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SF7-2_Starting_Fluid_50__Ether.pdf
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PREMIUM STARTING FLUID 50% ETHER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 09/07/2017 Revision date: 09/07/2017 Version: 1.0 Production After:6/1/2018 ? SECTION 1: Identification 1.1. Identification ? Product form : Mixture Product name : FVP STARTING FLUID 50% ETHER Product code : FVPSF7-2 1.2. Recommended use and restrictions on use Use of the substance/mixture : Starting fluid ? 1.3. Supplier Factory Motor Parts 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 (866) 387-3343 ? ? ? 1.4. Emergency telephone number Emergency number : INFOTRAC 1-800-535-5053 ? SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture ? GHS-US classification Flam. Aerosol 1 Press. Gas (Comp.) Skin Irrit. 2 STOT SE 3 Asp. Tox. 1 ? 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : ???? Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Extremely flammable aerosol Contains gas under pressure; may explode if heated Causes skin irritation May cause drowsiness or dizziness May be fatal if swallowed and enters airways Precautionary statements (GHS-US) : Keep away from heat, hot surfaces, open flames, sparks. - No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Avoid breathing dust, gas, fume, mist, spray, vapors Wash hands thoroughly after handling Use only outdoors or in a well-ventilated area Wear eye protection, face protection, protective clothing, protective gloves If swallowed: Immediately call a poison center/doctor Do NOT induce vomiting ? 09/07/2017 EN (English US) Page 1 FVP STARTING FLUID 50% ETHER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 09/07/2017 EN (English US) 2/8 ? ? ? If on skin: Wash with plenty of water Take off contaminated clothing and wash it before reuse If skin irritation occurs: Get medical advice/attention If inhaled: Remove person to fresh air and keep comfortable for breathing Call a poison center/doctor if you feel unwell Store in a well-ventilated place. Keep container tightly closed Store locked up Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation ? 2.3. Other hazards which do not result in classification No additional information available ? 2.4. Unknown acute toxicity (GHS US) Not applicable ? SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable ? 3.2. Mixtures ? Name Product identifier % Ethyl ether (CAS-No.) 60-29-7 50 - 60 Naphtha, petroleum, hydrotreated light (CAS-No.) 64742-49-0 40 - 50 Carbon dioxide (CAS-No.) 124-38-9 < 5 Distillates, petroleum, hydrotreated light naphthenic (CAS-No.) 64742-53-6 0.1 - 1 ? Hazardous constituents contained in Naphtha, petroleum, hydrotreated light (CAS-No.) 64742-49-0: ? Name Product identifier % n-Heptane (CAS-No.) 142-82-5 10 - 20 3-Methylhexane (CAS-No.) 589-34-4 <10 Methylcyclohexane (CAS-No.) 108-87-2 < 10 2-Methylhexane (CAS-No.) 591-76-4 < 10 2,3-Dimethylpentane (CAS-No.) 565-59-3 < 3 3-Ethylpentane (CAS-No.) 617-78-7 < 3 ? *Chemical name, CAS number and/or exact concentration have been withheld as a trade secret ? SECTION 4: First-aid measures 4.1. Description of first aid measures ? First-aid measures after inhalation : If inhaled and if breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. First-aid measures after skin contact : IF ON SKIN: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects (acute and delayed) ? Symptoms/effects after inhalation : May cause irritation to the respiratory tract. May cause drowsiness or dizziness. Symptoms/effects after skin contact : Causes skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/effects after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/effects after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. 4.3. Immediate medical attention and special treatment, if necessary Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). FVP STARTING FLUID 50% ETHER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 09/07/2017 EN (English US) 3/8 ? ? ? SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media ? Suitable extinguishing media : Carbon dioxide. Dry chemical. Foam. Water spray. Unsuitable extinguishing media : Do not use water jet. 5.2. Specific hazards arising from the chemical ? Fire hazard : Extremely flammable aerosol. Products of combustion may include, and are not limited to: oxides of carbon. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. Reactivity : No dangerous reactions known under normal conditions of use. 5.3. Special protective equipment and precautions for fire-fighters ? Firefighting instructions : DO NOT fight fire when fire reaches explosives. Evacuate area. Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Use water spray to keep fire-exposed containers cool. ? SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Eliminate every possible source of ignition. Use only non-sparking tools. Use special care to avoid static electric charges. ? 6.1.1. For non-emergency personnel No additional information available ? 6.1.2. For emergency responders No additional information available ? 6.2. Environmental precautions Prevent entry to sewers and public waters. ? 6.3. Methods and material for containment and cleaning up ? For containment : Eliminate all ignition sources if safe to do so. Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Use only non-sparking tools. Provide ventilation. 6.4. Reference to other sections For further information refer to section 8: "Exposure controls/personal protection" ? SECTION 7: Handling and storage 7.1. Precautions for safe handling ? Additional hazards when processed : Pressurized container: Do not pierce or burn, even after use. Hazardous waste due to potential risk of explosion. Precautions for safe handling : Keep away from sources of ignition - No smoking. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Hygiene measures : Wash contaminated clothing before reuse. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities ? Technical measures : Proper grounding procedures to avoid static electricity should be followed. Storage conditions : Keep out of the reach of children. Do not expose to temperatures exceeding 50 ?C/ 122 ?F. Keep in fireproof place. Store away from direct sunlight or other heat sources. Store in a well- ventilated place. ? SECTION 8: Exposure controls/personal protection 8.1. Control parameters ? Ethyl ether (60-29-7) ACGIH ACGIH TWA (ppm) 400 ppm FVP STARTING FLUID 50% ETHER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 09/07/2017 EN (English US) 4/8 ? ? ? Ethyl ether (60-29-7) ACGIH ACGIH STEL (ppm) 500 ppm OSHA OSHA PEL (TWA) (mg/m?) 1200 mg/m? OSHA OSHA PEL (TWA) (ppm) 400 ppm IDLH US IDLH (ppm) 1900 ppm (10% LEL) Naphtha, petroleum, hydrotreated light (64742-49-0) Not applicable n-Heptane (142-82-5) ACGIH ACGIH TWA (ppm) 400 ppm ACGIH ACGIH STEL (ppm) 500 ppm OSHA OSHA PEL (TWA) (mg/m?) 2000 mg/m? OSHA OSHA PEL (TWA) (ppm) 500 ppm IDLH US IDLH (ppm) 750 ppm NIOSH NIOSH REL (TWA) (mg/m?) 350 mg/m? NIOSH NIOSH REL (TWA) (ppm) 85 ppm NIOSH NIOSH REL (ceiling) (mg/m?) 1800 mg/m? NIOSH NIOSH REL (ceiling) (ppm) 440 ppm 3-Methylhexane (589-34-4) ACGIH ACGIH TWA (ppm) 400 ppm ACGIH ACGIH STEL (ppm) 500 ppm Methylcyclohexane (108-87-2) ACGIH ACGIH TWA (ppm) 400 ppm OSHA OSHA PEL (TWA) (mg/m?) 2000 mg/m? OSHA OSHA PEL (TWA) (ppm) 500 ppm IDLH US IDLH (ppm) 1200 ppm (10% LEL) NIOSH NIOSH REL (TWA) (mg/m?) 1600 mg/m? NIOSH NIOSH REL (TWA) (ppm) 400 ppm 2-Methylhexane (591-76-4) ACGIH ACGIH TWA (ppm) 400 ppm ACGIH ACGIH STEL (ppm) 500 ppm Carbon dioxide (124-38-9) ACGIH ACGIH TWA (ppm) 5000 ppm ACGIH ACGIH STEL (ppm) 30000 ppm OSHA OSHA PEL (TWA) (mg/m?) 9000 mg/m? OSHA OSHA PEL (TWA) (ppm) 5000 ppm IDLH US IDLH (ppm) 40000 ppm NIOSH NIOSH REL (TWA) (mg/m?) 9000 mg/m? NIOSH NIOSH REL (TWA) (ppm) 5000 ppm NIOSH NIOSH REL (STEL) (mg/m?) 54000 mg/m? NIOSH NIOSH REL (STEL) (ppm) 30000 ppm 2,3-Dimethylpentane (565-59-3) ACGIH ACGIH TWA (ppm) 400 ppm ACGIH ACGIH STEL (ppm) 500 ppm 3-Ethylpentane (617-78-7) Not applicable FVP STARTING FLUID 50% ETHER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 09/07/2017 EN (English US) 5/8 ? ? ? Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) Not applicable ? 8.2. Appropriate engineering controls ? Appropriate engineering controls : Ensure good ventilation of the work station. Environmental exposure controls : Avoid release to the environment. ? 8.3. Individual protection measures/Personal protective equipment ? Hand protection: ? Wear suitable gloves resistant to chemical penetration ? Eye protection: ? Safety glasses or goggles are recommended when using product. ? Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. ? Other information: ? Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or smoke when using this product. ? SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties ? Physical state : Liquid Appearance : Aerosol Color : Clear Odor : Solvent Odor threshold : No data available pH : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : No data available Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : Extremely flammable aerosol Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : No data available Specific gravity / density : 0.72 Solubility : No data available Partition coefficient n-octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosion limits : No data available Explosive properties : No data available Oxidizing properties : No data available 9.2. Other information No additional information available FVP STARTING FLUID 50% ETHER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 09/07/2017 EN (English US) 6/8 ? ? ? SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reactions known under normal conditions of use. ? 10.2. Chemical stability Extremely flammable aerosol. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. Extreme risk of explosion by shock, friction, fire or other sources of ignition. ? 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. ? 10.4. Conditions to avoid Heat. Sparks. Open flame. Direct sunlight. Incompatible materials. ? 10.5. Incompatible materials Strong oxidizing agents. Strong reducing agents. ? 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon. ? SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified ? Ethyl ether (60-29-7) LD50 oral rat 1215 mg/kg ATE US (oral) 1215 mg/kg body weight Naphtha, petroleum, hydrotreated light (64742-49-0) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 3160 mg/kg LC50 inhalation rat 73680 ppm/4h ATE US (gases) 73680 ppmV/4h n-Heptane (142-82-5) LD50 dermal rabbit 3000 mg/kg LC50 inhalation rat 103 g/m? (Exposure time: 4 h) ATE US (dermal) 3000 mg/kg body weight ATE US (vapors) 103 mg/l/4h ATE US (dust, mist) 103 mg/l/4h ? Methylcyclohexane (108-87-2) LD50 oral rat > 3200 mg/kg LD50 dermal rabbit > 86700 mg/kg ? Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat 2180 mg/m? (Exposure time: 4 h) ? Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity ? single exposure : May cause drowsiness or dizziness. ? Specific target organ toxicity ? repeated exposure ? : Not classified Aspiration hazard : May be fatal if swallowed and enters airways. ? Symptoms/effects after inhalation : May cause irritation to the respiratory tract. May cause drowsiness or dizziness. FVP STARTING FLUID 50% ETHER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 09/07/2017 EN (English US) 7/8 ? ? ? Symptoms/effects after skin contact : Causes skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/effects after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/effects after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. Other information : Likely routes of exposure: ingestion, inhalation, skin and eye. ? SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. ? Ethyl ether (60-29-7) LC50 fish 1 2560 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) LC50 fish 2 > 10000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) ? n-Heptane (142-82-5) LC50 fish 1 375 mg/l (Exposure time: 96 h - Species: Cichlid fish) ? Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) LC50 fish 1 > 5000 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) EC50 Daphnia 1 > 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna) ? 12.2. Persistence and degradability 5300 ? Persistence and degradability Not established. ? 12.3. Bioaccumulative potential 5300 ? Bioaccumulative potential Not established. Ethyl ether (60-29-7) Partition coefficient n-octanol/water 0.82 (at 23 ?C) ? n-Heptane (142-82-5) Partition coefficient n-octanol/water 4.66 ? Carbon dioxide (124-38-9) BCF fish 1 (no bioaccumulation) ? 12.4. Mobility in soil No additional information available ? 12.5. Other adverse effects Effect on the global warming : No known effects from this product. Other information : No other effects known. ? SECTION 13: Disposal considerations 13.1. Disposal methods ? Product/Packaging disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Container under pressure. Do not drill or burn even after use. Additional information : Flammable vapors may accumulate in the container. ? SECTION 14: Transport information ? Department of Transportation (DOT) In accordance with DOT UN-No.(DOT) : UN1950 Proper Shipping Name (DOT) : Aerosols Class (DOT) : 2.1 - Class 2.1 - Flammable gas 49 CFR 173.115 FVP STARTING FLUID 50% ETHER Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 09/07/2017 EN (English US) 8/8 ? ? ? Hazard labels (DOT) : ?? ?? ? ? SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory ? 15.2. International regulations No additional information available ? 15.3. US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm ? SECTION 16: Other information ? Date of issue : 09/07/2017 Revision date : 09/07/2017 Other information : None. Prepared by : Nexreg Compliance Inc. www.Nexreg.com ? NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. NFPA fire hazard : 4 - Materials that rapidly or completely vaporize at atmospheric pressure and normal ambient temperature or that are readily dispersed in air and burn readily. NFPA reactivity : 0 - Material that in themselves are normally stable, even under fire conditions. ?? SDS US (GHS HazCom 2012)_NEXREG_NEW ? Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use.