for a minimum of 48 hours. Note for the Doctor: 5.1 5.2 Section 5. Fire Fighting Measures Flash Pt: 66.00 C (150.8 F) Method Used: Pensky-Marten Closed Cup As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Fire Fighting Instructions: Autoignition Pt: ~ 257.00 C (494.6 F) Explosive Limits: LEL: 0.6 UEL: 4.7 Use water spray (fog), foam, dry chemicals, or carbon dioxide.Suitable Extinguishing Media: Combustible liquid and vapor. Vapor may cause flash fire. Vapors may accumulate in low or confined areas, travel considerable distance to source of ignition, and flash back. Runoff to sewer may cause fire or explosion hazard. Flammable Properties and Hazards: 5.3 6.3 Section 6. Accidental Release Measures Personal protection: Immediately contact emergency personnel. Eliminate all ignition sources. Keep unnecessary personnel away. Do not touch or walk through spilled material. Environmental Precautions and Clean-Up Methods: Contain spilled material. For small spills, add adsorbent (soil, sand, oil-dri) and use a non-sparking shovel or other means to transfer material to a sealed, appropriate, and labeled, container for disposal. For large spills, dike spilled material to ensure runoff does not reach a sewer, drain, or waterway. Place spilled material in an in an appropriate and labeled container for disposal. Minimize contact of spilled material with soils to prevent runoff to surface waters. Methods and Material For Containment and Cleaning Up: 7.1 Section 7. Handling and Storage Keep away from heat, sparks, and flame. Avoid contact with eyes, skin, and clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wash thoroughly after handling. To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Use explosion proof electrical equipment, including ventilation, lighting, and handling equipment. Keep out of the reach of children. Precautions To Be Taken in Handling: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 05/12/2014Revision: Page: 4 Fuel Stabilizer SAFETY DATA SHEET 08/15/2013Supersedes Revision: 7.2 Store in a segregated and approved area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Keep container in a well ventilated place. Store locked up. Precautions To Be Taken in Storing: Section 8. Exposure Controls/Personal Protection Britain EH40 France VLCAS # Partial Chemical Name Europe 8.1 Exposure Parameters: No data. No data. 68476-30-2 Fuel oil, no. 2 No data. TWA: 220 mg/m3 (50 ppm) STEL: 441 mg/m3 (100 ppm) TWA: 221 mg/m3 (50 ppm) STEL: 442 mg/m3 (100 ppm) 1330-20-7 Xylene (mixed isomers) TWA: 221 mg/m3 STEL: 442 mg/m3 No data. No data. 128-39-2 Butyl phenol, (2,6-Di-t-) No data. No data. No data. 94-91-7 Phenol,2,2'-(1-methyl-1,2-ethanediyl)bi s(nitrilomethylidyne)bis- No data. TWA: 441 mg/m3 (100 ppm) STEL: 552 mg/m3 (125 ppm) TWA: 88.4 mg/m3 (20 ppm) STEL: 442 mg/m3 (100 ppm) 100-41-4 Ethylbenzene TWA: 442 mg/m3 STEL: 884 mg/m3 No data. No data. 732-26-3 2,4,6-Tri-tert-butylphenol No data. OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits No data. TLV: 100 mg/m3 68476-30-2 Fuel oil, no. 2 No data. PEL: 100 ppm TLV: 100 ppm STEL: 150 ppm 1330-20-7 Xylene (mixed isomers) No data. No data. No data. 128-39-2 Butyl phenol, (2,6-Di-t-) No data. No data. No data. 94-91-7 Phenol,2,2'-(1-methyl-1,2-ethanediyl)bi s(nitrilomethylidyne)bis- No data. PEL: 100 ppm TLV: 100 ppm STEL: 125 ppm 100-41-4 Ethylbenzene No data. No data. No data. 732-26-3 2,4,6-Tri-tert-butylphenol No data. 8.2.1 Workers with high potential exposure must wear organic vapor respirators.Respiratory Equipment (Specify Type): Safety goggles are minimum protection. Goggles with a face shield are required for persons working closely with a potential for splashing. Eye Protection: Use chemical resistant, impervious gloves.Protective Gloves: Where contact is likely, wear chemical resistant gloves, a chemical resistant suit and boots. Additional body garments should be based upon the task being performed. Other Protective Clothing: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Engineering Controls (Ventilation etc.): 8.2 Exposure Controls: 8.2.2 Personal protection equipment: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 05/12/2014Revision: Page: 5 Fuel Stabilizer SAFETY DATA SHEET 08/15/2013Supersedes Revision: Section 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: No data. Flash Pt: 66.00 C (150.8 F) Method Used: Pensky-Marten Closed Cup Explosive Limits: LEL: 0.6 UEL: 4.7 Vapor Pressure (vs. Air or mm Hg): < 2 MM_HG at 20.0 C (68.0 F) Vapor Density (vs. Air = 1): No data. Evaporation Rate: No data. Light red liquid with a slight petroleum odor.Appearance and Odor: 9.1 Information on Basic Physical and Chemical Properties Specific Gravity (Water = 1): ~ 0.851 at 75.0 F (23.9 C) Density: 6.9875 LB/GA Solubility in Water: No data. Autoignition Pt: ~ 257.00 C (494.6 F) Viscosity: water thin at 25.0 C (77.0 F) Percent Volatile: 10.0 % by weight. 9.2 Other Information 10.4 10.5 10.6 10.1 10.2 10.3 Section 10. Stability and Reactivity High temperatures, sparks and open flames.Conditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Strong oxidizing and reducing agents.Incompatibility - Materials To Avoid: Carbon monoxide and carbon dioxides.Hazardous Decomposition Or Byproducts: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: No data available.Conditions To Avoid - Hazardous Reactions: No data available.Reactivity: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 05/12/2014Revision: Page: 6 Fuel Stabilizer SAFETY DATA SHEET 08/15/2013Supersedes Revision: 11.1 Section 11. Toxicological Information No data available.Information on Toxicological Effects: Chronic Toxicological Effects: CAS# 68476-30-2: Other Studies:, TDLo, Skin, Species: Rabbit, 100.0 ML/KG, 12 D. Results: Skin and Appendages: Skin: After systemic exposure: Dermatitis, irritative. Nutritional and Gross Metabolic:Weight loss or decreased weight gain. Related to Chronic Data - death. - "Toxicology of Petroleum Hydrocarbons, Proceedings of the Symposium, 1st, 1982," MacFarland, H.N., et al., eds., Washington, DC, American Petroleum Institute, 1983 Volume, Vol/p/yr: 1,1, 1983 Acute toxicity, LD50, Oral, Rat, 12.00 GM/KG. Results: Behavioral: Somnolence (general depressed activity). - Advances in Modern Environmental Toxicology., Senate Press, Inc., P.O. Box 252, Princeton Junction, NJ 08550, Vol/p/yr: 6,1, 1984 Acute toxicity, LD (Lethal dose), Skin, Species: Rabbit, 5.000 GM/KG. Results: Behavioral: Tremor. Behavioral: Convulsions or effect on seizure threshold. - Advances in Modern Environmental Toxicology., Senate Press, Inc., P.O. Box 252, Princeton Junction, NJ 08550, Vol/p/yr: 6,1, 1984 Tumorigenic Effects:, TDLo, Skin, Mouse, 243.0 GM/KG, 97 W. Results: Tumorigenic: Carcinogenic by RTECS criteria. Skin and Appendages: Other: Tumors. - Fundamental and Applied Toxicology., Academic Press, Inc., 1 E. First St., Duluth, MN 55802, Vol/p/yr: 9,297, 1987 Standard Draize Test, Skin, Species: Rabbit, 500.0 MG, 24 H, Moderate. Results: Brain and Coverings: Changes in surface EEG. - "Toxicology of Petroleum Hydrocarbons, Proceedings of the Symposium, 1st, 1982," MacFarland, H.N., et al., eds., Washington, DC, American Petroleum Institute, 1983 Volume, Vol/p/yr: 1,1, 1983 Standard Draize Test, Eyes, Species: Rabbit, 100.0 MG, 30 S, Mild. Results: Behavioral: Somnolence (general depressed activity). - "Toxicology of Petroleum Hydrocarbons, Proceedings of the Symposium, 1st, 1982," MacFarland, H.N., et al., eds., Washington, DC, American Petroleum Institute, 1983 Volume, Vol/p/yr: 1,1, 1983 MIRS MSDS, (c) A V Systems, Inc. Multi-region format 05/12/2014Revision: Page: 7 Fuel Stabilizer SAFETY DATA SHEET 08/15/2013Supersedes Revision: CAS # Hazardous Components (Chemical Name) NTP IARC ACGIH OSHA 68476-30-2 Fuel oil, no. 2 n.a. 2B A3 n.a. 1330-20-7 Xylene (mixed isomers) n.a. 3 A4 n.a. 128-39-2 Butyl phenol, (2,6-Di-t-) n.a. n.a. n.a. n.a. 94-91-7 Phenol,2,2'-(1-methyl-1,2-ethanediyl)bis(nitrilomethylidyne) bis- n.a. n.a. n.a. n.a. 100-41-4 Ethylbenzene n.a. 2B A3 n.a. 732-26-3 2,4,6-Tri-tert-butylphenol n.a. n.a. n.a. n.a. Section 12. Ecological Information 13.1 Disposal should be made in accordance with federal, state and local regulations.Waste Disposal Method: Section 13. Disposal Considerations Section 14. Transport Information Not-RestrictedDOT Proper Shipping Name: DOT Hazard Class: UN/NA Number: 14.1 LAND TRANSPORT (US DOT): Not-RestrictedADR/RID Shipping Name: 14.1 LAND TRANSPORT (European ADR/RID): UN Number: Hazard Class: Not-RestrictedIMDG/IMO Shipping Name: 14.2 MARINE TRANSPORT (IMDG/IMO): UN Number: Packing Group: Hazard Class: NoMarine Pollutant: CAS # Hazardous Components (Chemical Name) Section 15. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 68476-30-2 Fuel oil, no. 2 No No No 1330-20-7 Xylene (mixed isomers) No Yes 100 LB Yes 128-39-2 Butyl phenol, (2,6-Di-t-) No No No 94-91-7 Phenol,2,2'-(1-methyl-1,2-ethanediyl)bis(nitrilome thylidyne)bis- No No No 100-41-4 Ethylbenzene No Yes 1000 LB Yes 732-26-3 2,4,6-Tri-tert-butylphenol No No No CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 68476-30-2 Fuel oil, no. 2 CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No MIRS MSDS, (c) A V Systems, Inc. Multi-region format 05/12/2014Revision: Page: 8 Fuel Stabilizer SAFETY DATA SHEET 08/15/2013Supersedes Revision: 1330-20-7 Xylene (mixed isomers) CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: TAC, Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: CMR, Part 5; NC TAP: Yes; NJ EHS: Yes - 2014; NY Part 597: Yes; PA HSL: Yes - E; SC TAP: Yes; WI Air: Yes 128-39-2 Butyl phenol, (2,6-Di-t-) CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory, 4 Test, 8D TERM; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 94-91-7 Phenol,2,2'-(1-methyl-1,2-ethanediyl)bis(nitrilome thylidyne)bis- CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 100-41-4 Ethylbenzene CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Inventory, 4 Test; CA PROP.65: Yes; CA TAC, Title 8: TAC, Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: Part 5; NC TAP: Yes; NJ EHS: Yes - 0851; NY Part 597: Yes; PA HSL: Yes - E; SC TAP: Yes; WI Air: Yes 732-26-3 2,4,6-Tri-tert-butylphenol CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory, 4 Test, 12(b); CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No CAS # Hazardous Components (Chemical Name) International Regulatory Lists 68476-30-2 Fuel oil, no. 2 Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 1330-20-7 Xylene (mixed isomers) Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 128-39-2 Butyl phenol, (2,6-Di-t-) Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 94-91-7 Phenol,2,2'-(1-methyl-1,2-ethanediyl)bis(nitrilome thylidyne)bis- Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 100-41-4 Ethylbenzene Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes - 116-01 732-26-3 2,4,6-Tri-tert-butylphenol Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes European Community Risk and Safety Phrases: European Community Hazard Symbol codes: No data available. Section 16. Other Information EPA Fuel Additive Registration No. 0053Additional Information About This Product: Cyclo Industries, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Cyclo Industries, Inc. makes no representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, Cyclo Industries, Inc. will not be responsible for damages resulting Company Policy or Disclaimer: 05/12/2014Revision Date: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 05/12/2014Revision: Page: 9 Fuel Stabilizer SAFETY DATA SHEET 08/15/2013Supersedes Revision: from use of or reliance upon this information. MIRS MSDS, (c) A V Systems, Inc. Multi-region format