10/15/2014Revision: Page: 1 Chain & Cable Lube SAFETY DATA SHEET 05/05/2014Supersedes Revision: according to Regulation (EC) No. 1907/2006 as amended by (EC) No. 1272/2008 C6611.1 Product Code: Chain & Cable Lube Product Name: CYCLO INDUSTRIES, INC.Company Name: 902 SOUTH US HIGHWAY 1 JUPITER, FL 33477 First Aid EmergencyEmergency Contact: (800)752-7869 CHEMTREC (703) 527-3887 (800)424-9300 First Aid Emergency (Outside U.S.)Information: (312)906-6194 (800)843-7813 Phone Number: www.cyclo.comWeb site address: Section 1. Identification of the Substance/Mixture and of the Company/Undertaking 1.3 Details of the Supplier of the Safety Data Sheet: 1.2 Relevant identified uses of the substance or mixture and uses advised against: 1.4 Emergency telephone number: Section 2. Hazards Identification Germ Cell Mutagenicity, Category 1B Carcinogenicity, Category 1B Aspiration Toxicity, Category 1 Flammable Liquids, Category 1 Flammable Gases, Category 1 Serious Eye Damage/Eye Irritation, Category 2A Target Organ Systemic Toxicity (single exposure), Category 3 2.1 Classification of the Substance or Mixture: 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP]: 2.1.2 Classification according to Directive 1999/45/EC: P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood. P281: Use personal protective equipment as required. P233: Keep container tightly closed. P210: Keep away from heat/sparks/open flames/hot surfaces - No smoking. P280: Wear protective gloves/protective clothing/eye protection/face protection. GHS Precaution Phrases: H220: Extremely flammable gas. H224: Extremely flammable liquid and vapor. H340: May cause genetic defects. H350: May cause cancer. H304: May be fatal if swallowed and enters airways. H319: Causes serious eye irritation. H335: May cause respiratory irritation. H336: May cause drowsiness or dizziness. H280: Contents under pressure. May explode if heated. GHS Hazard Phrases: 2.2 Label Elements: 2.2.1 Labeling according to Regulation (EC) No 1272/2008 [CLP]: DangerGHS Signal Word: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 10/15/2014Revision: Page: 2 Chain & Cable Lube SAFETY DATA SHEET 05/05/2014Supersedes Revision: P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment specified by the manufacturer/supplier or the competent authority. - if dust clouds can occur. P243: Take precautionary measures against static discharge. P242: Use only non-sparking tools. P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P370+378: In case of fire, use alcohol foam, carbon dioxide, dry chemical or water fog to extinguish. P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P363: Wash contaminated clothing before reuse. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309+311: Call a POISON CENTER or doctor/physician if exposed or you feel unwell. GHS Response Phrases: P405: Store locked up. P501: Dispose of contents/container in accordance with local/regional/national/international regulation. P403+233: Store container tightly closed in well-ventilated place - if product is as volatile as to generate hazardous atmosphere. GHS Storage and Disposal Phrases: 2.2.2 Labeling according to Directive 1999/45/EC: 2.3 Adverse Human Health Effects and Symptoms: Hazard Rating System: Instability Special Hazard Health Flammability 2 4 0 CAS # Hazardous Components (Chemical Name)/ REACH Registration No. Section 3. Composition/Information on Ingredients Concentration EC No./ EC Index No. Risk Phrases/ GHS Classification 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic 55.0 -60.0 % 265-155-0 649-465-00-7 T; R45 Carcinogen 1B: H350 68476-86-8 Liquified petroleum gas, sweetened 15.0 -20.0 % 270-705-8 649-203-00-1 F+; T; R12-45-46 Comp. Gas: H280 Flam. Gas 1: H220 Mutagen 1B: H340 Carcinogen 1B: H350 64742-48-9 Hydrotreated heavy naphtha 5.0 -10.0 % 265-150-3 649-327-00-6 T; R45-65 Asp. Toxic. 1: H304 Mutagen 1B: H340 Carcinogen 1B: H350 79-20-9 Methyl acetate (Methyl ester of acetic acid} 5.0 -10.0 % 201-185-2 607-021-00-X F; Xi; R11-36-66-67 Flam. Liq. 2: H225 Eye Damage 2A: H319 TOST (SE) 3: H335 H336 64742-49-0 Naphtha (petroleum), hydrotreated light 1.0 -5.0 % 265-151-9 T; R45-65 MIRS MSDS, (c) A V Systems, Inc. Multi-region format 10/15/2014Revision: Page: 3 Chain & Cable Lube SAFETY DATA SHEET 05/05/2014Supersedes Revision: 649-328-00-1 Asp. Toxic. 1: H304 Mutagen 1B: H340 Carcinogen 1B: H350 67-64-1 Acetone 1.0 -5.0 % 200-662-2 606-001-00-8 F; Xi; R11-36-66-67 Flam. Liq. 2: H225 Eye Damage 2A: H319 TOST (SE) 3: H335 H336 64741-88-4 Mineral oil 1.0 -5.0 % 265-090-8 649-454-00-7 T; R45 Carcinogen 1B: H350 Section 4. First Aid Measures If swallowed, do not induce vomiting. If large amounts are swallowed, immediately call a physician. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If in eyes, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. In case of skin contact, wash with soap & large amounts of water. Remove contaminated clothing. Call physician immediately if adverse reaction occurs. Description of First Aid Measures: 4.1 5.1 5.2 Section 5. Fire Fighting Measures Flash Pt: -156.00 F (-104.4 C) Containers can build up pressure if exposed to heat (fire). As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Keep containers and surroundings cool with water spray. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Fire Fighting Instructions: Autoignition Pt: No data. Explosive Limits: LEL: 1.0 UEL: 9.5 Flammability Classification: NFPA Level 3 Aerosol Alcohol foam. Carbon dioxide. Dry chemical. Water fog.Suitable Extinguishing Media: Vapors can travel to a source of ignition and flash back. Extremely flammable. Material will readily ignite at room temperatures in the presence of an ignition source. "Empty" containers retain product residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind or expose such containers to heat, flame, sparks, static electricity or other sources of ignition; they may explode and cause injury or death. Contents under pressure. Containers may explode if exposed to high temperatures. Flammable Properties and Hazards: 5.3 6.3 Section 6. Accidental Release Measures Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Methods and Material For Containment and Cleaning Up: 7.1 Section 7. Handling and Storage Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Keep container tightly closed. Keep away from heat/sparks/open flames/hot surfaces - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment specified by the manufacturer/supplier or the competent authority. - if dust clouds can occur. Take precautionary measures against Precautions To Be Taken in Handling: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 10/15/2014Revision: Page: 4 Chain & Cable Lube SAFETY DATA SHEET 05/05/2014Supersedes Revision: 7.2 static discharge. Use only non-sparking tools. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Avoid breathing dust/fume/gas/mist/vapours/spray. Keep out of the reach of children. Store in cool/well-ventilated place. Store locked up.Precautions To Be Taken in Storing: Section 8. Exposure Controls/Personal Protection Britain EH40 France VLCAS # Partial Chemical Name Europe 8.1 Exposure Parameters: No data. No data. 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic No data. No data. No data. 68476-86-8 Liquified petroleum gas, sweetened No data. No data. No data. 64742-48-9 Hydrotreated heavy naphtha No data. TWA: 616 mg/m3 (200 ppm) STEL: 770 mg/m3 (250 ppm) TWA: 610 mg/m3 (200 ppm) STEL: 760 mg/m3 (250 ppm) 79-20-9 Methyl acetate (Methyl ester of acetic acid} No data. No data. No data. 64742-49-0 Naphtha (petroleum), hydrotreated light No data. TWA: 1210 mg/m3 (500 ppm) STEL: 3620 mg/m3 (1500 ppm) TWA: 1210 mg/m3 (500 ppm) STEL: 2420 mg/m3 (1000 ppm) 67-64-1 Acetone TWA: 1210 mg/m3 No data. No data. 64741-88-4 Mineral oil No data. OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits No data. No data. 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic No data. No data. No data. 68476-86-8 Liquified petroleum gas, sweetened No data. No data. No data. 64742-48-9 Hydrotreated heavy naphtha No data. PEL: 200 ppm TLV: 200 ppm STEL: 250 ppm 79-20-9 Methyl acetate (Methyl ester of acetic acid} No data. No data. No data. 64742-49-0 Naphtha (petroleum), hydrotreated light No data. PEL: 1000 ppm TLV: 500 ppm STEL: 750 ppm 67-64-1 Acetone No data. No data. No data. 64741-88-4 Mineral oil No data. 8.2.1 A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where air purifying respirators may not provide adequate protection. Respiratory Equipment (Specify Type): Wear safety glasses with side shields or goggles when using this product.Eye Protection: Impervious gloves.Protective Gloves: Standard industrial clothing standards should be followed.Other Protective Clothing: Good general ventilation should be sufficient to control airborne levels. Local exhaust ventilation may be necessary to control any air contaminants to within their TLVs during the use of this product. Engineering Controls (Ventilation etc.): 8.2 Exposure Controls: 8.2.2 Personal protection equipment: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 10/15/2014Revision: Page: 5 Chain & Cable Lube SAFETY DATA SHEET 05/05/2014Supersedes Revision: Wash hands before eating. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Follow all MSDS/label precautions even after container is emptied because they may retain product residues. Avoid prolonged or repeated contact with skin. Avoid breathing vapors from heated material. Avoid contact with eyes, skin and clothing. Work/Hygienic/Mainten ance Practices: Section 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: No data. Boiling Point: -23.00 F (-30.6 C) - 158.00 F (70.0 C) Flash Pt: -156.00 F (-104.4 C) Explosive Limits: LEL: 1.0 UEL: 9.5 Vapor Pressure (vs. Air or mm Hg): No data. Vapor Density (vs. Air = 1): > air Evaporation Rate: No data. Dark grey with solvent odor.Appearance and Odor: 9.1 Information on Basic Physical and Chemical Properties Specific Gravity (Water = 1): .7646 Solubility in Water: Negligible Autoignition Pt: No data. Percent Volatile: 24.8 % by weight. 9.2 Other Information 10.4 10.5 10.6 10.1 10.2 10.3 Section 10. Stability and Reactivity Open flames and high temperatures. Contact with strong oxidizing agents. All sources of ignition, welding and arcs. Keep product away from temperatures in excess of 120 degrees F. Do not crush, puncture or incinerate container. Do not expose to direct sunlight or store where temperatures could exceed 120 degrees F. Conditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Strong oxidizers.Incompatibility - Materials To Avoid: Smoke, fumes, oxides of carbon, nitrogen, silica and various metal oxides are possible decomposition products. Hazardous Decomposition Or Byproducts: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: No data available.Conditions To Avoid - Hazardous Reactions: No data available.Reactivity: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 10/15/2014Revision: Page: 6 Chain & Cable Lube SAFETY DATA SHEET 05/05/2014Supersedes Revision: 11.1 Section 11. Toxicological Information No data available.Information on Toxicological Effects: CAS# 64742-52-5: Mutagenicity:, Mutation test: Mutation in microorganisms., 10.00 UL/PLAT, Bacteria - Salmonella typhimurium,. Results: Behavioral: Coma. Biochemical:Metabolism (intermediary): Other. - Cell Biology and Toxicology., Princeton Scientific Pub., Inc., 301 N. Harrison St., CN 5279, Princeton, NJ 08540, Vol/p/yr: 2,63, 1986 Acute toxicity, LD (Lethal dose), Oral, Rat, 5.000 GM/KG. Results: Tumorigenic: Neoplastic by RTECS criteria. Lungs, Thorax, or Respiration: Tumors. Tumorigenic:Tumors at site of application. - Acute Toxicity Data. Journal of the American College of Toxicology, Part B., Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128, Vol/p/yr: 1,133, 1990 Acute toxicity, LD (Lethal dose), Skin, Species: Rabbit, 5.000 GM/KG. Results: Behavioral: Coma. Biochemical:Metabolism (intermediary): Other. - Acute Toxicity Data. Journal of the American College of Toxicology, Part B., Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128, Vol/p/yr: 1,133, 1990 Tumorigenic Effects:, TDLo, Skin, Mouse, 480.0 GM/KG, 80 W. Results: Tumorigenic: Neoplastic by RTECS criteria. Skin and Appendages: Other: Tumors. Tumorigenic:Tumors at site of application. - United States Environmental Protection Agency, Office of Pesticides and Toxic Substances., U.S. Environmental Protection Agency, Office of Pesticides and Toxic Substances, 401 M St., SW, Washington, DC 20460, Vol/p/yr: 8EHQ-0887-, Tumorigenic Effects:, TDLo, Skin, Mouse, 402.0 GM/KG, 78 W. Results: Tumorigenic: Equivocal tumorigenic agent by RTECS criteria. Skin and Appendages: Other: Tumors. Tumorigenic:Tumors at site of application. - British Journal of Cancer., Macmillan Press Ltd, Houndmills, Basingstoke, Hampshire RG21 2XS UK, Vol/p/yr: 48,429, 1983 Tumorigenic Effects:, TDLo, Skin, Mouse, 398.0 GM/KG, 22 W. Results: Tumorigenic: Equivocal tumorigenic agent by RTECS criteria. Skin and Appendages: Other: Tumors. Tumorigenic:Tumors at site of application. - British Journal of Cancer., Macmillan Press Ltd, Houndmills, Basingstoke, Hampshire RG21 2XS UK, Vol/p/yr: 48,429, 1983 MIRS MSDS, (c) A V Systems, Inc. Multi-region format 10/15/2014Revision: Page: 7 Chain & Cable Lube SAFETY DATA SHEET 05/05/2014Supersedes Revision: CAS # Hazardous Components (Chemical Name) NTP IARC ACGIH OSHA Standard Draize Test, Skin, Species: Rabbit, 500.0 MG, Severe. Results: Tumorigenic: Equivocal tumorigenic agent by RTECS criteria. Skin and Appendages: Other: Tumors. Tumorigenic:Tumors at site of application. - Acute Toxicity Data. Journal of the American College of Toxicology, Part B., Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128, Vol/p/yr: 1,133, 1990 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic n.a. n.a. n.a. n.a. 68476-86-8 Liquified petroleum gas, sweetened n.a. n.a. n.a. n.a. 64742-48-9 Hydrotreated heavy naphtha n.a. n.a. n.a. n.a. 79-20-9 Methyl acetate (Methyl ester of acetic acid} n.a. n.a. n.a. n.a. 64742-49-0 Naphtha (petroleum), hydrotreated light n.a. n.a. n.a. n.a. 67-64-1 Acetone n.a. n.a. A4 n.a. 64741-88-4 Mineral oil n.a. n.a. n.a. n.a. Section 12. Ecological Information 13.1 Dispose of contents/container in accordance with local/regional/national/international regulation. Waste Disposal Method: Section 13. Disposal Considerations Section 14. Transport Information Consumer CommodityDOT Proper Shipping Name: ORM-D ORM-DDOT Hazard Class: UN/NA Number: 14.1 LAND TRANSPORT (US DOT): Aerosols, Ltd. Qty.ADR/RID Shipping Name: 14.1 LAND TRANSPORT (European ADR/RID): 1950UN Number: N.A.Hazard Class: 2.1ADR Classification: Aerosols, Ltd. Qty.IMDG/IMO Shipping Name: 14.2 MARINE TRANSPORT (IMDG/IMO): 1950UN Number: Packing Group: N.A.Hazard Class: 2.1IMDG Classification: NoMarine Pollutant: Aerosols, Flammable, Ltd. Qty, 2.1ICAO/IATA Shipping Name: 14.3 AIR TRANSPORT (ICAO/IATA): 1950UN Number: N.A.Hazard Class: 2.1IATA Classification: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 10/15/2014Revision: Page: 8 Chain & Cable Lube SAFETY DATA SHEET 05/05/2014Supersedes Revision: CAS # Hazardous Components (Chemical Name) Section 15. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic No No No 68476-86-8 Liquified petroleum gas, sweetened No No No 64742-48-9 Hydrotreated heavy naphtha No No No 79-20-9 Methyl acetate (Methyl ester of acetic acid} No No No 64742-49-0 Naphtha (petroleum), hydrotreated light No No No 67-64-1 Acetone No Yes 5000 LB No 64741-88-4 Mineral oil No No No CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 68476-86-8 Liquified petroleum gas, sweetened CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 64742-48-9 Hydrotreated heavy naphtha CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 79-20-9 Methyl acetate (Methyl ester of acetic acid} CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory, 4 Test, 8A PAIR; CA PROP.65: No; CA TAC, Title 8: Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: Yes - 1; SC TAP: No; WI Air: Yes 64742-49-0 Naphtha (petroleum), hydrotreated light CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No 67-64-1 Acetone CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory, 4 Test; CA PROP.65: No; CA TAC, Title 8: Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: Part 5; NC TAP: No; NJ EHS: Yes - 0006; NY Part 597: Yes; PA HSL: Yes - E; SC TAP: No; WI Air: Yes 64741-88-4 Mineral oil CAA HAP,ODC: No; CWA NPDES: No; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: No; MA Oil/HazMat: No; MI CMR, Part 5: No; NC TAP: No; NJ EHS: No; NY Part 597: No; PA HSL: No; SC TAP: No; WI Air: No CAS # Hazardous Components (Chemical Name) International Regulatory Lists 64742-52-5 Mineral oil, petroleum distillates, hydrotreated heavy naphthenic Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 68476-86-8 Liquified petroleum gas, sweetened Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 64742-48-9 Hydrotreated heavy naphtha Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes MIRS MSDS, (c) A V Systems, Inc. Multi-region format 10/15/2014Revision: Page: 9 Chain & Cable Lube SAFETY DATA SHEET 05/05/2014Supersedes Revision: 79-20-9 Methyl acetate (Methyl ester of acetic acid} Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 64742-49-0 Naphtha (petroleum), hydrotreated light Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 67-64-1 Acetone Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes 64741-88-4 Mineral oil Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes European Community Risk and Safety Phrases: European Community Hazard Symbol codes: No data available. Section 16. Other Information No data available.Additional Information About This Product: Cyclo Industries, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Cyclo Industries, Inc. makes no representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, Cyclo Industries, Inc. will not be responsible for damages resulting from use of or reliance upon this information. Company Policy or Disclaimer: 10/15/2014Revision Date: MIRS MSDS, (c) A V Systems, Inc. Multi-region format