General Motors Corporation September, 1999 Material Safety Data Sheet Page 133 SECTION 01: CHEMICAL PRODUCT 81 COMPANY ID TlONSOURCES,CHECKAREAWlTHGASOETECTOR.MOVELEAKlNGCANS TRADENAME: ACDELCOCHOKECLEANER OUTDOORSANDEMPTYlNTOSUlTABLECONTAlNERBYDEPRESSlNG X21A VALVEBUllON.SMALLLIQUIDSPlLLSMAYBETAKEN UPWITH 12337814 ABSORBENTMATERIAL,SUCHASEARTHORFLOORDRY. MSDSSIGNED BYNAME:ANDREWB.WHlTLOCK SECTION 07: HANDLING AND STORAGE SAFEUSECATEGORYANDDESCRIPTION:02-SOLVENTS-FLASHPOINT:<100F PRECAUTlONSTOBETAKENINHANDLlNGANDSTORAGE:KEEPCONTAlNERS MSDSCREATE DATE:198501-01 CAPPEDWHENNOTINUSE.DONOTSTOREORHANDLENEARHEAT, LASTUPDATED DATE:1989-06-30 SPARKS,FLAME,OR STRONG OXIDIZERSALWAYSMAINTAINADEQUATE VENTILATION. MANUFACTURER'SID(MID):000539666 MANUFACTURER'SNAME:GUARDSMANPRODUCTSINC SECTlON7-OTHERINFORMATION: MANUFACTURER'SEMERGENCYPHONENUMBER/TEXT:US616-924-3950 AVOlDBREATHlNGVAPORSORMISTS;PROLONGEDORREPEATEDSKlNCDN- MANUFACTURER'SMAILINGADDRESS: TACT. ALSOSEEGMBA#514360&556365 SECTlON08:EXPOSURECONTROLS-PROTECTION 411 N.DARLlNG EYEPROTECTION:FACESHlELDORSAFETYGLASSESRECOMMENOED. FREMONT Ml 49412 RESPlRATORYPROTECTION:USESELFCONTAlNEDBREATHlNGAPPARATUSOR us EFFECTlVENIOSH/MSHAAPPROVEDRESPlRATORWHENEVEREXPOSURE LEVELSEXCEEDESTABLISHEDSTANDARDS. SECTION 02: COMPOSITION & INGREDIENT INFO PERSONALPROTECTlVEEQUIPMENT:NONEREQUlREDINNORMALUSE. CAS# FORMULATION W/V CHEMICALNAME WORK/HYGIENIC PRACTICES:BASlCGOODHOUSEKEEPING. 000067630 R 5.0000/20.0000% W ISOPROPYLALCOHOL SECTlON8-OTHERINFORMATION: 000078933 R 1.0000/15.0000% W 2-BUTANONE NONEGENERALLYREQUIRED. 000108883 R 65.0000/80.0000% W TOLUENE 068476868 R 5.0000/20.0000% W Petroleum gases,liquefied,sweete PRDTECTlVEGLOVES(SPECIFYlYPE):CHEMlCALRESISTANT. fled SECTION 09: PHYSICAL & CHEMICAL PROPERTIES THRESHOLDLlMlTVALUE:(ACGIH)2-BUTANONE#78933:200PPM.lSOPROPYL BOILING POlNTTEMPS:81.00C/178.00F ALCOHOL#67630:400PPM.TOLUENE#108883:100PPM.LlQUlFlED BOILING POINTTEXT: 178F(INITIAL BOILING POINT) PETROLEUMPROPELLANT#68476868:800PPM. SPECIFIC GRAVlTYVALUES:=0.8500 PERMISSIBLE EXPOSURE LIMIT:(DSHA)P-BUTANONE#78933:200PPM.ISO- SPECIFIC GRAVITYTEXT: q 0.85 PROPYLALCOHOL#67630:400PPM.TOLUENE#108883:200PPM.LIQUI- FlEDPETROLEUMPROPELLANT#68476868:1000PPM. VAPORDENSlTYVALUES:>l.OOOO VAPORDENSlTYTEXT:>l SECTION 03: HAZARDS IDENTIFICATION VAPORPRESSURETEXT:ND(ND=NOTDETERMINED) PRIMARYENTRYROUTEINDICATORS: PERCENTVOLATILEBYVOLUME:100.0000 SKIN PRlMARYENTRYROUTElNDlCATOR=Y PERCENTVOLATlLEBYVOLUMETEX-klOO EYEPRlMARYENTRYROUTElNDlCATOR=N SOLUBILITYINWATERTEXT: SLIGHT.WATER REACTIVE:NO lNHALATlONPRlMARYENTRYROUTElNDlCATOR=Y PHOFPRODUCTINSOLUTlONWlTHWATE~EXT:NA(NOTAPPLICABLE) lNGESTlONPRlMARYENTRYROUTElNDlCATOR=N APPEARANCE:WATERWHITEWlTHLACQUERTHlNNERODOR PRlMARYROUTESOFENTRYTEXT:ORAL;INHALATION;SKlNABSORPTION. EFFECTSOFOVERD(POSURE:HEADACHE,DIZZINESS,NAUSEA;SKlNANDEYE SECTION 10: STABILITY & REACTIVITY IRRITATION;MAYBEFATALIFINGESTED.CHRONlCHAZARDS:REPORTS STABlLl-lYINDICATOR:Y HAVEASSOClATEDREPEATEDANDPROLONGEDOCCUPATlONALOVERD(- STABILITY-CONDlTlONSTOAVOID:HEAT,SPARKS,OPEN FLAME. POSURETOSOLVENTSWITHPERMANENTBRAINDAMAGEANDNERVOUS STABILITY-TEXT:YES SYSTEMDAMAGE.lNTENTlONALMlSUSEBYDELlBERATELYCONCENTRAT- INGANDlNHALlNGHECONTENTSMAYBEHARMFULORFATAL.ASAPRE- lNCOMPATlBLEMATERIALS:STRONGOXlDlZERSLlKECHLORlNEORCONCEN- CAUTION,EXPOSURETOLIQUIDS,VAPORS,MlSTSORFUMESSHOULDBE TRATED02. MINIMIZED. HAZARDOUSDECOMPOSlTlONPRODUCTS:VARlOUSOXlDESOFCARBON. SECTION 04: FIRST AID MEASURES HAZARDOUS POLYMERIZATION INDICATOR:N EMERGENCYFlRSTAIDPROCEDURES-GENERAL:EYECDNTACT:FLUSHWlTH HAZARDOUSPOLYMERlZATlON-CONDlTlONSTOAVOID:NONEKNOWN. RUNNlNGWATERFOR15MINUTES,HOLOlNGLIDOPENTOEXPOSEAS HAZARDOUSPOLYMERIZATIONTEXTINO MUCHSURFACEASPOSSIBLE.CONTACTPHYSlClANIMMEDIATELYSKlN SECTION 13: DISPOSAL CONSIDERATIONS CONTACT:REMOVECONTAMlNATEDCLOTHlNGANDSHOES.WASH EXPOSEDAREAWlTHMlLDSOAPANDWATER,APPLYSKlNCREAMFOR WASTEDlSPOSALMETHOD:COMPLYWlTHALLSTATE,FEDERALANDLOCAL REGULATIONS. IRRITATION.INHALATION:IFOVERCOME BYAPOR,REMOVETO FRESH AIR ATONCE.APPLYARTlFlClALRESPlRATlONIFNECESSARY,CONTACTPHYSI- SECTION 14:TtiANSPORT INFORMATION CIAN IMMEDIATELY. INGESTION:DO NOTlNDUCEVOMITING,CONTACT SHlPPlNGNAME:CONSUMERCOMMODlTY PHYSICIAN IMMEDIATELY. HAZARDCLASS:V:ORM-DCONSUMERCOMMODITY SECTION 05: FIRE-FIGHTING MEASURES SECTION 16: OTHER INFORMATION EXllNGUlSHlNGMEDIA:FOAM,DRYCHEMICAL,C02. SPECIALFIREFIGHTING PROCEDURES:USESELFCONTAlNED BREATHING LOCALEXHAUST:ADEQUATETOMAlNTAlNLEVELBELOWESTABLISHED.RATE: >GOFPM. APPARATUSWATERIS NOTSUITABLEASAN EXTINGUISHING MEDIA,BUT MAYBEUSEFULFORCOOLINGNEARBYCONTAINERS. SPECIAL PROTECTlON(MECHANICAL):NO UNUSUALFlREANDD(PLOSIONHAZARDS:AEROSOLCONTAlNERSMAYBURST WHENEXPOSEDTOTEMPERATURESINEXCESSOF120F.FLAMEEXfEN- SION:60 INCHES.FLASHBACK:YES. AUTOIGNITION TEMPERATURE:ND. FLASHPOlNTTEXTzEXTREMELYFLAMMABLEAEROSOL SECTION 06: ACCIDENTAL RELEASE MEASURES SPlLLORLEAKPROCEDURES:**DANGERII LEAKINGAEROSOLSAREAN EXlREMEFlREANDEXPLOSlONHAZARD.*'REMOVEALLPOSSlBLElGNl-