505, DURAGLOSS WATER SPOT REMOVER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 05/28/2015 05/26/2016 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : 505, DURAGLOSS WATER SPOT REMOVER Product code : Part# 505 22oz, 506 Gal 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Brothers Research Corporation 2245 Airpark Drive Burlington, NC 27216 T 336-229-6480 1.4. Emergency telephone number Emergency number : 800-424-9300 Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Eye Irrit. 2A H319 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H319 - Causes serious eye irritation Precautionary statements (GHS-US) : P264 - Wash ... thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture 505, DURAGLOSS WATER SPOT REMOVER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/26/2016 EN (English US) 2/8 Name Product identifier % Classification (GHS-US) 1-propanol (CAS No) 71-23-8 1 - 2 Flam. Liq. 2, H225 Eye Dam. 1, H318 STOT SE 3, H336 butyl glycolether (CAS No) 111-76-2 0.5 - 1 Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove the victim into fresh air. If not breathing give artificial respiration. Get immediate medical advice/attention. Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Move victim away from exposure and into fresh air. Rinse immediately with plenty of water for 15 minutes. If eye irritation persists: Get medical advice/attention. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Do not induce vomiting. Call a physician or poison control center immediately. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Alcohol-resistant foam. Carbon dioxide. Dry chemical powder. Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Firefighting instructions : Water can be used to keep exposed containers cool, to protect;. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire- fighting water from entering environment. Protection during firefighting : Complete protective clothing. Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Absorb spill on vermiculite floor absorbent or other absorbent material. 6.1.1. For non-emergency personnel Protective equipment : Protective goggles. Protective clothing. Emergency procedures : Stop spill at source, prevent from spreading. No open flames, no sparks, and no smoking. Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Use personal protective equipment as required. Safety glasses. Protective gloves. Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 505, DURAGLOSS WATER SPOT REMOVER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/26/2016 EN (English US) 3/8 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Containers of this material may be hazardous when empited. All hazard precautions give should be observed. Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Containers may be hazardous when emptied. Since emptied containers retain product residues, all hazard precautions given in the data sheet should be observed. All 5 gallon and larger metal containers hsould be grounded or bonded when material is transferred. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep away from heat, sparks, and flames. Emptied containers may retain product residues. Precautions apply to emptied containers. Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 505, DURAGLOSS WATER SPOT REMOVER ACGIH Not applicable OSHA Not applicable DNEL DNEL ? 1-propanol (71-23-8) ACGIH ACGIH TWA (ppm) 100 ppm ACGIH ACGIH STEL (ppm) 100 ppm ACGIH Remark (ACGIH) Eye & URT irr OSHA OSHA PEL (TWA) (mg/m?) 500 mg/m? OSHA OSHA PEL (TWA) (ppm) 200 ppm butyl glycolether (111-76-2) ACGIH ACGIH TWA (ppm) 20 ppm ACGIH ACGIH STEL (ppm) 20 ppm OSHA Not applicable 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. 505, DURAGLOSS WATER SPOT REMOVER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/26/2016 EN (English US) 4/8 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Light Blue Liquid. Color : Blue Odor : Sweet Odor threshold : No data available pH : 3 - 4 Relative evaporation rate (butyl acetate=1) : No data available Melting point : No Data Freezing point : No data available Boiling point : 180 ?F @ 760 mmHg Flash point : > 160 ?F Auto-ignition temperature : NA Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 33 .0 mmHg @ 68.0 F Relative vapor density at 20 ?C : No data available Relative density : 1 @ 60.0 F Solubility : Water: > 0.01 Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable under normal conditions. Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Acids. Oxidizing agent. Strong acids. Strong bases. 10.6. Hazardous decomposition products None Expected. fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 1-propanol (71-23-8) LD50 oral rat > 2000 mg/kg (Rat) LD50 dermal rabbit 4049 mg/kg (Rabbit) LC50 inhalation rat (mg/l) 9.8 mg/l/4h (Rat) 505, DURAGLOSS WATER SPOT REMOVER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/26/2016 EN (English US) 5/8 1-propanol (71-23-8) ATE US (dermal) 4049.000 mg/kg body weight ATE US (vapors) 9.800 mg/l/4h ATE US (dust, mist) 9.800 mg/l/4h butyl glycolether (111-76-2) LD50 oral rat 1746 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Experimental value) LD50 dermal rat > 2000 mg/kg body weight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity) LC50 inhalation rat (mg/l) 2.2 mg/l/4h (Rat; Experimental value) LC50 inhalation rat (ppm) 450 ppm/4h (Rat; Experimental value) ATE US (oral) 1746.000 mg/kg body weight ATE US (dermal) 1100.000 mg/kg body weight ATE US (gases) 450.000 ppmV/4h ATE US (vapors) 2.200 mg/l/4h ATE US (dust, mist) 2.200 mg/l/4h Skin corrosion/irritation : Not classified pH: 3 - 4 Serious eye damage/irritation : Causes serious eye irritation. pH: 3 - 4 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified butyl glycolether (111-76-2) IARC group 3 - Not classifiable Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity 1-propanol (71-23-8) LC50 fish 1 3200 mg/l 48 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 4415 mg/l (24 h; Daphnia magna) EC50 other aquatic organisms 1 4168 mg/l (48 h; Protozoa) LC50 fish 2 4480 mg/l (96 h; Pimephales promelas) EC50 Daphnia 2 3644 mg/l (48 h; Daphnia magna) TLM fish 1 200 - 500,Gobio gobio TLM other aquatic organisms 1 100 - 1000,96 h Threshold limit algae 1 2000 mg/l (Selenastrum capricornutum) Threshold limit algae 2 3100 mg/l (168 h; Scenedesmus quadricauda) butyl glycolether (111-76-2) LC50 fish 1 1474 ppm (96 h; Oncorhynchus mykiss) EC50 Daphnia 1 1550 mg/l (48 h; Daphnia magna) Threshold limit algae 1 911 mg/l (72 h; Pseudokirchneriella subcapitata) Threshold limit algae 2 88 mg/l (72 h; Pseudokirchneriella subcapitata) 12.2. Persistence and degradability 505, DURAGLOSS WATER SPOT REMOVER Persistence and degradability Not established. 505, DURAGLOSS WATER SPOT REMOVER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/26/2016 EN (English US) 6/8 1-propanol (71-23-8) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biodegradable in the soil under anaerobic conditions. Biochemical oxygen demand (BOD) 0.47 - 1.63 g O?/g substance Chemical oxygen demand (COD) 2.23 g O?/g substance ThOD 2.4 g O?/g substance BOD (% of ThOD) 0.20 - 0.44 % ThOD butyl glycolether (111-76-2) Persistence and degradability Readily biodegradable in water. Low potential for adsorption in soil. Photooxidation in the air. 12.3. Bioaccumulative potential 505, DURAGLOSS WATER SPOT REMOVER Bioaccumulative potential Not established. 1-propanol (71-23-8) Log Pow 0.25 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). butyl glycolether (111-76-2) Log Pow 0.81 (Test data; 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil 1-propanol (71-23-8) Surface tension 0.024 N/m (20 ?C) butyl glycolether (111-76-2) Surface tension 0.065 N/m (20 ?C; 003) 12.5. Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available Air transport No additional information available 505, DURAGLOSS WATER SPOT REMOVER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/26/2016 EN (English US) 7/8 SECTION 15: Regulatory information 15.1. US Federal regulations 505, DURAGLOSS WATER SPOT REMOVER Not listed on the United States TSCA (Toxic Substances Control Act) inventory 1-propanol (71-23-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory butyl glycolether (111-76-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.2.2. National regulations \ \ 15.3. US State regulations 1-propanol (71-23-8) U.S. - New Jersey - Right to Know Hazardous Substance List butyl glycolether (111-76-2) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Revision date : 05/28/2015 Other information : None. Full text of H-phrases: ------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4 ------ Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Flam. Liq. 2 Flammable liquids Category 2 ------ Flam. Liq. 4 Flammable liquids Category 4 ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H225 Highly flammable liquid and vapor ------ H227 Combustible liquid ------ H302 Harmful if swallowed ------ H312 Harmful in contact with skin ------ H315 Causes skin irritation ------ H318 Causes serious eye damage ------ H319 Causes serious eye irritation ------ H332 Harmful if inhaled ------ H336 May cause drowsiness or dizziness 505, DURAGLOSS WATER SPOT REMOVER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/26/2016 EN (English US) 8/8 SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product