04/05/2016Revision: Page: 1 Engine Clean Degreaser SAFETY DATA SHEET 02/03/2016Supersedes Revision: C30Product Code: Engine Clean DegreaserProduct Name: CYCLO INDUSTRIES, INC.Company Name: 902 SOUTH US HIGHWAY 1 JUPITER, FL 33477 First Aid EmergencyEmergency Contact: (800)752-7869 CHEMTREC (703) 527-3887 (800)424-9300 First Aid Emergency (Outside U.S.)Information: (312)906-6194 (800)843-7813 Phone Number: www.cyclo.comWeb site address: 1. Product and Company Identification This email address is being protected from spambots. You need JavaScript enabled to view it. address: 2. Hazards Identification P210: Keep away from heat/sparks/open flames/hot surfaces - No smoking. P251: Pressurized container: Do not pierce or burn, even after use. P261: Avoid breathing dust/fume/gas/mist/vapors/spray. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P272: Contaminated work clothing should not be allowed out of the workplace. P273: Avoid release to the environment. P280: Wear protective gloves/protective clothing/eye protection/face protection. GHS Precaution Phrases: P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P363: Wash contaminated clothing before reuse. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309+311: Call a POISON CENTER or doctor/physician if exposed or you feel unwell. GHS Response Phrases: P405: Store locked up. P410+412: Protect from sunlight and do not expose to temperatures exceeding 50 ?C/122 ?F. GHS Storage and Disposal Phrases: H229: Pressurized container: may burst if heated. H302: Harmful if swallowed. H304: May be fatal if swallowed and enters airways. H317: May cause an allergic skin reaction. H318: Causes serious eye damage. H400: Very toxic to aquatic life. H410: Very toxic to aquatic life with long lasting effects. GHS Hazard Phrases: Acute Toxicity: Oral, Category 4 Serious Eye Damage/Eye Irritation, Category 1 Skin Sensitization, Category 1 Aspiration Toxicity, Category 1 Flammable Aerosols, Category 3 DangerGHS Signal Word: MIRS MSDS, (c) A V Systems, Inc. GHS format 04/05/2016Revision: Page: 2 Engine Clean Degreaser SAFETY DATA SHEET 02/03/2016Supersedes Revision: P501: Dispose of contents/container in accordance with local/regional/national/international regulation. Potential Health Effects (Acute and Chronic): Liquid or vapor can cause moderate to severe irritation.Eye Contact: Contact may dry the skin; prolonged contact may cause moderate irritation.Skin Contact: Respiratory irritation, headache, nausea, fatigue, drowsiness, impaired coordination.Inhalation: CAS # Hazardous Components (Chemical Name) 3. Composition/Information on Ingredients Concentration 64742-47-8 Hydrotreated light distillate (petroleum) 85.0 -95.0 % 68439-46-3 Alcohol ethoxylate 3.0 -5.0 % 124-38-9 Carbon dioxide 1.0 -3.0 % 5989-27-5 (R)-1-Methyl-4-(1-methylethenyl)-cyclohexene 2.0 -5.0 % 4. First Aid Measures If swallowed, do not induce vomiting. If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult give oxygen. If in eyes, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. In case of skin contact, remove contaminated clothing and shoes and launder before reuse. Wash with soap and water for 15 minutes. Call physician immediately if adverse reaction occurs. Emergency and First Aid Procedures: 5. Fire Fighting Measures Flash Pt: >= 70.00 C (158.0 F) Method Used: Pensky-Marten Closed Cup Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Closed containers may explode from internal pressure build up when exposed to extreme heat & discharge contents. Vapor accumulation can flash or explode if ignited. Overexposure to decomposition products may cause a health hazard. Symptoms may not be readily apparent. Fire Fighting Instructions: Water may be used to cool containers to prevent pressure build up & explosion when exposed to extreme heat. If water is used, fog nozzles preferred. Flammable Properties and Hazards: Autoignition Pt: No data. Explosive Limits: LEL: No data. UEL: No data. Flammability Classification: NFPA Level 2 Aerosol Foam, CO2, dry chemical, water fog.Suitable Extinguishing Media: No data available.Hazardous Combustion Products: 6. Accidental Release Measures Avoid breathing vapors. Ventilate area. Remove all sources of ignition. Clean up area with absorbent material & place in closed containers for disposal. Steps To Be Taken In Case Material Is Released Or Spilled: 7. Handling and Storage Keep away from heat/sparks/open flames/hot surfaces - No smoking. Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/fume/gas/mist/vapors/spray. Wash hands thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Avoid release to Precautions To Be Taken in Handling: MIRS MSDS, (c) A V Systems, Inc. GHS format 04/05/2016Revision: Page: 3 Engine Clean Degreaser SAFETY DATA SHEET 02/03/2016Supersedes Revision: the environment. Wear protective gloves/protective clothing/eye protection/face protection. Keep out of the reach of children. Protect from sunlight and do not expose to temperatures exceeding 50 ?C/122 ?F. Store locked up. Precautions To Be Taken in Storing: 8. Exposure Controls/Personal Protection OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits No data.No data. TLV: 200 mg/m3 64742-47-8 Hydrotreated light distillate (petroleum) No data.No data. No data. 68439-46-3 Alcohol ethoxylate No data.PEL: 5000 ppm TLV: 5000 ppm STEL: 30,000 ppm 124-38-9 Carbon dioxide No data.No data. No data. 5989-27-5 (R)-1-Methyl-4-(1-methylethenyl)-cyclo hexene Avoid breathing vapors. Use with adequate ventilation equal to out of doors. In restricted areas, use approved chemical/mechanical filters designed to remove a combination of particles & vapor. In confined areas, use approved air line type respirator or hood. Self-contained breathing apparatus is required for vapor concentrations above PEL/TLV limits. Respiratory Equipment (Specify Type): Chemical goggles; also wear a face shield if splashing hazard exists.Eye Protection: Solvent resistant gloves required for prolonged or repeated contact.Protective Gloves: Use of solvent resistant aprons or other clothing is recommended.Other Protective Clothing: Sufficient to prevent inhalation of solvent vapors. General dilution and/or local exhaust ventilation in volume or pattern to keep PEL/TLV of most hazardous ingredient below acceptable limit & LEL below stated limit. Engineering Controls (Ventilation etc.): Use in a well ventilated area. To prevent vapor build up, open doors & windows or use an explosion-proof exhaust fan to ensure fresh air exchange during & after use. Do not breathe vapor, gas or spray mist. Work/Hygienic/Maintenance Practices: 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: 310.00 F (154.4 C) - 410.00 F (210.0 C) Flash Pt: >= 70.00 C (158.0 F) Method Used: Pensky-Marten Closed Cup Explosive Limits: LEL: No data. UEL: No data. Vapor Pressure (vs. Air or mm Hg): No data. Vapor Density (vs. Air = 1): No data. Evaporation Rate: No data. pH: No data. Clear, colorless to slightly discolored solution with aromatic odor.Appearance and Odor: Flammability (solid, gas): No data available. Specific Gravity (Water = 1): .81 Solubility in Water: NIL MIRS MSDS, (c) A V Systems, Inc. GHS format 04/05/2016Revision: Page: 4 Engine Clean Degreaser SAFETY DATA SHEET 02/03/2016Supersedes Revision: Decomposition Temperature: No data. Autoignition Pt: No data. Percent Volatile: 3.0 % by weight. Viscosity: No data. Octanol/Water Partition Coefficient: No data. 10. Stability and Reactivity Application to hot surfaces. Storage above 120F. Exposure to open flame.Conditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Contact with oxidizing agents.Incompatibility - Materials To Avoid: May produce fumes when heated to decomposition. Fumes may contain carbon monoxide & other toxic fumes. Hazardous Decomposition or Byproducts: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: No data available.Conditions To Avoid - Hazardous Reactions: CAS # Hazardous Components (Chemical Name) NTP 11. Toxicological Information No data available.Toxicological Information: IARC ACGIH OSHA 64742-47-8 Hydrotreated light distillate (petroleum) n.a. n.a. A4 n.a. 68439-46-3 Alcohol ethoxylate n.a. n.a. n.a. n.a. 124-38-9 Carbon dioxide n.a. n.a. n.a. n.a. 5989-27-5 (R)-1-Methyl-4-(1-methylethenyl)-cyclohexene n.a. 3 n.a. n.a. No data available. 12. Ecological Information Dispose of contents/container in accordance with local/regional/national/international regulation. Waste Disposal Method: 13. Disposal Considerations 14. Transport Information Consumer CommodityDOT Proper Shipping Name: ORM-D ORM-DDOT Hazard Class: UN/NA Number: LAND TRANSPORT (US DOT): Aerosols, Ltd. Qty.ADR/RID Shipping Name: LAND TRANSPORT (European ADR/RID): 1950UN Number: N.A.Hazard Class: 2.1ADR Classification: Aerosols, Ltd. Qty.IMDG/IMO Shipping Name: MARINE TRANSPORT (IMDG/IMO): 1950UN Number: Packing Group: N.A.Hazard Class: 2.2IMDG Classification: IMDG MFAG Number: IMDG EMS Page: NoMarine Pollutant: MIRS MSDS, (c) A V Systems, Inc. GHS format 04/05/2016Revision: Page: 5 Engine Clean Degreaser SAFETY DATA SHEET 02/03/2016Supersedes Revision: Aerosols, non-flammable, 2.2, Ltd. Qty.ICAO/IATA Shipping Name: AIR TRANSPORT (ICAO/IATA): 1950UN Number: N.A.Hazard Class: 2.2IATA Classification: CAS # Hazardous Components (Chemical Name) 15. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 64742-47-8 Hydrotreated light distillate (petroleum) No No No 68439-46-3 Alcohol ethoxylate No No No 124-38-9 Carbon dioxide No No No 5989-27-5 (R)-1-Methyl-4-(1-methylethenyl)-cyclohexene No No No CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 64742-47-8 Hydrotreated light distillate (petroleum) CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 68439-46-3 Alcohol ethoxylate CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 124-38-9 Carbon dioxide CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: Yes - 1; SC TAP: No; WI Air: Yes 5989-27-5 (R)-1-Methyl-4-(1-methylethenyl)-cyclohexene CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No CAS # Hazardous Components (Chemical Name) International Regulatory Lists 64742-47-8 Hydrotreated light distillate (petroleum) Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 68439-46-3 Alcohol ethoxylate Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 124-38-9 Carbon dioxide Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 5989-27-5 (R)-1-Methyl-4-(1-methylethenyl)-cyclohexene Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes MIRS MSDS, (c) A V Systems, Inc. GHS format 04/05/2016Revision: Page: 6 Engine Clean Degreaser SAFETY DATA SHEET 02/03/2016Supersedes Revision: 16. Other Information No data available.Additional Information About This Product: Hazard Rating System: Instability Special Hazard Health Flammability Cyclo Industries, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Cyclo Industries, Inc. makes no representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, Cyclo Industries, Inc. will not be responsible for damages resulting from use of or reliance upon this information. Company Policy or Disclaimer: 2 2 0 04/05/2016Revision Date: NFPA: MIRS MSDS, (c) A V Systems, Inc. GHS format