701, DURAGLOSS WHITEWALL TIRE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date: 05/28/2015 06/02/2016 EN (English US) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : 701, DURAGLOSS WHITEWALL TIRE CLEANER Product code : Part #701 22oz, 703 Gal 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet Brothers Research Corporation 2245 Airpark Drive Burlington, NC 27216 T 336-229-6480 1.4. Emergency telephone number Emergency number : 800-424-9300 Chemtrec SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin Irrit. 2 H315 Eye Irrit. 2A H319 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H315 - Causes skin irritation H319 - Causes serious eye irritation Precautionary statements (GHS-US) : P264 - Wash ... thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - If on skin: Wash with plenty of water/? P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P321 - Specific treatment (see ... on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture 701, DURAGLOSS WHITEWALL TIRE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/02/2016 EN (English US) 2/8 Name Product identifier % Classification (GHS-US) butyl glycolether (CAS No) 111-76-2 1 - 3 Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Acute Tox. 4 (Inhalation:dust,mist), H332 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 disodium metasilicate (CAS No) 6834-92-0 0.5 - 1 Skin Corr. 1A, H314 STOT SE 3, H335 potassium hydroxide,0.5%<=conc<2%,aqueous solutions (CAS No) 1310-58-3 0.5 - 1 Acute Tox. 4 (Oral), H302 Skin Corr. 1A, H314 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Remove the victim into fresh air. If not breathing give artificial respiration. Get immediate medical advice/attention. Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : If skin irritation or rash occurs: Get medical advice/attention. Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Wash skin with plenty of water. First-aid measures after eye contact : Move victim away from exposure and into fresh air. Rinse immediately with plenty of water for 15 minutes. Get medical advice/attention. Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. Rinse eyes with water as a precaution. First-aid measures after ingestion : Do not induce vomiting. Call a physician or poison control center immediately. Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Call a poison center/doctor/physician if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide. Dry chemical powder. Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : ---------- TO BE COMPLETED ---------- Explosion hazard : ---------- TO BE COMPLETED ---------- Reactivity : ---------- TO BE COMPLETED ---------- 5.3. Advice for firefighters Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Complete protective clothing. Self-contained breathing apparatus. Do not enter fire area without proper protective equipment, including respiratory protection. Do not attempt to take action without suitable protective equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Absorb spill on vermiculite floor absorbent or other absorbent material. 6.1.1. For non-emergency personnel Protective equipment : Protective clothing. Protective goggles. Emergency procedures : If runoff ocurrs, notify authorities as required. Pump or vacuum transfer spilled product to clean containers for recovery. Absorb unrecoverable product. Transfer contaminated absorbent, material to containers for disposal. Close container tightly and dispose of properly. Evacuate unnecessary personnel. 701, DURAGLOSS WHITEWALL TIRE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/02/2016 EN (English US) 3/8 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. Equip cleanup crew with proper protection. For further information refer to section 8: "Exposure controls/personal protection". Emergency procedures : Ventilate area. 6.2. Environmental precautions Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Containers of this material may be hazardous when empited. All hazard precautions give should be observed. Precautions for safe handling : Ensure good ventilation of the work station. Wear personal protective equipment. Handle and open the container with care. Treat empty drums with caution. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Emptied containers may retain product residues. Precautions apply to emptied containers. Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Keep cool. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 701, DURAGLOSS WHITEWALL TIRE CLEANER ACGIH Not applicable OSHA Not applicable butyl glycolether (111-76-2) ACGIH ACGIH TWA (ppm) 20 ppm ACGIH ACGIH STEL (ppm) 20 ppm OSHA Not applicable disodium metasilicate (6834-92-0) ACGIH Not applicable OSHA Not applicable potassium hydroxide,0.5%<=conc<2%,aqueous solutions (1310-58-3) ACGIH ACGIH Ceiling (mg/m?) 2 mg/m? OSHA Not applicable 8.2. Exposure controls Appropriate engineering controls : Ensure good ventilation of the work station. 701, DURAGLOSS WHITEWALL TIRE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/02/2016 EN (English US) 4/8 Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Environmental exposure controls : Avoid release to the environment. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear Liquid. Color : Clear Liquid Odor : Butyl Odor threshold : No data available pH : 11 - 12 Relative evaporation rate (butyl acetate=1) : No data available Melting point : No Data Freezing point : No data available Boiling point : 212 ?F Flash point : > 200 ?F Auto-ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : 140 @ 130.0 F Relative vapor density at 20 ?C : No data available Relative density : H20 = <1 Solubility : Soluble in water. Water: Solubility in water of component(s) of the mixture : ? : ? : > 18 g/100ml ? : Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity ---------- TO BE COMPLETED ---------- 10.2. Chemical stability Stable under normal conditions. Not established. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 701, DURAGLOSS WHITEWALL TIRE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/02/2016 EN (English US) 5/8 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified butyl glycolether (111-76-2) LD50 oral rat 1746 mg/kg body weight (Rat; Equivalent or similar to OECD 401; Experimental value) LD50 dermal rat > 2000 mg/kg body weight (Rat; Experimental value; OECD 402: Acute Dermal Toxicity) LC50 inhalation rat (mg/l) 2.2 mg/l/4h (Rat; Experimental value) LC50 inhalation rat (ppm) 450 ppm/4h (Rat; Experimental value) ATE US (oral) 1746.000 mg/kg body weight ATE US (dermal) 1100.000 mg/kg body weight ATE US (gases) 450.000 ppmV/4h ATE US (vapors) 2.200 mg/l/4h ATE US (dust, mist) 2.200 mg/l/4h disodium metasilicate (6834-92-0) LD50 dermal rat > 5000 mg/kg body weight (Rat; Read-across; OECD 402: Acute Dermal Toxicity) potassium hydroxide,0.5%<=conc<2%,aqueous solutions (1310-58-3) ATE US (oral) 500.000 mg/kg body weight Skin corrosion/irritation : Causes skin irritation. pH: 11 - 12 Serious eye damage/irritation : Causes serious eye irritation. pH: 11 - 12 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified butyl glycolether (111-76-2) IARC group 3 - Not classifiable Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. butyl glycolether (111-76-2) LC50 fish 1 1474 ppm (96 h; Oncorhynchus mykiss) EC50 Daphnia 1 1550 mg/l (48 h; Daphnia magna) Threshold limit algae 1 911 mg/l (72 h; Pseudokirchneriella subcapitata) Threshold limit algae 2 88 mg/l (72 h; Pseudokirchneriella subcapitata) disodium metasilicate (6834-92-0) LC50 fish 1 210 mg/l (96 h; Brachydanio rerio) 701, DURAGLOSS WHITEWALL TIRE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/02/2016 EN (English US) 6/8 disodium metasilicate (6834-92-0) EC50 Daphnia 1 216 mg/l (96 h; Daphnia magna; GLP) LC50 fish 2 2320 mg/l (96 h; Gambusia affinis) EC50 Daphnia 2 632 mg/l (96 h; Lymnaea sp.) Threshold limit algae 1 207 mg/l (72 h; Scenedesmus subspicatus; GLP) potassium hydroxide,0.5%<=conc<2%,aqueous solutions (1310-58-3) LC50 fish 1 100 - 1000 mg/l (96 h; Pisces) LC50 other aquatic organisms 1 100 - 1000 mg/l (96 h) Threshold limit other aquatic organisms 1 100 - 1000,96 h 12.2. Persistence and degradability 701, DURAGLOSS WHITEWALL TIRE CLEANER Persistence and degradability Not established. butyl glycolether (111-76-2) Persistence and degradability Readily biodegradable in water. Low potential for adsorption in soil. Photooxidation in the air. disodium metasilicate (6834-92-0) Persistence and degradability Biodegradability: not applicable. No (test)data on mobility of the substance available. Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable ThOD Not applicable BOD (% of ThOD) Not applicable potassium hydroxide,0.5%<=conc<2%,aqueous solutions (1310-58-3) Persistence and degradability Biodegradability: not applicable. No (test)data on mobility of the components available. Biochemical oxygen demand (BOD) Not applicable Chemical oxygen demand (COD) Not applicable ThOD Not applicable BOD (% of ThOD) Not applicable 12.3. Bioaccumulative potential 701, DURAGLOSS WHITEWALL TIRE CLEANER Bioaccumulative potential Not established. butyl glycolether (111-76-2) Log Pow 0.81 (Test data; 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). disodium metasilicate (6834-92-0) Bioaccumulative potential Bioaccumulation: not applicable. potassium hydroxide,0.5%<=conc<2%,aqueous solutions (1310-58-3) Bioaccumulative potential Not bioaccumulative. 12.4. Mobility in soil butyl glycolether (111-76-2) Surface tension 0.065 N/m (20 ?C; 003) 12.5. Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. 701, DURAGLOSS WHITEWALL TIRE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/02/2016 EN (English US) 7/8 SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations 701, DURAGLOSS WHITEWALL TIRE CLEANER Not listed on the United States TSCA (Toxic Substances Control Act) inventory butyl glycolether (111-76-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory disodium metasilicate (6834-92-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] 15.2.2. National regulations \ \ \ 15.3. US State regulations butyl glycolether (111-76-2) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Revision date : 05/28/2015 Other information : None. 701, DURAGLOSS WHITEWALL TIRE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/02/2016 EN (English US) 8/8 Full text of H-phrases: ------ Acute Tox. 4 (Dermal) Acute toxicity (dermal) Category 4 ------ Acute Tox. 4 (Inhalation:dust,mist) Acute toxicity (inhalation:dust,mist) Category 4 ------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4 ------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A ------ Flam. Liq. 4 Flammable liquids Category 4 ------ Skin Corr. 1A Skin corrosion/irritation Category 1A ------ Skin Irrit. 2 Skin corrosion/irritation Category 2 ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H227 Combustible liquid ------ H302 Harmful if swallowed ------ H312 Harmful in contact with skin ------ H314 Causes severe skin burns and eye damage ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation ------ H332 Harmful if inhaled ------ H335 May cause respiratory irritation SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product