SAFETY DATA SHEET 1. Identification Product number 1000009323 Product identifier DURAGLOSS 451 FABRIC AND CARPET CLEANER Company information BROTHERS RESEARCH Corp. 2245 AIR PARK DRIVE BURLINGTON, NC 27216 United States Emergency telephone US 1-866-836-8855 Emergency telephone outside US 1-952-852-4646 Version # 01 Recommended use Cleaner Recommended restrictions None known. 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Category 2Serious eye damage/eye irritationHealth hazards Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Causes serious eye irritation. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Wash thoroughly after handling. Wear eye/face protection. Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Storage Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 106-97-8Butane 2.5 - 10 112-34-5Diethylene Glycol Monobutyl Ether 2.5 - 10 68439-46-3Alcohols, C9-11, ethoxylated 1 - 2.5 74-98-6Propane Other components below reportable levels 90 - 100 1 - 2.5 #: This substance has workplace exposure limit(s). *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 1 / 9 Product name: DURAGLOSS 451 FABRIC AND CARPET CLEANER Product #: 1000009323 Version #: 01 Issue date: 06-29-2015 SDS US 4. First-aid measures Inhalation If symptoms develop move victim to fresh air. Get medical attention if symptoms persist. Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician or poison control center immediately. Ingestion Rinse mouth. Most important symptoms/effects, acute and delayed Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into waterways, sewer, basements or confined areas. Following product recovery, flush area with water. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Avoid contact with eyes. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid release to the environment. Observe good industrial hygiene practices. 2 / 9 Product name: DURAGLOSS 451 FABRIC AND CARPET CLEANER Product #: 1000009323 Version #: 01 Issue date: 06-29-2015 SDS US Conditions for safe storage, including any incompatibilities Level 1 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the SDS). Level 1 Aerosol (NFPA 30B) 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 1800 mg/m3Propane (CAS 74-98-6) 1000 ppm US. ACGIH Threshold Limit Values ValueComponents FormType STEL 1000 ppmButane (CAS 106-97-8) TWA 10 ppm Inhalable fraction and vapor. Diethylene Glycol Monobutyl Ether (CAS 112-34-5) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 1900 mg/m3Butane (CAS 106-97-8) 800 ppm TWA 1800 mg/m3Propane (CAS 74-98-6) 1000 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Individual protection measures, such as personal protective equipment Eye/face protection If contact is likely, safety glasses with side shields are recommended. Hand protection Wear appropriate chemical resistant gloves. Skin protection Other Not available. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Cloudy. Physical state Gas. Form Aerosol. Color Pale yellow Colorless. Odor Mint-like. Odor threshold Not available. pH 10.3 - 11.3 estimated Melting point/freezing point Not available. Initial boiling point and boiling range 212 ?F (100 ?C) estimated Flash point -156.0 ?F (-104.4 ?C) Propellant estimated 3 / 9 Product name: DURAGLOSS 451 FABRIC AND CARPET CLEANER Product #: 1000009323 Version #: 01 Issue date: 06-29-2015 SDS US Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure 60 - 80 @ 70F estimated Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Specific gravity 0.958 - 1.058 estimated estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Hazardous polymerization does not occur. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Fire or intense heat may cause violent rupture of packages. Incompatible materials Strong oxidizing agents. Hazardous decomposition products No hazardous decomposition products are known. 11. Toxicological information Information on likely routes of exposure Ingestion Expected to be a low ingestion hazard. Inhalation Prolonged inhalation may be harmful. Skin contact Causes mild skin irritation. Eye contact Causes serious eye irritation. Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Information on toxicological effects Acute toxicity Expected to be a low hazard for usual industrial or commercial handling by trained personnel. Test ResultsProduct Species DURAGLOSS 451 FABRIC AND CARPET CLEANER (CAS Mixture) LD50 Rat Dermal Acute 35029 mg/kg LC50 Rat Inhalation 682 mg/l/4h 4 / 9 Product name: DURAGLOSS 451 FABRIC AND CARPET CLEANER Product #: 1000009323 Version #: 01 Issue date: 06-29-2015 SDS US Test ResultsProduct Species LD50 Rat Oral Test ResultsComponents Species Butane (CAS 106-97-8) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l Diethylene Glycol Monobutyl Ether (CAS 112-34-5) LD50 Guinea pig Dermal Acute 2 ml/kg, 2 Days Rabbit 2764 mg/kg, 24 Hours LD100 Rabbit Oral 4000 mg/kg LD50 Guinea pig 2000 mg/kg Mouse 2410 mg/kg Rabbit 2500 - 3000 mg/kg Rat 3306 mg/kg Propane (CAS 74-98-6) LC50 Mouse Inhalation Acute 1237 mg/l, 120 Minutes 52 %, 120 Minutes Rat 1355 mg/l 658 mg/l/4h * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes mild skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity - single exposure Not available. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity Harmful to aquatic life with long lasting effects. 5 / 9 Product name: DURAGLOSS 451 FABRIC AND CARPET CLEANER Product #: 1000009323 Version #: 01 Issue date: 06-29-2015 SDS US Product Test ResultsSpecies DURAGLOSS 451 FABRIC AND CARPET CLEANER (CAS Mixture) Aquatic IC50Algae 141 mg/L, 72 HoursAlgae EC50Crustacea 19687 mg/L, 48 HoursDaphnia LC50Fish 1007 mg/L, 96 HoursFish Components Test ResultsSpecies Alcohols, C9-11, ethoxylated (CAS 68439-46-3) Aquatic EC50Crustacea 2.9 - 8.5 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 6 - 12 mg/l, 96 hoursFathead minnow (Pimephales promelas) * Estimates for product may be based on additional component data not shown. Diethylene Glycol Monobutyl Ether (CAS 112-34-5) Aquatic LC50Fish 1300 mg/l, 96 hoursBluegill (Lepomis macrochirus) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) Butane 2.89 Diethylene Glycol Monobutyl Ether 0.56 Propane 2.36 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Waste from residues / unused products Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. 14. Transport information DOT UN1950UN number Aerosols, flammableUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulk 6 / 9 Product name: DURAGLOSS 451 FABRIC AND CARPET CLEANER Product #: 1000009323 Version #: 01 Issue date: 06-29-2015 SDS US This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity. Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20 and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently. IATA UN1950UN number Aerosols, flammableUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group No.Environmental hazards 10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only LTD QTYPackaging Exceptions IMDG UN1950UN number AEROSOLSUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group No.Marine pollutant Environmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user LTD QTYPackaging Exceptions Not applicable.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code DOT IATA; IMDG 7 / 9 Product name: DURAGLOSS 451 FABRIC AND CARPET CLEANER Product #: 1000009323 Version #: 01 Issue date: 06-29-2015 SDS US 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous chemical No SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Butane (CAS 106-97-8) Propane (CAS 74-98-6) Safe Drinking Water Act (SDWA) Not regulated. US state regulations US. Massachusetts RTK - Substance List Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. New Jersey Worker and Community Right-to-Know Act Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. Pennsylvania Worker and Community Right-to-Know Law Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. Rhode Island RTK Butane (CAS 106-97-8) Propane (CAS 74-98-6) US. California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) 8 / 9 Product name: DURAGLOSS 451 FABRIC AND CARPET CLEANER Product #: 1000009323 Version #: 01 Issue date: 06-29-2015 SDS US Country(s) or region Inventory name On inventory (yes/no)* NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 06-29-2015 Version # 01 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision Information Product and Company Identification: Alternate Trade Names 9 / 9 Product name: DURAGLOSS 451 FABRIC AND CARPET CLEANER Product #: 1000009323 Version #: 01 Issue date: 06-29-2015 SDS US