430, DURAGLOSS HD TRUCK & EQUIPMENT WASH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 05/28/2015 09/23/2015 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : 430, DURAGLOSS HD TRUCK & EQUIPMENT WASH Product code : 430 32oz, 431 Gal, 435 5Gal, 4330 30Gal, 4355 55Gal 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Brothers Research Corporation 2245 Airpark Drive Burlington, NC 27216 T 336-229-6480 1.4. Emergency telephone number Emergency number : 800-424-9300 Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin Corr. 1A H314 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS05 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H314 - Causes severe skin burns and eye damage Precautionary statements (GHS-US) : P260 - Do not breathe dust/fume/gas/mist/vapors/spray P264 - Wash ... thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a poison center/doctor/? P321 - Specific treatment (see ... on this label) P363 - Wash contaminated clothing before reuse P405 - Store locked up P501 - Dispose of contents/container to ... 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 430, DURAGLOSS HD TRUCK & EQUIPMENT WASH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/23/2015 EN (English US) 2/6 3.2. Mixture Name Product identifier % Classification (GHS-US) disodium metasilicate (CAS No) 6834-92-0 5 - 9 Skin Corr. 1A, H314 STOT SE 3, H335 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove the victim into fresh air. If not breathing give artificial respiration. Get medical advice/attention. Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove clothing while washing. Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Move victim away from exposure and into fresh air. Get medical advice/attention. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Do not induce vomiting. Call a physician or poison control center immediately. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Foam. Dry chemical powder. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Non combustible. Not flammable. 5.3. Advice for firefighters Firefighting instructions : Water can be used to keep exposed containers cool, to protect;. Wear normal protective equipment (full bunker gear) and possitive-pressure self contained breathing appartus. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Absorb spill on vermiculite floor absorbent or other absorbent material. 6.1.1. For non-emergency personnel Protective equipment : Protective clothing. Protective goggles. Emergency procedures : If runoff ocurrs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, material to containers for disposal. Close container tightly and dispose of properly. Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Notify authorities if product enters sewers or public waters. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Transfer contaminated absorbent, soil and othe material to containers for disposal. Close container tightly and dispose of properly. 430, DURAGLOSS HD TRUCK & EQUIPMENT WASH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/23/2015 EN (English US) 3/6 Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Containers may be hazardous when emptied. Since emptied containers retain product residues, all hazard precautions given in the data sheet should be observed. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep away from heat, sparks, and flames. Emptied containers may retain product residues. Precautions apply to emptied containers. Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 430, DURAGLOSS HD TRUCK & EQUIPMENT WASH ACGIH Not applicable OSHA Not applicable disodium metasilicate (6834-92-0) ACGIH Not applicable OSHA Not applicable 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Purple. Color : Purple Odor : No data available Odor threshold : No data available pH : 11 - 12 Relative evaporation rate (butyl acetate=1) : No data available Melting point : ? ?F No Data Freezing point : No data available Boiling point : 212 ?F Flash point : > 200 ?F Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 140 @ 130.0 F 430, DURAGLOSS HD TRUCK & EQUIPMENT WASH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/23/2015 EN (English US) 4/6 Relative vapor density at 20 ?C : No data available Relative density : H20= <1 Solubility : Soluble in water. Water: Solubility in water of component(s) of the mixture : ? : > 18 g/100ml Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable under normal conditions. Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products Carbon dioxide. Carbon monoxide. fume. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified disodium metasilicate (6834-92-0) LD50 dermal rat > 5000 mg/kg body weight (Rat; Read-across; OECD 402: Acute Dermal Toxicity) Skin corrosion/irritation : Causes severe skin burns and eye damage. pH: 11 - 12 Serious eye damage/irritation : Not classified pH: 11 - 12 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. 430, DURAGLOSS HD TRUCK & EQUIPMENT WASH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/23/2015 EN (English US) 5/6 SECTION 12: Ecological information 12.1. Toxicity disodium metasilicate (6834-92-0) LC50 fish 1 210 mg/l (96 h; Brachydanio rerio) EC50 Daphnia 1 216 mg/l (96 h; Daphnia magna; GLP) LC50 fish 2 2320 mg/l (96 h; Gambusia affinis) EC50 Daphnia 2 632 mg/l (96 h; Lymnaea sp.) Threshold limit algae 1 207 mg/l (72 h; Scenedesmus subspicatus; GLP) 12.2. Persistence and degradability 430, DURAGLOSS HD TRUCK & EQUIPMENT WASH Persistence and degradability Not established. disodium metasilicate (6834-92-0) Persistence and degradability Biodegradability: not applicable. No (test)data on mobility of the substance available. Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable ThOD Not applicable BOD (% of ThOD) Not applicable 12.3. Bioaccumulative potential 430, DURAGLOSS HD TRUCK & EQUIPMENT WASH Bioaccumulative potential Not established. disodium metasilicate (6834-92-0) Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available Air transport No additional information available 430, DURAGLOSS HD TRUCK & EQUIPMENT WASH Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 09/23/2015 EN (English US) 6/6 SECTION 15: Regulatory information 15.1. US Federal regulations 430, DURAGLOSS HD TRUCK & EQUIPMENT WASH Not listed on the United States TSCA (Toxic Substances Control Act) inventory disodium metasilicate (6834-92-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations \ 15.3. US State regulations SECTION 16: Other information Revision date : 05/28/2015 Other information : None. Full text of H-phrases: ------ Skin Corr. 1A Skin corrosion/irritation Category 1A ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H314 Causes severe skin burns and eye damage ------ H335 May cause respiratory irritation SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product