461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 05/28/2015 05/18/2017 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : 461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE Product code : 461 32oz, 462 Gal 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Brothers Research Corporation 2245 Airpark Drive Burlington, NC 27216 T 336-229-6480 1.4. Emergency telephone number Emergency number : 800-424-9300 Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Eye Irrit. 2A H319 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H319 - Causes serious eye irritation Precautionary statements (GHS-US) : P264 - Wash face, hands, hands, forearms and face thoroughly after handling P280 - Wear eye protection, face protection, face shield, protective clothing, protective gloves P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture 461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/18/2017 EN (English) 2/6 Name Product identifier % GHS-US classification pentasodium triphosphate (CAS No) 7758-29-4 1 - 3 Not classified Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove the victim into fresh air. If not breathing give artificial respiration. Get immediate medical advice/attention. Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash skin with plenty of water. First-aid measures after eye contact : Move victim away from exposure and into fresh air. Rinse immediately with plenty of water for 15 minutes. Get medical advice/attention. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. Rinse eyes with water as a precaution. First-aid measures after ingestion : Do not induce vomiting. Call a physician or poison control center immediately. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Dry chemical powder. Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Non-flammable. Explosion hazard : Not applicable. Reactivity : No data available. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Complete protective clothing. Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Absorb spill on vermiculite floor absorbent or other absorbent material. 6.1.1. For non-emergency personnel Protective equipment : Protective clothing. Protective goggles. Gloves. Emergency procedures : Stop spill at source, prevent from spreading. If runoff ocurrs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, material to containers for disposal. Close container tightly and dispose of properly. Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/18/2017 EN (English) 3/6 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Wear personal protective equipment. Avoid contact with food. Wash hands after use. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep only in the original container in a cool, well ventilated place away from : Store in a well-ventilated place. Keep container closed when not in use. Keep cool. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE ACGIH Not applicable OSHA Not applicable pentasodium triphosphate (7758-29-4) ACGIH Not applicable OSHA Not applicable 8.2. Exposure controls Appropriate engineering controls : Ensure good ventilation of the work station. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Environmental exposure controls : Avoid release to the environment. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear Liquid. Colour : Clear Liquid Odour : Citrus Orange Odour threshold : No data available pH : 9 Relative evaporation rate (butylacetate=1) : No data available Melting point : No Data 461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/18/2017 EN (English) 4/6 Freezing point : No data available Boiling point : 212 ?F Flash point : > 200 ?F Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : 140 @ 130.0 F Relative vapour density at 20 ?C : No data available Relative density : 1 Solubility : Soluble in water. Water: Solubility in water of component(s) of the mixture : ? pentasodium triphosphate: 15 g/100ml Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidising properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No data available. 10.2. Chemical stability Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified pentasodium triphosphate (7758-29-4) LD50 oral rat > 2000 mg/kg (Rat) LD50 dermal rabbit > 4640 mg/kg (Rabbit) Skin corrosion/irritation : Not classified pH: 9 Serious eye damage/irritation : Causes serious eye irritation. pH: 9 Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified 461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/18/2017 EN (English) 5/6 Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. pentasodium triphosphate (7758-29-4) LC50 fish 1 1650 mg/l (LC50; 48 h) EC50 Daphnia 1 1089 mg/l (EC50; 505 h) 12.2. Persistence and degradability 461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE Persistence and degradability Not established. pentasodium triphosphate (7758-29-4) Persistence and degradability Biodegradability: not applicable. Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable ThOD Not applicable 12.3. Bioaccumulative potential 461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE Bioaccumulative potential Not established. pentasodium triphosphate (7758-29-4) Bioaccumulative potential Not bioaccumulative. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available 461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/18/2017 EN (English) 6/6 Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations 461, DURAGLOSS ULTIMATE ORANGE CLEANER CONCENTRATE Not listed on the United States TSCA (Toxic Substances Control Act) inventory pentasodium triphosphate (7758-29-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Not listed on the United States SARA Section 313 RQ (Reportable quantity, section 304 of EPA's List of Lists) 5000 lb 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.2.2. National regulations \ 15.3. US State regulations pentasodium triphosphate (7758-29-4) U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Revision date : 05/28/2015 Other information : None. Full text of H-phrases: ------ Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A ------ H319 Causes serious eye irritation SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product