08/30/2013Revision: Page: 1 Air Brake Anti Freeze 1 Gal. SAFETY DATA SHEET 01/30/2012Supersedes Revision: according to Regulation (EC) No. 1907/2006 as amended by (EC) No. 1272/2008 C981.1 Product Code: Air Brake Anti Freeze 1 Gal. Product Name: CYCLO INDUSTRIES, INC.Company Name: 902 SOUTH US HIGHWAY 1 JUPITER, FL 33477 First Aid EmergencyEmergency Contact: (800)752-7869 CHEMTREC (703) 527-3887 (800)424-9300 First Aid Emergency (Outside U.S.)Information: (312)906-6194 (800)843-7813 Phone Number: www.cyclo.comWeb site address: Section 1. Identification of the Substance/Mixture and of the Company/Undertaking 1.3 Details of the Supplier of the Safety Data Sheet: 1.2 Relevant identified uses of the substance or mixture and uses advised against: 1.4 Emergency telephone number: Section 2. Hazards Identification Flammable Liquids, Category 2 Acute Toxicity: Inhalation, Category 3 Acute Toxicity: Oral, Category 3 Acute Toxicity: Skin, Category 3 Target Organ Systemic Toxicity (single exposure), Category 1 2.1 Classification of the Substance or Mixture: 2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP]: P233: Keep container tightly closed. P210: Keep away from heat/sparks/open flames/hot surfaces. P280: Wear protective gloves/protective clothing/eye protection/face protection. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof electrical/ventilating/lighting equipment. P243: Take precautionary measures against static discharge. P242: Use only non-sparking tools. P271: Use only outdoors or in a well-ventilated area. P261: Avoid breathing dust/fume/gas/mist/vapours/spray. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. GHS Precaution Phrases: P370+378: In case of fire, use alcohol foam, foam, dry chemical or carbon dioxide to extinguish. GHS Response Phrases: H225: Highly flammable liquid and vapor. H331: Toxic if inhaled. H301: Toxic if swallowed. H311: Toxic in contact with skin. H370: Causes damage to organs. GHS Hazard Phrases: 2.2 Label Elements: 2.2.1 Labeling according to Regulation (EC) No 1272/2008 [CLP]: DangerGHS Signal Word: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 08/30/2013Revision: Page: 2 Air Brake Anti Freeze 1 Gal. SAFETY DATA SHEET 01/30/2012Supersedes Revision: P303+361+353: IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skin with water/shower. P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P330: Rinse mouth. P305 +351: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER/doctor if you feel unwell. P501: Dispose of contents/container in accordance with local/regional/national/international regulation. P403+233: Store container tightly closed in well-ventilated place. GHS Storage and Disposal Phrases: 2.3 Adverse Human Health Effects and Symptoms: Hazard Rating System: Instability Special Hazard Health Flammability 2 4 0 CAS # Hazardous Components (Chemical Name)/ REACH Registration No. Section 3. Composition/Information on Ingredients Concentration EC No./ EC Index No. GHS Classification 67-56-1 Methanol 95.0 -100.0 % 200-659-6 603-001-00-X Flam. Liq. 2: H225 Acute Tox.(O) 3: H301 Acute Tox.(D) 3: H311 Acute Tox.(I) 3: H331 TOST (SE) 1: H370 Section 4. First Aid Measures If swallowed, immediately call a physician/Poison Control Center. If inhaled, remove to fresh air. If not breathing give artificial respiration preferably mouth-to-mouth. If breathing is difficult, give oxygen. In case of eye contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes. In case of skin contact, wash with soap and water. Remove contaminated clothing and shoes, and launder before reuse. Call physician immediately if adverse reaction occurs. Description of First Aid Measures: 4.1 5.1 5.2 Section 5. Fire Fighting Measures Flash Pt: 52.00 F (11.1 C) Method Used: TAG Closed Cup Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Avoid water streams which may splash and spread flaming liquid. Water spray can be used to reduce the intensity of the flames and dilute spills to a non-flammable mixture. Vapor may cause flash fire. Methanol and water mixtures will burn unless very dilute. Mixtures with 25% or more Methanol are OSHA Class 1 Flammable Liquids. Fire Fighting Instructions: Autoignition Pt: 475.00 F (246.1 C) Explosive Limits: LEL: 6% UEL: 36% Alcohol foam, foam, dry chemical, carbon dioxide.Suitable Extinguishing Media: No data available.Flammable Properties and Hazards: 5.3 MIRS MSDS, (c) A V Systems, Inc. Multi-region format 08/30/2013Revision: Page: 3 Air Brake Anti Freeze 1 Gal. SAFETY DATA SHEET 01/30/2012Supersedes Revision: 6.3 Section 6. Accidental Release Measures Wear appropriate protective clothing and equipment to prevent skin and eye contact. Avoid breathing vapor. When airborne exposure limits are exceeded use NIOSH approved respiratory protection equipment appropriate to the material and/or its components. Remove sources of ignition. Increase area ventilation. Stop release at source. Dike area and contain. Absorb spills on inert material such as perlite, vermiculite, sand or dirt. Place in double polyethylene bags. Isolate from other waste materials. Do not allow to enter sanitary drains, sewer or surface and subsurface waters. Methods and Material For Containment and Cleaning Up: 7.1 7.2 Section 7. Handling and Storage Avoid breathing vapors. If exposed to high vapor concentration, leave area at once. Avoid contact with skin and eyes. Use only in a well ventilated area. Keep away from food and smoking materials. Wash hands before eating and smoking. Keep out of the reach of children. Precautions To Be Taken in Handling: Keep container closed when not in use. Keep away from heat and flame. Avoid extreme temperatures. Precautions To Be Taken in Storing: Section 8. Exposure Controls/Personal Protection Britain EH40 France VLCAS # Partial Chemical Name Europe 8.1 Exposure Parameters: TWA: 266 mg/m3 (200 ppm) STEL: 333 mg/m3 (250 ppm) TWA: 260 mg/m3 (200 ppm) STEL: 1300 mg/m3 (1000 ppm) 67-56-1 Methanol TWA: 260 mg/m3 OSHA TWA ACGIH TWACAS # Partial Chemical Name Other Limits PEL: 200 ppm TLV: 200 ppm STEL: 250 ppm 67-56-1 Methanol No data. 8.2.1 Appropriate respiratory protection shall be worn when applied engineering controls are not adequate to protect against inhalation exposure. Organic vapor cartridge respirators NOT recommended for methanol vapor exposures. Respiratory Equipment (Specify Type): Safety glasses with side shields.Eye Protection: Use chemical resistant gloves for prolonged skin contact.Protective Gloves: No data available.Other Protective Clothing: Use local exhaust. Eyewash stations. Showers.Engineering Controls (Ventilation etc.): 8.2 Exposure Controls: 8.2.2 Personal protection equipment: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 08/30/2013Revision: Page: 4 Air Brake Anti Freeze 1 Gal. SAFETY DATA SHEET 01/30/2012Supersedes Revision: Section 9. Physical and Chemical Properties Physical States: [ ] Gas [ X ] Liquid [ ] Solid Melting Point: NE Boiling Point: 148.00 F (64.4 C) Flash Pt: 52.00 F (11.1 C) Method Used: TAG Closed Cup Explosive Limits: LEL: 6% UEL: 36% Vapor Pressure (vs. Air or mm Hg): 135@25C Vapor Density (vs. Air = 1): 1.11 Evaporation Rate: > 1 pH: ~ 7 Clear to light blue liquid. Mild alcohol odor.Appearance and Odor: 9.1 Information on Basic Physical and Chemical Properties Specific Gravity (Water = 1): .791@60F Solubility in Water: Soluble Autoignition Pt: 475.00 F (246.1 C) Viscosity: NE Percent Volatile: > 98.0 % 9.2 Other Information 10.4 10.5 10.6 10.1 10.2 10.3 Section 10. Stability and Reactivity Avoid any source of ignition.Conditions To Avoid - Instability: Unstable [ ] Stable [ X ]Stability: Strong oxidizing agents. Chromic anhydride, lead perchlorate and perchloric acids.Incompatibility - Materials To Avoid: Carbon monoxide. Carbon dioxide. Acrid smoke with irritating fumes.Hazardous Decomposition Or Byproducts: Will occur [ ] Will not occur [ X ]Possibility of Hazardous Reactions: No data available.Conditions To Avoid - Hazardous Reactions: No data available.Reactivity: MIRS MSDS, (c) A V Systems, Inc. Multi-region format 08/30/2013Revision: Page: 5 Air Brake Anti Freeze 1 Gal. SAFETY DATA SHEET 01/30/2012Supersedes Revision: 11.1 CAS # Hazardous Components (Chemical Name) NTP Section 11. Toxicological Information No data available.Information on Toxicological Effects: IARC ACGIH OSHA 67-56-1 Methanol n.a. n.a. n.a. n.a. Section 12. Ecological Information 13.1 Disposal should be made in accordance with federal, state and local regulations.Waste Disposal Method: Section 13. Disposal Considerations Section 14. Transport Information MethanolDOT Proper Shipping Name: 3 FLAMMABLE LIQUIDDOT Hazard Class: 1230UN/NA Number: IIPacking Group: 14.1 LAND TRANSPORT (US DOT): MethanolADR/RID Shipping Name: 14.1 LAND TRANSPORT (European ADR/RID): 1230UN Number: IIPacking Group: 3 (6.1) - FLAMMABLE LIQUID, POISON Hazard Class: MethanolIMDG/IMO Shipping Name: 14.2 MARINE TRANSPORT (IMDG/IMO): 1230UN Number: IIPacking Group: 3 - FLAMMABLE LIQUIDHazard Class: 3,6.1IMDG Classification: NoMarine Pollutant: CAS # Hazardous Components (Chemical Name) Section 15. Regulatory Information S. 302 (EHS) S. 304 RQ S. 313 (TRI) EPA SARA (Superfund Amendments and Reauthorization Act of 1986) Lists 67-56-1 Methanol No Yes 5000 LB Yes CAS # Hazardous Components (Chemical Name) Other US EPA or State Lists 67-56-1 Methanol CAA HAP,ODC: HAP; CWA NPDES: No; TSCA: Inventory; CA PROP.65: No; CA TAC, Title 8: TAC, Title 8; MA Oil/HazMat: Yes; MI CMR, Part 5: Part 5; NC TAP: Yes; NJ EHS: Yes - 1222; NY Part 597: Yes; PA HSL: Yes - E; SC TAP: Yes; WI Air: Yes CAS # Hazardous Components (Chemical Name) International Regulatory Lists 67-56-1 Methanol Canadian DSL: Yes; Canadian NDSL: No; Taiwan TCSCA: Yes MIRS MSDS, (c) A V Systems, Inc. Multi-region format 08/30/2013Revision: Page: 6 Air Brake Anti Freeze 1 Gal. SAFETY DATA SHEET 01/30/2012Supersedes Revision: Section 16. Other Information No data available.Additional Information About This Product: Cyclo Industries, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. Individuals receiving this information must exercise their independent judgment in determining its appropriateness for a particular purpose. Cyclo Industries, Inc. makes no representations or warranties, either expressed or implied, of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, Cyclo Industries, Inc. will not be responsible for damages resulting from use of or reliance upon this information. Company Policy or Disclaimer: 08/30/2013Revision Date: MIRS MSDS, (c) A V Systems, Inc. Multi-region format