SAFETY DATA SHEET 1. Identification Product number 1000009597 Product identifier DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) Company information BROTHERS RESEARCH Corp. 2245 AIR PARK DRIVE BURLINGTON, NC 27216 United States Emergency telephone US 1-866-836-8855 Emergency telephone outside US 1-952-852-4646 Version # 01 Recommended use COATING Recommended restrictions None known. 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Not classified.Health hazards Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Category 2Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Response Wash hands after handling. Storage Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 106-97-8Butane 1 - 2.5 74-98-6Propane 1 - 2.5 1336-21-6Ammonium Hydroxide Other components below reportable levels 90 - 100 0.1 - 1 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 1 / 9 Product name: DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) Product #: 1000009597 Version #: 01 Issue date: 06-29-2015 SDS US 4. First-aid measures Inhalation Move to fresh air. If breathing is difficult, give oxygen. Get medical attention if symptoms persist. Skin contact Immediately take off all contaminated clothing. Get medical attention if irritation develops or persists. Eye contact Get medical attention if irritation develops or persists. Ingestion In the unlikely event of swallowing contact a physician or poison control center. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Do not use mouth-to-mouth method if victim ingested the substance. If ingestion of a large amount does occur, seek medical attention. No need for first aid is anticipated if material is swallowed. Most important symptoms/effects, acute and delayed Direct contact with eyes may cause temporary irritation. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Symptoms may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water. Unsuitable extinguishing media None known. Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions In the event of fire and/or explosion do not breathe fumes. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Withdraw immediately in case of rising sound from venting safety devices or any discoloration of tanks due to fire. Move containers from fire area if you can do it without risk. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible, withdraw from area and let fire burn. Cool containers with flooding quantities of water until well after fire is out. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move container from fire area if it can be done without risk. Cool containers exposed to flames with water until well after the fire is out. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Ventilate closed spaces before entering. Keep out of low areas. Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stay upwind. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Prevent entry into waterways, sewers, basements or confined areas. Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Collect spillage. Clean contaminated surface thoroughly. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. This material and its container must be disposed of as hazardous waste. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 2 / 9 Product name: DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) Product #: 1000009597 Version #: 01 Issue date: 06-29-2015 SDS US 7. Handling and storage Precautions for safe handling Vapors may form explosive mixtures with air. May be ignited by open flame. Do not handle or store near an open flame, heat or other sources of ignition. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Ground and bond containers when transferring material. Do not re-use empty containers. Use only with adequate ventilation. Do not breathe gas/fumes/vapor/spray. Observe good industrial hygiene practices. Wash thoroughly after handling. Handle and open container with care. Do not empty into drains. Conditions for safe storage, including any incompatibilities Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 1 Aerosol (NFPA 30B) 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 1800 mg/m3Propane (CAS 74-98-6) 1000 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 1000 ppmButane (CAS 106-97-8) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 1900 mg/m3Butane (CAS 106-97-8) 800 ppm TWA 1800 mg/m3Propane (CAS 74-98-6) 1000 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Ensure adequate ventilation, especially in confined areas. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Hand protection Not normally needed. Other Not normally needed. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Compressed liquefied gas. Physical state Liquid. Form Aerosol. Color White. Odor Ammoniacal. Odor threshold Not available. pH 10 - 11 estimated Melting point/freezing point Not available. 3 / 9 Product name: DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) Product #: 1000009597 Version #: 01 Issue date: 06-29-2015 SDS US Initial boiling point and boiling range Not available. Flash point -156.0 ?F (-104.4 ?C) estimated estimated Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 50 - 60 psig @ 70F estimated Vapor density Not available. Relative density 0.967 g/cm3 estimated Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Density 0.47 g/cm3 estimated Heat of combustion 1.75 kJ/g estimated Heat of combustion (NFPA 30B) 1.75 kJ/g estimated Percent volatile 52 % estimated Specific gravity 0.967 estimated VOC (Weight %) 4 % estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Stable at normal conditions. Possibility of hazardous reactions Hazardous polymerization does not occur. Conditions to avoid Heat, flames and sparks. Avoid temperatures exceeding the flash point. Incompatible materials None known. Hazardous decomposition products May include oxides of nitrogen. May include oxides of phosphorus. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation No adverse effects due to inhalation are expected. Skin contact Not available. Eye contact Direct contact with eyes may cause temporary irritation. Symptoms related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity 4 / 9 Product name: DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) Product #: 1000009597 Version #: 01 Issue date: 06-29-2015 SDS US Test ResultsProduct Species DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) (CAS Mixture) LD50 Rat Dermal Acute 4252 mg/kg LC50 Rat Inhalation 16450 mg/l/4h LD50 Rat Oral Test ResultsComponents Species Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l Propane (CAS 74-98-6) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l 658 mg/l/4h * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Not expected to be hazardous by OSHA criteria. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory or skin sensitization Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity Not expected to be hazardous by OSHA criteria. Not expected to be hazardous by WHMIS criteria. Carcinogenicity Not expected to be hazardous by WHMIS criteria. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity Not expected to be hazardous by OSHA criteria. Not expected to be hazardous by WHMIS criteria. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not likely, due to the form of the product. Further information This product has no known adverse effect on human health. 12. Ecological information Ecotoxicity LC50: 833 mg/L, Fish, 96.00 Hours EC50: 68.75 mg/L, Daphnia, 48.00 Hours Toxic to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected. Product Test ResultsSpecies DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) (CAS Mixture) Aquatic EC50Crustacea 68.75 mg/L, 48 HoursDaphnia 5 / 9 Product name: DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) Product #: 1000009597 Version #: 01 Issue date: 06-29-2015 SDS US Product Test ResultsSpecies LC50Fish 833 mg/L, 96 HoursFish Components Test ResultsSpecies Ammonium Hydroxide (CAS 1336-21-6) Aquatic EC50Crustacea 0.66 mg/L, 48 HoursDaphnia * Estimates for product may be based on additional component data not shown. LC50Fish 15 mg/l, 96 hoursWestern mosquitofish (Gambusia affinis) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) Butane 2.89 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Consult authorities before disposal. Contents under pressure. Dispose of this material and its container at hazardous or special waste collection point. Do not puncture, incinerate or crush. This material and its container must be disposed of as hazardous waste. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950UN number Aerosols, flammableUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk NoneLabel(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulk This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN1950UN number Aerosols, flammableUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 6 / 9 Product name: DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) Product #: 1000009597 Version #: 01 Issue date: 06-29-2015 SDS US 2.1Label(s) Not applicable.Packing group YesEnvironmental hazards 10LERG Code Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special precautions for user Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only LTD QTYPackaging Exceptions IMDG UN1950UN number AEROSOLSUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group YesMarine pollutant Environmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling. Special precautions for user LTD QTYPackaging Exceptions Not applicable.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 7 / 9 Product name: DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) Product #: 1000009597 Version #: 01 Issue date: 06-29-2015 SDS US Marine pollutant General information IMDG Regulated Marine Pollutant. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Ammonium Hydroxide (CAS 1336-21-6) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. US state regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US. Massachusetts RTK - Substance List Ammonium Hydroxide (CAS 1336-21-6) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act Ammonium Hydroxide (CAS 1336-21-6) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. Pennsylvania Worker and Community Right-to-Know Law Ammonium Hydroxide (CAS 1336-21-6) Butane (CAS 106-97-8) Propane (CAS 74-98-6) 8 / 9 Product name: DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) Product #: 1000009597 Version #: 01 Issue date: 06-29-2015 SDS US US. Rhode Island RTK Ammonium Hydroxide (CAS 1336-21-6) Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) YesJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 06-29-2015 Version # 01 Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision Information Product and Company Identification: Alternate Trade Names 9 / 9 Product name: DURAGLOSS 261 TIRE GLOSS (AEROSOL FOAM) Product #: 1000009597 Version #: 01 Issue date: 06-29-2015 SDS US