401, DURAGLOSS ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 05/28/2015 09/22/2015 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : 401, DURAGLOSS ALL PURPOSE CLEANER Product code : PART# 401, 403, 4035 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Brothers Research Corporation 2245 Airpark Drive Burlington, NC 27216 T 336-229-6480 1.4. Emergency telephone number Emergency number : 800-424-9300 Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin Irrit. 2 H315 Eye Dam. 1 H318 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS05 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H315 - Causes skin irritation H318 - Causes serious eye damage Precautionary statements (GHS-US) : P264 - Wash ... thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - If on skin: Wash with plenty of water/? P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER, a doctor P321 - Specific treatment (see ... on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture 401, DURAGLOSS ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/22/2015 EN (English US) 2/8 Name Product identifier % Classification (GHS-US) disodium metasilicate (CAS No) 6834-92-0 2 - 3 Skin Corr. 1A, H314 STOT SE 3, H335 butyl glycolether (CAS No) 111-76-2 1 - 2 Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. Specific treatment (see ... on this label). First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. 401, DURAGLOSS ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/22/2015 EN (English US) 3/8 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Hygiene measures : Wash ... thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 401, DURAGLOSS ALL PURPOSE CLEANER ACGIH Not applicable OSHA Not applicable butyl glycolether (111-76-2) ACGIH ACGIH TWA (ppm) 20 ppm ACGIH ACGIH STEL (ppm) 20 ppm OSHA Not applicable disodium metasilicate (6834-92-0) ACGIH Not applicable OSHA Not applicable 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear Green Liquid. Color : Green Odor : Sweet Odor threshold : No data available pH : 11 - 12 Relative evaporation rate (butyl acetate=1) : No data available Melting point : No Data Freezing point : No data available Boiling point : 212 ?F Flash point : > 200 ?F Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available 401, DURAGLOSS ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/22/2015 EN (English US) 4/8 Vapor pressure : 140 @130.0 F Relative vapor density at 20 ?C : No data available Relative density : H20=1 <1 Specific gravity / density : < 1 Solubility : Soluble in water. Water: Solubility in water of component(s) of the mixture : ? : ? : > 18 g/100ml Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified butyl glycolether (111-76-2) LD50 oral rat 1746 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Experimental value) LD50 dermal rat > 2000 mg/kg body weight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity) LC50 inhalation rat (mg/l) 2.2 mg/l/4h (Rat; Experimental value) LC50 inhalation rat (ppm) 450 ppm/4h (Rat; Experimental value) ATE US (oral) 1746.000 mg/kg body weight ATE US (dermal) 1100.000 mg/kg body weight ATE US (gases) 450.000 ppmV/4h ATE US (vapors) 2.200 mg/l/4h ATE US (dust, mist) 2.200 mg/l/4h disodium metasilicate (6834-92-0) LD50 dermal rat > 5000 mg/kg body weight (Rat; Read-across; OECD 402: Acute Dermal Toxicity) Skin corrosion/irritation : Causes skin irritation. pH: 11 - 12 Serious eye damage/irritation : Causes serious eye damage. pH: 11 - 12 Respiratory or skin sensitization : Not classified 401, DURAGLOSS ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/22/2015 EN (English US) 5/8 Germ cell mutagenicity : Not classified Carcinogenicity : Not classified butyl glycolether (111-76-2) IARC group 3 - Not classifiable Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye damage. SECTION 12: Ecological information 12.1. Toxicity butyl glycolether (111-76-2) LC50 fish 1 1474 ppm (96 h; Oncorhynchus mykiss) EC50 Daphnia 1 1550 mg/l (48 h; Daphnia magna) Threshold limit algae 1 911 mg/l (72 h; Pseudokirchneriella subcapitata) Threshold limit algae 2 88 mg/l (72 h; Pseudokirchneriella subcapitata) disodium metasilicate (6834-92-0) LC50 fish 1 210 mg/l (96 h; Brachydanio rerio) EC50 Daphnia 1 216 mg/l (96 h; Daphnia magna; GLP) LC50 fish 2 2320 mg/l (96 h; Gambusia affinis) EC50 Daphnia 2 632 mg/l (96 h; Lymnaea sp.) Threshold limit algae 1 207 mg/l (72 h; Scenedesmus subspicatus; GLP) 12.2. Persistence and degradability 401, DURAGLOSS ALL PURPOSE CLEANER Persistence and degradability Not established. butyl glycolether (111-76-2) Persistence and degradability Readily biodegradable in water. Low potential for adsorption in soil. Photooxidation in the air. disodium metasilicate (6834-92-0) Persistence and degradability Biodegradability: not applicable. No (test)data on mobility of the substance available. Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable ThOD Not applicable BOD (% of ThOD) Not applicable 12.3. Bioaccumulative potential 401, DURAGLOSS ALL PURPOSE CLEANER Bioaccumulative potential Not established. butyl glycolether (111-76-2) Log Pow 0.81 (Test data; 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). disodium metasilicate (6834-92-0) Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil 401, DURAGLOSS ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/22/2015 EN (English US) 6/8 butyl glycolether (111-76-2) Surface tension 0.065 N/m (20 ?C; 003) 12.5. Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector?s sorting instructions. Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Transport document description : UN3253 Disodium trioxosilicate, 8, III UN-No.(DOT) : UN3253 Proper Shipping Name (DOT) : Disodium trioxosilicate Transport hazard class(es) (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136 Hazard labels (DOT) : 8 - Corrosive Packing group (DOT) : III - Minor Danger DOT Special Provisions (49 CFR 172.102) : IB8 - Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). IP3 - Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner. T1 - 1.5 178.274(d)(2) Normal............. 178.275(d)(2) TP33 - The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. DOT Packaging Exceptions (49 CFR 173.xxx) : 154 DOT Packaging Non Bulk (49 CFR 173.xxx) : 213 DOT Packaging Bulk (49 CFR 173.xxx) : 240 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 25 kg DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 100 kg DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. DOT Vessel Stowage Other : 52 - Stow ??separated from?? acids Additional information Other information : No supplementary information available. 401, DURAGLOSS ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/22/2015 EN (English US) 7/8 ADR No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations 401, DURAGLOSS ALL PURPOSE CLEANER Listed on the United States TSCA (Toxic Substances Control Act) inventory butyl glycolether (111-76-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory disodium metasilicate (6834-92-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations \ \ 15.3. US State regulations butyl glycolether (111-76-2) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Revision date : 05/28/2015 Other information : None. 401, DURAGLOSS ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/22/2015 EN (English US) 8/8 Full text of H-phrases: ------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4 ------ Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Flam. Liq. 4 Flammable liquids Category 4 ------ Skin Corr. 1A Skin corrosion/irritation Category 1A ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H227 Combustible liquid ------ H302 Harmful if swallowed ------ H312 Harmful in contact with skin ------ H314 Causes severe skin burns and eye damage ------ H315 Causes skin irritation ------ H318 Causes serious eye damage ------ H319 Causes serious eye irritation ------ H332 Harmful if inhaled ------ H335 May cause respiratory irritation SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product