08/25/2015Revision: Page: 1 Air Brake Anti Freeze 32 fl. oz. SAFETY DATA SHEET 05/05/2014Supersedes Revision: C97Product Code: Air Brake Anti Freeze 32 fl. oz.Product Name: CYCLO INDUSTRIES, INC.Company Name: 902 SOUTH US HIGHWAY 1 JUPITER, FL 33477 First Aid EmergencyEmergency Contact: (800)752-7869 CHEMTREC (703) 527-3887 (800)424-9300 First Aid Emergency (Outside U.S.)Information: (312)906-6194 (800)843-7813 Phone Number: www.cyclo.comWeb site address: 1. Product and Company Identification This email address is being protected from spambots. You need JavaScript enabled to view it. address: 2. Hazards Identification P233: Keep container tightly closed. P210: Keep away from heat/sparks/open flames/hot surfaces - No smoking. P280: Wear protective gloves/protective clothing/eye protection/face protection. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P243: Take precautionary measures against static discharge. P242: Use only non-sparking tools. P260: Do not breathe dust/fume/gas/mist/vapours/spray. P270: Do not eat,drink or smoke when using product. P271: Use only outdoors or in a well-ventilated area. P264: Wash hands thoroughly after handling. GHS Precaution Phrases: P370+378: In case of fire, use alcohol foam, foam, dry chemical or carbon dioxide to extinguish. P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P363: Wash contaminated clothing before reuse. P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309+311: Call a POISON CENTER or doctor/physician if exposed or you feel unwell. GHS Response Phrases: P405: Store locked up.GHS Storage and Disposal H225: Highly flammable liquid and vapor. H331: Toxic if inhaled. H301: Toxic if swallowed. H311: Toxic in contact with skin. H370: Causes damage to organs. GHS Hazard Phrases: Flammable Liquids, Category 2 Acute Toxicity: Inhalation, Category 3 Acute Toxicity: Oral, Category 3 Acute Toxicity: Skin, Category 3 Specific Target Organ Toxicity (single exposure), Category 1 DangerGHS Signal Word: MIRS MSDS, (c) A V Systems, Inc. GHS format 08/25/2015Revision: Page: 2 Air Brake Anti Freeze 32 fl. oz. SAFETY DATA SHEET 05/05/2014Supersedes Revision: P501: Dispose of contents/container in accordance with local/regional/national/international regulation. P403+233: Store container tightly closed in well-ventilated place. Phrases: No data available.Potential Health Effects (Acute and Chronic): CAS # Hazardous Components (Chemical Name) 3. Composition/Information on Ingredients Concentration 67-56-1 Methanol 95.0 -100.0 % 4. First Aid Measures If swallowed, immediately call a physician/Poison Control Center. If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen. If in eyes, rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. In case of skin contact, wash with soap and water. Remove contaminated clothing and shoes, and launder before reuse. Call physician immediately if adverse reaction occurs. Emergency and First Aid Procedures: 5. Fire Fighting Measures Flash Pt: 52.00 F (11.1 C) Method Used: TAG Closed Cup Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Avoid water streams which may splash and spread flaming liquid. Water spray can be used to reduce the intensity of the flames and dilute spills to a non-flammable mixture. Vapor may cause flash fire. Methanol and water mixtures will burn unless very dilute. Mixtures with 25% or more Methanol are OSHA Class 1 Flammable Liquids. Fire Fighting Instructions: No data available.Flammable Properties and Hazards: Autoignition Pt: 475.00 F (246.1 C) Explosive Limits: LEL: 6% UEL: 36% Alcohol foam, foam, dry chemical, carbon dioxide.Suitable Extinguishing Media: Carbon dioxide. Carbon monoxide. Acrid smoke and irritating fumes.Hazardous Combustion Products: 6. Accidental Release Measures Wear appropriate protective clothing and equipment to prevent skin and eye contact. Avoid breathing vapor. When airborne exposure limits are exceeded use NIOSH approved respiratory protection equipment appropriate to the material and/or its components. Remove sources of ignition. Increase area ventilation. Stop release at source. Dike area and contain. Absorb spills on inert material such as perlite, vermiculite, sand or dirt. Place in double polyethylene bags. Isolate from other waste materials. Do not allow to enter sanitary drains, sewer or surface and subsurface waters. Steps To Be Taken In Case Material Is Released Or Spilled: 7. Handling and Storage Keep container tightly closed. Keep away from heat/sparks/open flames/hot surfaces - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary measures against static discharge. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Do not eat,drink or smoke when using product. Use only outdoors or in a well-ventilated area. Wash hands thoroughly after handling. Keep out of the reach of children. Precautions To Be Taken in Handling: MIRS MSDS, (c) A V Systems, Inc. GHS format 08/25/2015Revision: Page: 3 Air Brake Anti Freeze 32 fl. oz. SAFETY DATA SHEET 05/05/2014Supersedes Revision: Store locked up. Keep container closed when not in use. Keep away from heat and flame. Avoid extreme temperatures. Precautions To Be Taken in Storing: 8. Exposure Controls/Personal Protection OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits No data.PEL: 200 ppm TLV: 200 ppm STEL: 250 ppm 67-56-1 Methanol Appropriate respiratory protection shall be worn when applied engineering controls are not adequate to protect against inhalation exposure. Organic vapor cartridge respirators NOT recommended for methanol vapor exposures. Respiratory Equipment (Specify Type): Safety glasses with side shields.Eye Protection: Use chemical resistant gloves for prolonged skin contact.Protective Gloves: No data available.Other Protective Clothing: Use local exhaust. Eyewash stations. Showers.Engineering Controls (Ventilation etc.): 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: NE Boiling Point: 148.00 F (64.4 C) Flash Pt: 52.00 F (11.1 C) Method Used: TAG Closed Cup Explosive Limits: LEL: 6% UEL: 36% Vapor Pressure (vs. Air or mm Hg): 135@25C Vapor Density (vs. Air = 1): 1.11 Evaporation Rate: > 1 pH: ~ 7 Clear to light blue liquid. Mild alcohol odor.Appearance and Odor: Flammability (solid, gas): No data available. Specific Gravity (Water = 1): .791@60F Solubility in Water: Soluble Autoignition Pt: 475.00 F (246.1 C) Percent Volatile: > 98.0 % Viscosity: NE 10. Stability and Reactivity Avoid any source of ignition.Conditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Strong oxidizing agents. Chromic anhydride, lead perchlorate and perchloric acids.Incompatibility - Materials To Avoid: Carbon monoxide. Carbon dioxide. Acrid smoke with irritating fumes.Hazardous Decomposition or Byproducts: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: No data available.Conditions To Avoid - Hazardous Reactions: MIRS MSDS, (c) A V Systems, Inc. GHS format 08/25/2015Revision: Page: 4 Air Brake Anti Freeze 32 fl. oz. SAFETY DATA SHEET 05/05/2014Supersedes Revision: CAS # Hazardous Components (Chemical Name) NTP 11. Toxicological Information No data available.Toxicological Information: IARC ACGIH OSHA 67-56-1 Methanol n.a. n.a. n.a. n.a. No data available. 12. Ecological Information Dispose of contents/container in accordance with local/regional/national/international regulation. Waste Disposal Method: 13. Disposal Considerations 14. Transport Information Consumer CommodityDOT Proper Shipping Name: ORM-D ORM-DDOT Hazard Class: UN/NA Number: LAND TRANSPORT (US DOT): Methanol, Ltd QtyADR/RID Shipping Name: LAND TRANSPORT (European ADR/RID): 1230UN Number: IIPacking Group: 3 (6.1) - FLAMMABLE LIQUID, POISON Hazard Class: Methanol, Ltd QtyIMDG/IMO Shipping Name: MARINE TRANSPORT (IMDG/IMO): 1230UN Number: IIPacking Group: 3 (6.1) - FLAMMABLE LIQUID, POISON Hazard Class: 3,6.1IMDG Classification: IMDG MFAG Number: IMDG EMS Page: NoMarine Pollutant: CAS # Hazardous Components (Chemical Name) 15. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 67-56-1 Methanol No Yes 5000 LB Yes CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 67-56-1 Methanol CAA HAP,ODC: HAP; CWA NPDES: No; TSCA: Yes - Inventory; CA PROP.65: No; CA TAC, Title 8: TAC, Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: Part 5; NC TAP: Yes; NJ EHS: Yes - 1222; NY Part 597: Yes; PA HSL: Yes - E; SC TAP: Yes; WI Air: Yes CAS # Hazardous Components (Chemical Name) International Regulatory Lists 67-56-1 Methanol Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes MIRS MSDS, (c) A V Systems, Inc. GHS format 08/25/2015Revision: Page: 5 Air Brake Anti Freeze 32 fl. oz. SAFETY DATA SHEET 05/05/2014Supersedes Revision: 16. Other Information No data available.Additional Information About This Product: Hazard Rating System: Instability Special Hazard Health Flammability Cyclo Industries, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Cyclo Industries, Inc. makes no representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, Cyclo Industries, Inc. will not be responsible for damages resulting from use of or reliance upon this information. Company Policy or Disclaimer: 2 4 0 08/25/2015Revision Date: NFPA: MIRS MSDS, (c) A V Systems, Inc. GHS format