04/26/2013Revision: 04/26/2013Printed: Page: 1 Disc Brake Quiet SAFETY DATA SHEET 01/30/2012Supercedes Revision: according to Regulation (EC) No. 1907/2006 as amended by (EC) No. 1272/2008 C361.1 Product Code: Disc Brake Quiet Product Name: CYCLO INDUSTRIES, INC.Company Name: 902 SOUTH US HIGHWAY 1 JUPITER, FL 33477 First Aid EmergencyEmergency Contact: (800)752-7869 CHEMTREC (703) 527-3887 (800)424-9300 First Aid Emergency (Outside U.S.)Information: (312)906-6194 (800)843-7813 Phone Number: www.cyclo.comWeb site address: Section 1. Identification of the Substance/Mixture and of the Company/Undertaking 1.3 Details of the Supplier of the Safety Data Sheet: 1.2 Relevant identified uses of the substance or mixture and uses advised against: 1.4 Emergency telephone number: Section 2. Hazards Identification Flammable Gases, Category 1 Gas Under Pressure, Compressed gas Flammable Liquids, Category 2 Skin Corrosion/Irritation, Category 2 Toxic To Reproduction, Category 2 Target Organ Systemic Toxicity (single exposure), Category 3 Target Organ Systemic Toxicity (repeated exposure), Category 2 Aspiration Toxicity, Category 1 2.1 Classification of the Substance or Mixture: 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP]: P210: Keep away from heat/sparks/open flames/hot surfaces. P280: Wear protective gloves/clothing and eye/face protection as specified by the manufacturer/supplier or the competent authority. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. GHS Precaution Phrases: H220: Extremely flammable gas. H280: Contains gas under pressure; may explode if heated. H225: Highly flammable liquid and vapor. H315: Causes skin irritation. H361: Suspected of damaging fertility or the unborn child. H335: May cause respiratory irritation. H373: May cause damage to organs through prolonged or repeated exposure. H304: May be fatal if swallowed and enters airways. GHS Hazard Phrases: Danger Warning Warning Danger 2.2 Label Elements: 2.2.1 Labeling according to Regulation (EC) No 1272/2008 [CLP]: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 04/26/2013Revision: 04/26/2013Printed: Page: 2 Disc Brake Quiet SAFETY DATA SHEET 01/30/2012Supercedes Revision: P260: Do not breathe dust/fume/gas/mist/vapours/spray. P273: Avoid release to the environment. P370+378: In case of fire, use CO2, dry chemical or foam for extinction. P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P302+352: IF ON SKIN: Wash with plenty of soap and water. P309+311: Call a POISON CENTER or doctor/physician if exposed or you feel unwell. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331: Do NOT induce vomiting. GHS Response Phrases: P410: Protect from sunlight. P501: Dispose of contents/container in accordance with local/regional/national/international regulation. P403+233: Store container tightly closed in well-ventilated place. GHS Storage and Disposal Phrases: 2.3 Adverse Human Health Effects and Symptoms: Hazard Rating System: Instability Special Hazard Health Flammability HEALTH FLAMMABILITY PPE PHYSICAL 2 2 4 2 4 0 CAS # Hazardous Components (Chemical Name)/ REACH Registration No. Section 3. Composition/Information on Ingredients Concentration EC No./ EC Index No. GHS Classification 142-82-5 Heptane 40.0 -50.0 % 205-563-8 601-008-00-2 Flam. Liq. 2: H225 Asp. Toxic. 1: H304 Skin Corr. 2: H315 TOST (SE) 3: H335 H336 Aquatic (A) 1: H400 Aquatic (C) 1: H410 74-98-6 Propane 10.0 -20.0 % 200-827-9 601-003-00-5 Flam. Gas 1: H220 Comp. Gas: H280 108-88-3 Toluene 10.0 -15.0 % 203-625-9 601-021-00-3 Flam. Liq. 2: H225 Toxic Repro. 2: H361 Asp. Toxic. 1: H304 TOST (RE) 2: H373 Skin Corr. 2: H315 TOST (SE) 3: H335 H336 106-97-8 Butane 1.0 -10.0 % 203-448-7 601-004-01-8 Flam. Gas 1: H220 Comp. Gas: H280 MIRS MSDS, (c) A V Systems, Inc. Multi-region format 04/26/2013Revision: 04/26/2013Printed: Page: 3 Disc Brake Quiet SAFETY DATA SHEET 01/30/2012Supercedes Revision: Section 4. First Aid Measures If swallowed, seek medical attention immediately. Aspiration hazard: do not induce vomiting or give anything by mouth because this material can enter the lungs and cause severe lung damage. Do not leave individual unattended. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of eye contact, immediately flush eyes with large amounts of water for at least 15 minutes while holding eyelids open. In case of skin contact, wash with soap and water. Remove contaminated clothing and shoes, and launder before reuse. Call physician immediately if adverse reaction occurs. Description of First Aid Measures: 4.1 5.1 5.2 Section 5. Fire Fighting Measures Flash Pt: < 0.00 F (-17.8 C) Method Used: TAG Closed Cup EXTREMELY FLAMMABLE. Contents under pressure. Cool exposed containers with water spray to prevent bursting. SCBA should be used whenever chemical fires are present. Fire Fighting Instructions: Autoignition Pt: No data. Explosive Limits: LEL: No data. UEL: No data. Flammability Classification: NFPA Level 2 Aerosol Carbon dioxide, dry chemicals, foam.Suitable Extinguishing Media: No data available.Flammable Properties and Hazards: 5.3 6.3 Section 6. Accidental Release Measures Wear appropriate protective clothing and equipment to prevent skin and eye contact. Contain any liquid from leaking containers. Remove sources of ignition. Increase area ventilation. Do not puncture or incinerate container. Contents under pressure. Clean up using dry procedures; avoid dusting. Sweep or gather up material and place in proper container for disposal or recovery. Do not allow to enter sanitary drains, sewer or surface and subsurface waters. Methods and Material For Containment and Cleaning Up: 7.1 7.2 Section 7. Handling and Storage Danger: extremely flammable. Caution: contents under pressure. Keep away from heat and open flame. Do not puncture or incinerate. Use only in a well ventilated area. Keep out of the reach of children. Precautions To Be Taken in Handling: Do not store above 120 degrees F. Do not store in passenger compartment of automobile. Precautions To Be Taken in Storing: Section 8. Exposure Controls/Personal Protection Britain EH40 France VLCAS # Partial Chemical Name Europe 8.1 Exposure Parameters: TWA: 2085 mg/m3 (500 ppm) STEL: () TWA: 1668 mg/m3 (400 ppm) STEL: 2085 mg/m3 (500 ppm) 142-82-5 Heptane TWA: 2085. mg/m3 No data. No data. 74-98-6 Propane No data. TWA: 191 mg/m3 (50 ppm) STEL: 384 mg/m3 (100 ppm) TWA: 192 mg/m3 (50 ppm) STEL: 384 mg/m3 (100 ppm) 108-88-3 Toluene TWA: 192 mg/m3 STEL: 384 mg/m3 TWA: 1450 mg/m3 (600 ppm) TWA: 1900 mg/m3 (800 106-97-8 Butane No data. MIRS MSDS, (c) A V Systems, Inc. Multi-region format 04/26/2013Revision: 04/26/2013Printed: Page: 4 Disc Brake Quiet SAFETY DATA SHEET 01/30/2012Supercedes Revision: STEL: 1810 mg/m3 (750 ppm) ppm) OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits PEL: 500 ppm TLV: 400 ppm 142-82-5 Heptane No data. PEL: 1000 ppm TLV: (2500 ppm) 74-98-6 Propane No data. PEL: 200 ppm STEL: 500 ppm/(10min) CEIL: 300 ppm TLV: 50 ppm 108-88-3 Toluene No data. No data. TLV: (800 ppm) 106-97-8 Butane No data. 8.2.1 Use an approved NIOSH organic vapor respirator below the TLV. If TLV is exceeded or overexposure is likely, use positive pressure or self-contained breathing apparatus. Respiratory Equipment (Specify Type): Wear safety glasses or goggles to protect against exposure.Eye Protection: Use chemical resistant gloves for prolonged skin contact.Protective Gloves: Rubber apron.Other Protective Clothing: Exhaust ventilation. Showers. Eyewash stations.Engineering Controls (Ventilation etc.): 8.2 Exposure Controls: 8.2.2 Personal protection equipment: Section 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: NE Boiling Point: No data. Flash Pt: < 0.00 F (-17.8 C) Method Used: TAG Closed Cup Explosive Limits: LEL: No data. UEL: No data. Vapor Pressure (vs. Air or mm Hg): NE Vapor Density (vs. Air = 1): NE Evaporation Rate: NE Clear, colorless spray/mist. Typical solvent odor.Appearance and Odor: 9.1 Information on Basic Physical and Chemical Properties Specific Gravity (Water = 1): .81 Solubility in Water: Negligible Autoignition Pt: No data. Viscosity: NE Percent Volatile: NE 9.2 Other Information 10.4 10.5 10.1 10.2 10.3 Section 10. Stability and Reactivity Keep away from heat, sparks and flame. Temperature over 120 degrees F.Conditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Strong acids. Strong oxidizing agents.Incompatibility - Materials To Avoid: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: No data available.Conditions To Avoid - Hazardous Reactions: No data available.Reactivity: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 04/26/2013Revision: 04/26/2013Printed: Page: 5 Disc Brake Quiet SAFETY DATA SHEET 01/30/2012Supercedes Revision: 10.6 Carbon monoxide. Carbon dioxide.Hazardous Decomposition Or Byproducts: 11.1 Section 11. Toxicological Information No data available.Information on Toxicological Effects: CAS# 142-82-5: Other Studies:, TDLo, Oral, Rat, 60.00 GM/KG, 3 W. Results: Kidney, Ureter, Bladder: Changes in liver weight. - National Technical Information Service, Vol/p/yr: OTS0571116, Other Studies:, TDLo, Oral, Rat, 260.0 GM/KG, 13 W. Results: Kidney, Ureter, Bladder: Changes in bladder weight. Endocrine:Hypoglycemia. Nutritional and Gross Metabolic:Weight loss or decreased weight gain. - National Technical Information Service, Vol/p/yr: OTS0571116, Other Studies:, TCLo, Inhalation, Rat, 4000. PPM, 6 D. Results: Brain and Coverings: Recordings from specific areas of CNS. Sense Organs and Special Senses (Nose, Eye, Ear, and Taste): Ear: Changes in cochlear structure or function. Nutritional and Gross Metabolic:Weight loss or decreased weight gain. - Pharmacology and Toxicology, Munksgaard International Pub., POB 2148, Copenhagen K Denmark, Vol/p/yr: 76,41, 1995 Other Studies:, TDLo, Intraperitoneal, Rat, 9625. MG/KG, 7 D. Results: Liver: Other changes. Blood:Changes in serum composition (e.g. Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels: Multiple enzyme effects. - Toxicology Letters., Elsevier Science Pub. B.V., POB 211, 1000 AE, Amsterdam 1000 AE Netherlands, Vol/p/yr: 14,169, 1982 Other Studies:, TDLo, Intraperitoneal, Rat, 8840. MG/KG, 45 D. Results: Liver: Other changes. Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels: Phosphatases. Biochemical:Enzyme inhibition, induction, or change in blood or tissue levels: Hepatic microsomal mixed oxidase (dealkylation, hydroxylation, etc.) - JAT, Journal of Applied Toxicology., John Wiley & Sons Ltd., Baffins Lane, Chichester, W.Sussex PO19 1UD UK, Vol/p/yr: 8,81, 1988 Acute toxicity, TCLo, Inhalation, Human, 1000. PPM, 6 M. Results: Behavioral: Hallucinations, distorted perceptions. - "U.S. Bureau of Mines Report of Investigation No. 2979," Patty, F.A., and W.P. Yant, 1929 Volume, Vol/p/yr: 2979,-, 1929 MIRS MSDS, (c) A V Systems, Inc. Multi-region format 04/26/2013Revision: 04/26/2013Printed: Page: 6 Disc Brake Quiet SAFETY DATA SHEET 01/30/2012Supercedes Revision: CAS # Hazardous Components (Chemical Name) NTP IARC ACGIH OSHA Acute toxicity, LC50, Inhalation, Rat, 103.0 GM/M3, 4 H. Results: Behavioral: Change in motor activity (specific assay). Behavioral: Alteration of classical conditioning. - Gigiena Truda i Professional'nye Zabolevaniya.(Labor Hygiene and Occupational Disease), V/O Mezhdunarodnaya Kniga, Moscow 113095 Russia, Vol/p/yr: 32(10),23, 1988 Acute toxicity, LCLO, Inhalation, Mouse, 59.00 GM/M3, 41 M. Results: Behavioral: Convulsions or effect on seizure threshold. - Biochemische Zeitschrift., For publisher information, see EJBCAI, Berlin Germany, Vol/p/yr: 115,235, 1921 Acute toxicity, LD50, Intravenous, Mouse, 222.0 MG/KG. Results: Brain and Coverings: Changes in circulation (hemorrhage,thrombosis, etc. Lungs, Thorax, or Respiration:Dyspnea. Gastrointestinal:Nausea or vomiting. - Journal of Pharmaceutical Sciences., American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037, Vol/p/yr: 67,566, 1978 142-82-5 Heptane n.a. n.a. n.a. n.a. 74-98-6 Propane n.a. n.a. n.a. n.a. 108-88-3 Toluene n.a. 3 A4 n.a. 106-97-8 Butane n.a. n.a. n.a. n.a. Section 12. Ecological Information 13.1 Disposal should be made in accordance with federal, state and local regulations.Waste Disposal Method: Section 13. Disposal Considerations Section 14. Transport Information Consumer CommodityDOT Proper Shipping Name: ORM-D ORM-DDOT Hazard Class: UN/NA Number: 14.1 LAND TRANSPORT (US DOT): ADR/RID Shipping Name: 14.1 LAND TRANSPORT (European ADR/RID): 1950UN Number: N.A.Hazard Class: 2ADR Classification: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 04/26/2013Revision: 04/26/2013Printed: Page: 7 Disc Brake Quiet SAFETY DATA SHEET 01/30/2012Supercedes Revision: Aerosols, Ltd. Qty.IMDG/IMO Shipping Name: 14.2 MARINE TRANSPORT (IMDG/IMO): 1950UN Number: Packing Group: N.A.Hazard Class: 2.1IMDG Classification: Aerosols, flammable, 2.1, Ltd. Qty.ICAO/IATA Shipping Name: 14.3 AIR TRANSPORT (ICAO/IATA): 1950UN Number: N.A.Hazard Class: 2.1IATA Classification: CAS # Hazardous Components (Chemical Name) Section 15. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 142-82-5 Heptane No No No 74-98-6 Propane No No No 108-88-3 Toluene No Yes 1000 LB Yes 106-97-8 Butane No No No CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 142-82-5 Heptane CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory, 4 Test, 8A PAIR; CA PROP.65: No; CA TAC, Title 8: Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: No; NC TAP: No; NJ EHS: Yes - 1339; NY Part 597: No; PA HSL: Yes - 1; SC TAP: No; WI Air: No 74-98-6 Propane CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: Yes; MI CMR, Part 5: No; NC TAP: No; NJ EHS: Yes - 1594; NY Part 597: No; PA HSL: Yes - 1; SC TAP: No; WI Air: No 108-88-3 Toluene CAA HAP,ODC: HAP; CWA NPDES: Yes; TSCA: Inventory, 8A CAIR; CA PROP.65: Yes; CA TAC, Title 8: TAC, Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: CMR, Part 5; NC TAP: Yes; NJ EHS: Yes - 1866; NY Part 597: Yes; PA HSL: Yes - E; SC TAP: Yes; WI Air: Yes 106-97-8 Butane CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: No; NC TAP: No; NJ EHS: Yes - 0273; NY Part 597: No; PA HSL: Yes - 1; SC TAP: No; WI Air: No CAS # Hazardous Components (Chemical Name) International Regulatory Lists 142-82-5 Heptane Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: No 74-98-6 Propane Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: No 108-88-3 Toluene Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: No 106-97-8 Butane Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: No Section 16. Other Information No data available.Additional Information About This Product: Cyclo Industries, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving this information must exercise their independent judgment in determining its appropriateness Company Policy or Disclaimer: 04/26/2013Revision Date: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 04/26/2013Revision: 04/26/2013Printed: Page: 8 Disc Brake Quiet SAFETY DATA SHEET 01/30/2012Supercedes Revision: for a particular purpose. Cyclo Industries, Inc. makes no representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, Cyclo Industries, Inc. will not be responsible for damages resulting from use of or reliance upon this information. MIRS MSDS, (c) A V Systems, Inc. Multi-region format