10/28/2014Revision: Page: 1 Fogging Oil SAFETY DATA SHEET 06/13/2013Supersedes Revision: C4100Product Code: Fogging OilProduct Name: CYCLO INDUSTRIES, INC.Company Name: 902 SOUTH US HIGHWAY 1 JUPITER, FL 33477 First Aid EmergencyEmergency Contact: (800)752-7869 CHEMTREC (703) 527-3887 (800)424-9300 First Aid Emergency (Outside U.S.)Information: (312)906-6194 (800)843-7813 Phone Number: www.cyclo.comWeb site address: 1. Product and Company Identification This email address is being protected from spambots. You need JavaScript enabled to view it. address: 2. Hazards Identification P233: Keep container tightly closed. P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P280: Wear protective gloves/protective clothing/eye protection/face protection. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P243: Take precautionary measures against static discharge. P242: Use only non-sparking tools. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P270: Do not eat, drink or smoke when using this product. P281: Use personal protective equipment as required. GHS Precaution Phrases: P370+378: In case of fire, use foam, carbon dioxide, dry chemical oralcohol-resistantGHS Response Phrases: H220: Extremely flammable gas. H226: Flammable liquid and vapor. H304: May be fatal if swallowed and enters airways. H315: Causes skin irritation. H317: May cause an allergic skin reaction. H317: May cause an allergic skin reaction H319: Causes serious eye damage. H332: Harmful if inhaled. H336: May cause drowiness or dizziness. H340: May cause genetic defects. H350: May cause cancer. H280: Contents under pressure. May explode if heated. GHS Hazard Phrases: Flammable Liquids, Category 3 Acute Toxicity: Inhalation, Category 4 Germ Cell Mutagenicity, Category 1A Carcinogenicity, Category 1B Aspiration Toxicity, Category 1 Skin Corrosion/Irritation, Category 2 Skin Sensitization, Category 1 Serious Eye Damage/Eye Irritation, Category 2A DangerGHS Signal Word: MIRS MSDS, (c) A V Systems, Inc. GHS format 10/28/2014Revision: Page: 2 Fogging Oil SAFETY DATA SHEET 06/13/2013Supersedes Revision: foam to extinguish. P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P363: Wash contaminated clothing before reuse. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309+311: Call a POISON CENTER or doctor/physician if exposed or you feel unwell. P403+235: Store in cool/well-ventilated place. P501: Dispose of contents/container in accordance with local/regional/national/international regulation. P405: Store locked up. GHS Storage and Disposal Phrases: Repeated contact with skin may irritate pre-existing skin conditions.Medical Conditions Generally Aggravated By Exposure: Potential Health Effects (Acute and Chronic): CAS # Hazardous Components (Chemical Name) 3. Composition/Information on Ingredients Concentration 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic 50.0 -70.0 % 68476-86-8 Liquified petroleum gas, sweetened 15.0 -25.0 % 64742-46-7 Hydrotreated Distillate 15.0 -20.0 % NA Corrosion Inhibitor 0.9 % 8052-41-3 Stoddard solvent 0.73 % 57855-77-3 Naphthalenesulfonic acid, dinonyl-, calcium salt 0.06 % 4. First Aid Measures If swallowed, do not induce vomiting. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. In case of skin contact, wash with soap and large amounts of water. Remove contaminated clothing. If in eyes, rinse cautiously with water for several minutes, Remove contact lenses, if present and easy to do. Continue rinsing. Call physician immediately if adverse reaction occurs. Emergency and First Aid Procedures: Eyes: Contact with eyes may cause irritation, redness and pain. Causes moderate to severe eye irritation. Skin: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). Prolonged contact with liquid may cause slight temporary irritation. Inhalation: Prolonged inhalation may be harmful. Inhaling large quantities of mist or vapor may cause some irritation to nose, throat and lungs. Avoid breathing mists from this product. Exposure to high doses may cause central nervous system depression (anesthetic-like effects). Doses which cause anesthetic-like effects may also cause adverse effects in liver, lungs and kidneys. Ingestion: Ingestion is not considered to be a hazard encountered in normal industrial use. This material may be harmful or fatal if swallowed. Aspiration hazard. Low order of Signs and Symptoms Of Exposure: MIRS MSDS, (c) A V Systems, Inc. GHS format 10/28/2014Revision: Page: 3 Fogging Oil SAFETY DATA SHEET 06/13/2013Supersedes Revision: toxicity. May cause mild nausea and abdominal discomfort. 5. Fire Fighting Measures Flash Pt: -141.00 F (-96.1 C) Method Used: TAG Closed Cup Containers can build up pressure if exposed to heat (fire). As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Keep containers and surroundings cool with water spray. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulating in low areas. Fire Fighting Instructions: Vapors can travel to a source of ignition and flash back. Extremely flammable. Material will readily ignite at room temperatures in the presence of an ignition source. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, flame, sparks, static electricity, or other sources of ignition; they may explode and cause injury or death. Contents under pressure. Containers may explode if exposed to high temperatures. Flammable Properties and Hazards: Autoignition Pt: No data. Explosive Limits: LEL: .7 UEL: 9.5 Flammability Classification: NFPA Level 3 Aerosol Foam, carbon dioxide, dry chemical, alcohol-resistant foam.Suitable Extinguishing Media: 6. Accidental Release Measures Use recommended personal protective equipment. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Steps To Be Taken In Case Material Is Released Or Spilled: 7. Handling and Storage Wash thoroughly after handling. Use only in well-ventilated area. Keep out of the reach of children. Precautions To Be Taken in Handling: Keep from freezing. Keep away from heat, sparks, and flame. Keep container closed when not in use. Do not store above 120 degrees F. Do not spray into open flame or near other sources of ignition. Do not store in direct contact with sunlight, puncture, crush or incinerate container. Precautions To Be Taken in Storing: 8. Exposure Controls/Personal Protection OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits No data.No data. No data. 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic No data.No data. No data. 68476-86-8 Liquified petroleum gas, sweetened No data.No data. No data. 64742-46-7 Hydrotreated Distillate No data.No data. No data. NA Corrosion Inhibitor No data.PEL: 500 ppm TLV: 100 ppm 8052-41-3 Stoddard solvent No data.No data. No data. 57855-77-3 Naphthalenesulfonic acid, dinonyl-, calcium salt MIRS MSDS, (c) A V Systems, Inc. GHS format 10/28/2014Revision: Page: 4 Fogging Oil SAFETY DATA SHEET 06/13/2013Supersedes Revision: A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Respiratory Equipment (Specify Type): Wear safety glasses with side shields or goggles when using this product.Eye Protection: Gloves resistant to petroleum distillates should be worn.Protective Gloves: Wear impervious protective clothing, including boots, gloves, protective apron or coveralls to prevent skin contact. Other Protective Clothing: Good general ventilation should be sufficient to control airborne levels. Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. Engineering Controls (Ventilation etc.): Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Follow all MSDS/label precautions even after container is emptied because they may retain product residues. Use spark-proof tools and explosion proof equipment. Avoid prolonged or repeated contact with skin. Avoid breathing vapors from heated material. Avoid contact with eyes, skin and clothing. Work/Hygienic/Maintenance Practices: 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: -94.00 C (-137.2 F) Autoignition Pt: No data. Flash Pt: -141.00 F (-96.1 C) Method Used: TAG Closed Cup Explosive Limits: LEL: .7 UEL: 9.5 Specific Gravity (Water = 1): .820 Light amber brown liquid with solvent odor.Appearance and Odor: Vapor Pressure (vs. Air or mm Hg): No data. Vapor Density (vs. Air = 1): No data. Evaporation Rate: No data. Solubility in Water: No data. Percent Volatile: 27.62 % by weight. 10. Stability and Reactivity Open flames and high temperatures. Contact with strong oxidizing agents. Avoid all sources of ignition, welding arcs and open flames. Keep product away from temperatures in excess of 120F (49C). Do not crush, puncture or incinerate container. Do not expose to direct sunlight or store where temperatures could exceed 120F. Conditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Strong oxidizing agents. Strong bases.Incompatibility - Materials To Avoid: Carbon oxides; fumes.Hazardous Decomposition Or Byproducts: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: MIRS MSDS, (c) A V Systems, Inc. GHS format 10/28/2014Revision: Page: 5 Fogging Oil SAFETY DATA SHEET 06/13/2013Supersedes Revision: No data available.Conditions To Avoid - Hazardous Reactions: 11. Toxicological Information LD50: >5000 mg/kg LC50: >4600 ppm Toxicological Information: CAS# 64742-52-5: Mutagenicity:, Mutation test: Mutation in microorganisms., 10.00 UL/PLAT, Bacteria - Salmonella typhimurium,. Results: Behavioral: Coma. Biochemical:Metabolism (intermediary): Other. - Cell Biology and Toxicology., Princeton Scientific Pub., Inc., 301 N. Harrison St., CN 5279, Princeton, NJ 08540, Vol/p/yr: 2,63, 1986 Acute toxicity, LD (Lethal dose), Oral, Rat, 5.000 GM/KG. Results: Tumorigenic: Neoplastic by RTECS criteria. Lungs, Thorax, or Respiration: Tumors. Tumorigenic:Tumors at site of application. - Acute Toxicity Data. Journal of the American College of Toxicology, Part B., Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128, Vol/p/yr: 1,133, 1990 Acute toxicity, LD (Lethal dose), Skin, Species: Rabbit, 5.000 GM/KG. Results: Behavioral: Coma. Biochemical:Metabolism (intermediary): Other. - Acute Toxicity Data. Journal of the American College of Toxicology, Part B., Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128, Vol/p/yr: 1,133, 1990 Tumorigenic Effects:, TDLo, Skin, Mouse, 480.0 GM/KG, 80 W. Results: Tumorigenic: Neoplastic by RTECS criteria. Skin and Appendages: Other: Tumors. Tumorigenic:Tumors at site of application. - United States Environmental Protection Agency, Office of Pesticides and Toxic Substances., U.S. Environmental Protection Agency, Office of Pesticides and Toxic Substances, 401 M St., SW, Washington, DC 20460, Vol/p/yr: 8EHQ-0887-, Tumorigenic Effects:, TDLo, Skin, Mouse, 402.0 GM/KG, 78 W. Results: Tumorigenic: Equivocal tumorigenic agent by RTECS criteria. Skin and Appendages: Other: Tumors. Tumorigenic:Tumors at site of application. - British Journal of Cancer., Macmillan Press Ltd, Houndmills, Basingstoke, Hampshire RG21 2XS UK, Vol/p/yr: 48,429, 1983 Tumorigenic Effects:, TDLo, Skin, Mouse, 398.0 GM/KG, 22 W. Results: Tumorigenic: Equivocal tumorigenic agent by RTECS criteria. Skin and Appendages: Other: Tumors. Tumorigenic:Tumors at site of application. MIRS MSDS, (c) A V Systems, Inc. GHS format 10/28/2014Revision: Page: 6 Fogging Oil SAFETY DATA SHEET 06/13/2013Supersedes Revision: CAS # Hazardous Components (Chemical Name) NTP IARC ACGIH OSHA - British Journal of Cancer., Macmillan Press Ltd, Houndmills, Basingstoke, Hampshire RG21 2XS UK, Vol/p/yr: 48,429, 1983 Standard Draize Test, Skin, Species: Rabbit, 500.0 MG, Severe. Results: Tumorigenic: Equivocal tumorigenic agent by RTECS criteria. Skin and Appendages: Other: Tumors. Tumorigenic:Tumors at site of application. - Acute Toxicity Data. Journal of the American College of Toxicology, Part B., Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128, Vol/p/yr: 1,133, 1990 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic n.a. n.a. n.a. n.a. 68476-86-8 Liquified petroleum gas, sweetened n.a. n.a. n.a. n.a. 64742-46-7 Hydrotreated Distillate n.a. n.a. n.a. n.a. NA Corrosion Inhibitor n.a. n.a. n.a. n.a. 8052-41-3 Stoddard solvent n.a. n.a. n.a. n.a. 57855-77-3 Naphthalenesulfonic acid, dinonyl-, calcium salt n.a. n.a. n.a. n.a. No data available. 12. Ecological Information Dispose of contents/container in accordance with local/regional/national/international regulation. Waste Disposal Method: 13. Disposal Considerations 14. Transport Information Consumer CommodityDOT Proper Shipping Name: ORM-D ORM-DDOT Hazard Class: UN/NA Number: LAND TRANSPORT (US DOT): ADR/RID Shipping Name: LAND TRANSPORT (European ADR/RID): 1950UN Number: N.A.Hazard Class: 2ADR Classification: Aerosols, Ltd. Qty.IMDG/IMO Shipping Name: MARINE TRANSPORT (IMDG/IMO): 1950UN Number: Packing Group: N.A.Hazard Class: 2.1IMDG Classification: NoMarine Pollutant: Aerosols, flammable, 2.1, Ltd. Qty.ICAO/IATA Shipping Name: AIR TRANSPORT (ICAO/IATA): 1950UN Number: N.A.Hazard Class: 2.1IATA Classification: MIRS MSDS, (c) A V Systems, Inc. GHS format 10/28/2014Revision: Page: 7 Fogging Oil SAFETY DATA SHEET 06/13/2013Supersedes Revision: CAS # Hazardous Components (Chemical Name) 15. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic No No No 68476-86-8 Liquified petroleum gas, sweetened No No No 64742-46-7 Hydrotreated Distillate No No No NA Corrosion Inhibitor No No No 8052-41-3 Stoddard solvent No No No 57855-77-3 Naphthalenesulfonic acid, dinonyl-, calcium salt No No No CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 68476-86-8 Liquified petroleum gas, sweetened CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 64742-46-7 Hydrotreated Distillate CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No NA Corrosion Inhibitor CAA HAP,ODC: No; CWA NPDES: No; TSCA: No; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 8052-41-3 Stoddard solvent CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: Title 8; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: Yes - 1736; NY Part 597: No; PA HSL: Yes - 1; SC TAP: No; WI Air: Yes 57855-77-3 Naphthalenesulfonic acid, dinonyl-, calcium salt CAA HAP,ODC: No; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No CAS # Hazardous Components (Chemical Name) International Regulatory Lists 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 68476-86-8 Liquified petroleum gas, sweetened Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 64742-46-7 Hydrotreated Distillate Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes NA Corrosion Inhibitor Canadian DSL: No; Canadian NDSL: No; Taiwan TCSCA: No 8052-41-3 Stoddard solvent Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 57855-77-3 Naphthalenesulfonic acid, dinonyl-, calcium salt Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes MIRS MSDS, (c) A V Systems, Inc. GHS format 10/28/2014Revision: Page: 8 Fogging Oil SAFETY DATA SHEET 06/13/2013Supersedes Revision: 16. Other Information No data available.Additional Information About This Product: Hazard Rating System: Instability Special Hazard Health Flammability Cyclo Industries, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Cyclo Industries, Inc. makes no representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, Cyclo Industries, Inc. will not be responsible for damages resulting from use of or reliance upon this information. Company Policy or Disclaimer: 2 4 0 10/28/2014Revision Date: NFPA: MIRS MSDS, (c) A V Systems, Inc. GHS format