SAFETY DATA SHEET Issue Date 01-Jan-2009 Revision Date 28-May-2015 Version 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : FJC R134A CHARGE WITH STOP LEAK Product code : 528 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Oil Charge 1.3. Details of the supplier of the safety data sheet Supplier Address FJC 101 Commercial Drive Mooresville, NC 28115 1.4. Emergency telephone number Emergency number : INFOTRAC 1-352-323-3500 (International)1-800-535-5053 (North America) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Liquefied gas H280 Repr. 1B H360 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS04 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H280 - Contains gas under pressure; may explode if heated H360 - May damage fertility or the unborn child Precautionary statements (GHS-US) : P201 - Obtain special instructions P202 - Do not handle until all safety precautions have been read and understood P280 - Wear protective gloves,protective clothing,eye protection,face protection P308+P313 - If exposed or concerned: Get medical advice/attention P405 - Store locked up P410+P403 - Protect from sunlight. Store in a well-ventilated place P501 - Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. P251 - Pressurized container: Do not pierce or burn, even after use P410+P412 - Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/11/2014 EN (English US) 2/11 2.3. Other hazards Other hazards not contributing to the classification : Contains gas under pressure; may explode if heated. Intentional misuse and inhalation abuse may cause cardiac or central nervous systems effects. Warning. May Cause frostbite in contact with skin. May Cause frostbite in contact with skin. (Liquid form can be ejected if the aerosol can is not held upright during use.) Warning. 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Classification (GHS-US) Benzyl Butyl Phthalate (CAS No) 85-68-7 < 1 Repr. 1B, H360 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest. First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : May damage fertility or the unborn child. Symptoms/injuries after inhalation : Coughing. Irritation of the respiratory tract. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Rapid respiration. Slight irritation. Symptoms/injuries after skin contact : Causes skin irritation. Blisters. May cause moderate irritation. Red skin. Symptoms/injuries after eye contact : Causes eye irritation. Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/11/2014 EN (English US) 3/11 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Other information : NFPA Aerosol Level 1. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Remove ignition sources. 6.1.1. For non-emergency personnel Protective equipment : Gloves. Safety glasses. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Methods for cleaning up : Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Pressurized container: Do not pierce or burn, even after use. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Do not handle until all safety precautions have been read and understood. Obtain special instructions. Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Do not eat, drink or smoke when using this product. Wash affected areas thoroughly after handling. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage area : Store in a well-ventilated place. 7.3. Specific end use(s) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/11/2014 EN (English US) 4/11 Follow Label Directions. SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Local exhaust venilation, vent hoods. Personal protective equipment : Gloves. Safety glasses. Avoid all unnecessary exposure. Materials for protective clothing : neoprene. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas Appearance : Liquid. Color : Red. Odor : Characteristic. Petroleum-like odour. Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/11/2014 EN (English US) 5/11 Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : 0.965 Solubility : Insoluble in water. Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information VOC content : 0 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Toxic fume. . Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/11/2014 EN (English US) 6/11 1,1,1,2-Tetrafluoroethane (811-97-2) LC50 inhalation rat (mg/l) > 2000 mg/l/4h (Rat; Literature study) LC50 inhalation rat (ppm) > 359300 ppm/4h (Rat; Literature study) Benzyl Butyl Phthalate (85-68-7) LD50 oral rat 2330 mg/kg (Rat) LD50 dermal rat 6700 mg/kg (Rat) LD50 dermal rabbit > 10000 mg/kg (Rabbit) LC50 inhalation rat (mg/l) > 6.7 mg/l/4h (Rat) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Benzyl Butyl Phthalate (85-68-7) IARC group 3 Reproductive toxicity : May damage fertility or the unborn child. Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : Coughing. Irritation of the respiratory tract. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Rapid respiration. Slight irritation. Symptoms/injuries after skin contact : Causes skin irritation. Blisters. May cause moderate irritation. Red skin. Symptoms/injuries after eye contact : Causes eye irritation. Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue. Symptoms/injuries after ingestion : May be harmful if swallowed and enters airways. May be fatal if swallowed and enters airways. SECTION 12: Ecological information 12.1. Toxicity Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/11/2014 EN (English US) 7/11 1,1,1,2-Tetrafluoroethane (811-97-2) LC50 fish 1 450 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 980 mg/l (48 h; Daphnia magna) Benzyl Butyl Phthalate (85-68-7) LC50 fish 1 1.5 mg/l (96 h; Pimephales promelas; Measured concentration) EC50 Daphnia 1 1.6 - 1.8 mg/l (48 h; Daphnia magna) EC50 other aquatic organisms 1 0.64 mg/l (72 h; Diatomeae; Growth rate) LC50 fish 2 0.82 mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Measured concentration) EC50 Daphnia 2 0.97 mg/l (48 h; Daphnia magna) Threshold limit algae 1 0.20 mg/l (72 h; Diatomeae; Growth rate) Threshold limit algae 2 0.31 mg/l (72 h; Scenedesmus subspicatus; Growth rate) 12.2. Persistence and degradability FJC R134A CHARGE WITH STOP LEAK Persistence and degradability Not established. 1,1,1,2-Tetrafluoroethane (811-97-2) Persistence and degradability Not readily biodegradable in water. Polyol Ester (Proprietary) Persistence and degradability Not established. Ester (Proprietary) Persistence and degradability Not established. Proprietary Inhibitor Package (Proprietary) Persistence and degradability Not established. Benzyl Butyl Phthalate (85-68-7) Persistence and degradability Readily biodegradable in water. Forming sediments in water. Biodegradability in soil: no data available. Adsorbs into the soil. 12.3. Bioaccumulative potential FJC R134A CHARGE WITH STOP LEAK Bioaccumulative potential Not established. 1,1,1,2-Tetrafluoroethane (811-97-2) BCF other aquatic organisms 1 5 - 58 (Estimated value) Log Pow 1.06 (OECD 107: Partition Coefficient (n-octanol/water): Shake Flask Method) Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/11/2014 EN (English US) 8/11 Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Polyol Ester (Proprietary) Bioaccumulative potential Not established. Ester (Proprietary) Bioaccumulative potential Not established. Proprietary Inhibitor Package (Proprietary) Bioaccumulative potential Not established. Benzyl Butyl Phthalate (85-68-7) BCF fish 1 188 (408 h; Lepomis macrochirus) BCF fish 2 663 (504 h; Lepomis macrochirus) BCF other aquatic organisms 1 26 - 270 Log Pow 3.57 - 5.8 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to appropriate waste disposal facility, in accordance with local, regional, national, international regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / US DOT (ground): RID / IMDG / IATA / ADN UN1078, Refrigerant gases, n.o.s., 2.2, Limited Quantity ICAO/IATA (air): UN1078, Refrigerant gases, n.o.s., 2.2 , Limited Quantity IMO/IMDG (water): UN1078, Refrigerant gases, n.o.s. (1,1,1,2-Tetrafluoroethane, Petroleum Distillates), 2.2 Special Provisions: Not applicable T50 - this subchapter. When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of 14.2. UN proper shipping name Proper Shipping Name (DOT) : Refrigerant gases, n.o.s. Department of Transportation (DOT) Hazard : Classes 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115 Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/11/2014 EN (English US) 9/11 Hazard labels (DOT) : 2.2 - Non-flammable gas DOT Symbols : G - Identifies PSN requiring a technical name DOT Special Provisions (49 CFR 172.102) : T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter. DOT Packaging Exceptions (49 CFR 173.xxx) : 306 DOT Packaging Non Bulk (49 CFR 173.xxx) : 304 DOT Packaging Bulk (49 CFR 173.xxx) : 314;315 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available Transport by sea DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. Air transport DOT Quantity Limitations Passenger aircraft/rail : (49 CFR 173.27) 75 kg DOT Quantity Limitations Cargo aircraft only (49 : CFR 175.75) 150 kg SECTION 15: Regulatory information 15.1. US Federal regulations FJC R134A CHARGE WITH STOP LEAK SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Sudden release of pressure hazard 1,1,1,2-Tetrafluoroethane (811-97-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Sudden release of pressure hazard Polyol Ester (Proprietary) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA FJC R134A CHARGE WITH STOP LEAK Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/11/2014 EN (English US) 10/11 WHMIS Classification Class A - Compressed Gas 1,1,1,2-Tetrafluoroethane (811-97-2) WHMIS Classification Class A - Compressed Gas Polyol Ester (Proprietary) WHMIS Classification Uncontrolled product according to WHMIS classification criteria EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations Polyol Ester (Proprietary) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory 15.3. US State regulations No additional information available SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 03/11/2014 EN (English US) 11/11 ------ ------ ------ ------ NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 0 - Materials that will not burn. NFPA reactivity : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 0 Minimal Hazard Physical : 1 Slight Hazard Personal Protection : B SDS US (GHS HazCom 2012) - TCC Issue Date 01-Jan-2009 Revision Date 28-May-2015 Revision Note New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet Liquefied gas Gases under pressure Liquefied gas Repr. 1B Reproductive toxicity Category 1B H280 Contains gas under pressure; may explode if heated H360 May damage fertility or the unborn child